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This paper aims to investigate the thermal oxidation behavior of trimethylolpropane trioleate (TMPTO) base oil when exposed to Fe surfaces.

Samples of TMPTO bulk oil were placed in Fe vessels and heated in an oven to accelerate the oxidation at different time intervals, while others were placed in glass vessels and used as experimental controls. Subsequently, the physicochemical properties of the oxidized TMPTOs, including the kinematic viscosity and acid value, were measured and a structural analysis was conducted using the Raman and Fourier transform infrared (FTIR) techniques.

The results demonstrate that the TMPTO bulk oil exhibited an exponential increase in the kinematic viscosity along with the increasing acid value over the oxidation time. The Fe surface significantly increased the kinematic viscosity of TMPTO, while only mildly impacting its acid value compared with the experimental controls. The structural analysis results of the TMPTO suggest that the C = C and = C-H bonds were the vulnerable sites. Furthermore, the results suggest that the Fe surface evidently accelerates the chemical reactions of the C = C and the = C-H bonds, and less alcohols and more carbonyl products were identified in the oil samples that were heated in the Fe vessels.

The results demonstrate that the Fe surfaces affected the oxidation behavior of the TMPTO base oil, and an interaction mechanism between the Fe and the TMPTO is developed.

This paper aims to investigate the thermal oxidation characteristics of the unsaturated bonds (C=C) of trimethylolpropane trioleate (TMPTO) and to reveal the high temperature oxidation decay mechanism of unsaturated esters and the nature of the anti-oxidation properties of the additives.

Using a DXR laser microscopic Raman spectrometer and Linkam FTIR600 temperature control platform, the isothermal oxidation experiments of TMPTO with or without 1.0 wt. % of different antioxidants were performed.

The results indicated that the Raman peaks of =C-H, C=C and -CH₂- weaken gradually with prolonged oxidation time, and the corresponding Raman intensities drop rapidly at higher temperatures. The aromatic amine antioxidant can decrease the attenuation of peak intensity, as it significantly reduces the rate constant of C=C thermal oxidation. The hindered phenolic antioxidant has a protective effect during the early stages of oxidation (induction period), but it may accelerate the oxidation of C=C afterwards.

Research on the structure changes of synthetic esters during oxidation by Raman spectroscopy will be of great importance in promoting the use of Raman spectroscopy to analyze the oxidation of lubricants.

This paper aims to investigate the tribological behavior and online infrared spectra of three types of lubricating oils containing dinonyl diphenylamine (DNDA) antioxidant, which are mineral oil (MO), poly alpha olefin (PAO) and trimethylolpropane trioleate (TMPTO), during the friction process at high temperature (temperature rising at first and isothermal holding afterwards).

A platform of low speed four-ball tribometer equipped with a temperature controller combined with infrared spectrometer was established. MO, PAO and TMPTO base oils were mixed with 1.0 Wt.% DNDA antioxidant, coded as MO_a, PAO_a and TMPTO_a in sequence. The friction coefficient and online infrared spectra of the oils were tested during the friction process of temperature rising at first and isothermal holding afterwards, and the wear tracks of the upper balls were measured using a confocal scanning optical microscope.

The results indicated that the DNDA antioxidant was depleted to reduce the generation of alcohols and carbonyl products, and the depletion rate of DNDA followed the sequence of MO_a > PAO_a > TMPTO_a. In the temperature rising friction process, the critical transition of friction coefficient was confirmed. The addition of DNDA antioxidant reduced the temperature of the oils at the critical transition of friction coefficient, and the temperature followed the sequence of TMPTO_a > PAO_a > MO_a. After the critical transition, the friction coefficient was first increased and then declined to a steady value; the friction coefficient of MO_a increased and declined first, followed by PAO_a and TMPTO_a. In the steady stage of friction, there was no obvious effect of DNDA on the friction coefficient of the oils. Moreover, DNDA enhanced the wear properties of MO_a and PAO_a; no obvious improvement was revealed for the wear property of TMPTO_a.

The established platform of low speed four-ball tribometer combined with infrared spectrometer successfully realized online testing of the structure changes of lubricating oil during high temperature friction, which can give some reference on the oxidation and friction researches of lubricating oil.

The purpose of this paper is to synthesize amines/phenolic antioxidants by a new method and to characterize the influence of antioxidants on thermo-oxidative degradation in trimethylolpropane trioleate (TMPTO) base oil.

The molecule structures of antioxidants and lubricants were confirmed using Fourier transform infrared spectroscopy (FTIR). The oxidative stability of antioxidants and lubricants was evaluated by pressurized differential scanning calorimetry (PDSC).

These findings suggested that butyl-octyl-diphenylamine has obvious advantage on kinematic viscosity inhibition, and amine-phenol combination antioxidant has a slightly better suppression of total acid in TMPTO under thermal oxidation at 200°C for 96 h. The FTIR characterizations showed that all antioxidants could protect the basic structure of TMPTO in the early stage of thermal degradation.

Under the action of butyl-octyl-diphenylamine, the dehydrogenation of TMPTO is easily met with the alkenyl hydrogen = C–H bond in the unsaturated C = C. Meanwhile, as octadecyl 3-(3, 5-di-tert-butyl-4-hydroxyphenyl)propionate protects TMPTO, the unsaturated C = C bond in the base oil molecule easily breaks down during transition.

This study aims to analyse the deep resource mining that causes high in situ stress, and the disturbance of tunnelling and mining which may induce large stress concentration, plastic deformation and rock strata compression deformation. The depth of deep resources, excavation rate and multilayered heterogeneity are critical factors of excavation disturbance in deep rock. However, at present, there are few engineering practices used in deep resource mining, and it is difficult to analyse the high in situ stress and dynamic three-dimensional (3D) excavation process in laboratory experiments. As a result, an understanding of the behaviours and mechanisms of the dynamic evolution of the stress field and plastic zone in deep tunnelling and mining surrounding rock is still lacking.

This study introduced a 3D engineering-scale finite element model and analysed the scheme involved the elastoplastic constitutive and element deletion techniques, while considering the influence of the deep rock mass of the roadway excavation, coal seam mining-induced stress, plastic zone in the process of mining disturbance of the in situ stress state, excavation rate and layered rock mass properties at the depths of 500 m, 1,500 m and 2,500 m of several typical coal seams, and the tunnelling and excavation rates of 0.5 m/step, 1 m/step and 2 m/step. An engineering-scale numerical model of the layered rock and soil body in an actual mining area were also established.

The simulation results of the surrounding rock stress field, dynamic evolution and maximum value change of the plastic zone, large deformation and settlement of the layered rock mass are obtained. The numerical results indicate that the process of mining can be accelerated with the increase in the tunnelling and excavation rate, but the vertical concentrated stress induced by the surrounding rock intensifies with the increase in the excavation rate, which becomes a crucial factor affecting the instability of the surrounding rock. The deep rock mass is in the high in situ stress state, and the stress and plastic strain maxima of the surrounding rock induced by the tunnelling and mining processes increase sharply with the excavation depth. In ultra-deep conditions (depth of 2,500 m), the maximum vertical stress is quickly reached by the conventional tunnelling and mining process. Compared with the deep homogeneous rock mass model, the multilayered heterogeneous rock mass produces higher mining-induced stress and plastic strain in each layer during the entire process of tunnelling and mining, and each layer presents a squeeze and dislocation deformation.

The results of this study can provide a valuable reference for the dynamic evolution of stress and plastic deformation in roadway tunnelling and coal seam mining to investigate the mechanisms of in situ stress at typical depths, excavation rates, stress concentrations, plastic deformations and compression behaviours of multilayered heterogeneity.

The purpose of this paper is to develop new types of anchor bolt materials by adding corrosion-resistant elements for alloying and microstructure regulation.

Three new anchor bolt materials were designed around the 1Ni system. The stress corrosion cracking resistance of the new materials was characterized by microstructure observation, electrochemical testing and slow strain rate tensile testing.

The strength of the new anchor bolt materials has been improved, and the stress corrosion sensitivity has been reduced. The addition of Nb makes the material exhibit excellent stress corrosion resistance under –1,200 mV conditions, but the expected results were not achieved when Nb and Sb were coupled.

The new anchor bolt materials designed around 1Ni have excellent stress corrosion resistance, which is the development direction of future materials. Nb allows the material to retain its ability to extend in hydrogen-evolution environments.

This paper aims to investigate the impact of executives’ self-interested behaviors induced by the pay bandwagon on stock price crash risk in Chinese listed firms and attempt to shed light on the influencing channels of this effect.

The empirical analysis is based on the panel data set which contains information on the executives and stock price of 11,710 firm-year observations over the period 2007–2015. The multiple linear regression models are implemented to examine whether the executive pay bandwagon affects corporate future stock price crash risk. Then, earnings management, tax avoidance and overinvestment are applied as the behavior choice of executive pay bandwagon to analyze the potential influencing channels.

Results indicate that the lower the executives’ pay is than the median pay level of executives in firms of similar size and industry, incentives of pay bandwagon are stronger, leading to a higher future stock price crash risk. Moreover, evidence shows that the positive relationship between executive pay bandwagon and crash risk is attenuated when firms have strong external monitoring mechanisms such as Big Four auditors, cross-listing in the Hong Kong stock exchange, high marketization process and high institutional ownership. Then, some weak evidence supports that internal governance such as internal control plays the same moderating role. In addition, based on the path test, the stock price crash effect of the executive pay bandwagon has a complete tax avoidance intermediary effect and a partial earnings management intermediary effect.

This study contributes to the executive compensation literature from a psychological perspective on the economic consequences research brought about by the pay bandwagon for China’s listed firms. Moreover, this paper provides a supplement to the literature on factors which is completely different from previous studies that affect the future stock price crash risk.

The utilisation of building information modelling (BIM) technology is rapidly increasing among construction professionals across the world. Notwithstanding, recent studies revealed a low level of BIM implementation in the context of the Nigerian construction sector. Moreover, previous studies have established that BIM application comes with its share of various barriers. Therefore, this study aims to carry out an on-site survey on barriers to the application of BIM on construction sites in the Nigerian construction industry.

An extensive review of literature on BIM barriers was conducted, from where 33 factors were identified as significant BIM barriers peculiar to the developing countries. A questionnaire was developed and distributed to the targeted respondents, who are practicing professionals in the Nigerian construction industry, based on the identified barriers. The data collected were analysed by using both descriptive and inferential statistics.

The principal component analysis revealed that 27 barriers were peculiar to the Nigerian construction industry. The “lack of familiarity with BIM capacity, habitual resistance to change from the traditional style of design and build, and poor awareness of BIM benefit” were identified as the three most critical barriers hindering BIM application on construction sites in the Nigerian construction industry.

This study reveals key information on the peculiar barriers to BIM application in the Nigerian construction industry. The avoidance of these barriers will not only assist various construction stakeholders in the successful implementation of BIM application on a construction project but also promote information management systems and productivity within the construction industry to a great extent. These will further improve post-construction activities.

This study provides a substantial understanding of BIM state of the art in the context of barriers hindering BIM application on construction sites in the Nigerian construction industry.

This study aims to overcome the involved challenging issues and provide high-precision eigensolutions. General eigenproblems in the system of ordinary differential equations (ODEs) serve as mathematical models for vector Sturm-Liouville (SL) and free vibration problems. High-precision eigenvalue and eigenfunction solutions are crucial bases for the reliable dynamic analysis of structures. However, solutions that meet the error tolerances specified are difficult to obtain for issues such as coefficients of variable matrices, coincident and adjacent approximate eigenvalues, continuous orders of eigenpairs and varying boundary conditions.

This study presents an h-version adaptive finite element method based on the superconvergent patch recovery displacement method for eigenproblems in system of second-order ODEs. The high-order shape function interpolation technique is further introduced to acquire superconvergent solution of eigenfunction, and superconvergent solution of eigenvalue is obtained by computing the Rayleigh quotient. Superconvergent solution of eigenfunction is used to estimate the error of finite element solution in the energy norm. The mesh is then, subdivided to generate an improved mesh, based on the error.

Representative eigenproblems examples, containing typical vector SL and free vibration of beams problems involved the aforementioned challenging issues, are selected to evaluate the accuracy and reliability of the proposed method. Non-uniform refined meshes are established to suit eigenfunctions change, and numerical solutions satisfy the pre-specified error tolerance.

The proposed combination of methodologies described in the paper, leads to a powerful h-version mesh refinement algorithm for eigenproblems in system of second-order ODEs, that can be extended to other classes of applications in damage detection of multiple cracks in structures based on the high-precision eigensolutions.

Moderately thick circular cylindrical shells are widely used as supporting structures or storage cavities in structural engineering, rock engineering, and aerospace engineering. In practical engineering, shells often work with micro-cracks or defects. The existence of micro-crack damage may result in the disturbance of dynamic behaviours and even induce accidental dynamic disasters. The free vibration frequency and mode are important parameters for the dynamic performance and damage identification analysis. In particular, stiffness weakening of the local damage region leads to significant changes in the vibration mode, which makes it difficult for the mesh generated in the conventional finite element method to capture a high-precision solution of the local oscillation.

In response to the above problems, this study developed an adaptive finite element method and a crack damage characterisation method for moderately thick circular cylindrical shells. By introducing the inverse power iteration method, error estimation, and mesh subdivision refinement technique for the analysis of finite element eigenvalue problems, an adaptive computation scheme was constructed for the free vibration problem of moderately thick circular cylindrical shells with circumferential crack damage.

Based on typical numerical examples, the established adaptive finite element solution for the free vibration of moderately thick circular cylindrical shells demonstrated its suitability for solving the high-precision free vibration frequency and mode of cylindrical shell structures. The any order frequency and mode shape of cracked cylindrical shells under the conditions of different ring wave numbers, crack locations, crack depths, and multiple cracks were successfully solved. The influences of the location, depth, and number of cracks on the disturbance of dynamic behaviours were analysed.

This study can be used as a reference for the adaptive finite element solution of free vibration of moderately thick circular cylindrical shells with cracks and lays the foundation for further development of a high-performance computation method suitable for the dynamic disturbance and damage identification analysis of general cracked structures.