Dong Liu, ZhenYu Chen and XingPeng Guo
The purpose of this paper is to consider the effect of acetic acid and acetate on the anodic and cathodic reactions of carbon steel present in CO2 corrosion.
Abstract
Purpose
The purpose of this paper is to consider the effect of acetic acid and acetate on the anodic and cathodic reactions of carbon steel present in CO2 corrosion.
Design/methodology/approach
The corrosion behaviour of carbon steel (N80) in CO2‐saturated 1% NaCl solution at 50°C and 0.1 MPa was investigated by using weight‐loss tests, electrochemical methods (polarization curves and electrochemical impedance spectroscopy) and surface analysis (scanning electron microscopy).
Findings
The results indicated that: both HAc and Ac− significantly increased the corrosion rate of carbon steel, and the surface chemical reactions of cathodic reduction were enhanced in the presence of HAc and Ac−. Because adsorbed HAc could be reduced directly in the presence of Ac−, the corrosion rate increased, even though the pH of the solution increased. Ac− played an important role in the anodic dissolution processes, which mainly affects the formation/adsorption of intermediates, and acts to form more soluble corrosion products.
Originality/value
The results of this work clarify the role of acetic acid or acetate in the anodic and cathodic reactions of CO2 corrosion.
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Lu Zhaoling, Fu Chaoyang and Guo Xingpeng
This paper seeks to investigate the different inhibition performance and adsorption behaviour of dodecylamine in acidic and neutral environments and to understand further the…
Abstract
Purpose
This paper seeks to investigate the different inhibition performance and adsorption behaviour of dodecylamine in acidic and neutral environments and to understand further the inhibition mechanism of dodecylamine in CO2‐saturated brine solution.
Design/methodology/approach
The inhibition performance and adsorption behaviour of dodecylamine on N80 steel in CO2‐saturated brine solution in acidic and neutral environments were investigated by potentiodynamic polarization, electrochemical impedance spectroscopy and the attenuated total reflection‐Fourier transform infrared spectroscopy.
Findings
Corrosion potentials exhibited a pronounced shift in the positive direction at higher concentrations of dodecylamine. The inhibition efficiency of dodecylamine was shown to be pH‐dependent. The effective inhibition concentration of dodecylamine decreased from pH 4.9 to 7.4. In a neutral environment, the inhibitor was shown to affect the deposition of the corrosion products and provide more active sites to bond with the inhibitor. More alkaline environments made the electron cloud density of dodecylamine much higher, which was more favourable to the interaction of dodecylamine and the naked metal base, and hence dodecylamine had a much better inhibition performance in a neutral environment than in acidic environments.
Originality/value
This paper provides information regarding the inhibition performance and adsorption behaviour of dodecylamine on N80 steel and probes the inhibition mechanism of dodecylamine in acidic and neutral environments. The results of the work contribute to an understanding of the inhibition mechanism of the inhibitor in different environments, which will be useful for effective design and choice of inhibitors in CO2 corrosion.
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Maosheng Wen, En Zhu Hu, Xingpeng Fei and Kunhong Hu
This paper aims to use an ionic liquid (IL, [HMIM]PF6) to improve the lubrication performance of liquid metal (LM) as a lithium grease additive and to expand the application range…
Abstract
Purpose
This paper aims to use an ionic liquid (IL, [HMIM]PF6) to improve the lubrication performance of liquid metal (LM) as a lithium grease additive and to expand the application range of LM.
Design/methodology/approach
In this paper, the different mass ratios of [HMIM]PF6/LM mixtures were added into the lithium grease on a four-ball tribo-meter to investigate the effects of its tribological behavior. Scanning electron mircoscope/energy dispersive spectroscopy and X-ray photoelectron spectroscopy were used to reveal the anti-wear and friction-reducing mechanism of the additives.
Findings
When the load was used at 461 N, the average coefficient of friction (ACOF) and average wear scar diameter (AWSD) of steel ball Lubricated with grease with an optimal ratio of 2:3 ([HMIM]PF6/LM) were reduced by 32.8% and 30.5%, respectively. Friction and wear mechanisms are ascribed to friction-induced additive components that can simultaneously form a composite lubrication film consisting of FePO4, FeF3, Ga2O3, In2O3 and SnO2.
Research limitations/implications
Compared with the pure lithium-based grease, when [HMIM]PF6/LM was added with an optimal ratio of 2:3, the ACOF and AWSD were reduced by 12.4% from 0.097 to 0.085 and 23.8% from 552.117 µm to 420.590 µm under 392 N, respectively. When at 461 N, the ACOF and AWSD of steel ball were reduced by 32.8% from 0.122 to 0.082 and 30.5% from 715.714 µm to 497.472 µm, respectively. It was shown that the simultaneous addition of LM and [HMIM]PF6 can form a composite lubrication film consisting of FePO4, FeF3, Ga2O3, In2O3 and SnO2.
Originality/value
In this paper, [HMIM]P F6 is added with LM simultaneously to improve the lubrication properties of lithium grease, and expand the application scope of LM.
Peer review
The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-01-2024-0017/
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Yang Wang, Xingpeng He, Jian Zuo and Raufdeen Rameezdeen
The public's trust in the authorities has a great impact on people's perception and cognition on development of different types of urban transport infrastructure projects (UTIPs)…
Abstract
Purpose
The public's trust in the authorities has a great impact on people's perception and cognition on development of different types of urban transport infrastructure projects (UTIPs). Given the importance of public acceptance for the efficient construction and operation of UTIPs, this study aims at investigating the personal and environmental factors that influence public acceptance behavior from the perspective of stakeholder management.
Design/methodology/approach
Based on social cognitive theory (SCT), this study explores the multiple dimensions of social trust on public acceptance in the development of UTIPs by a comparative case study. Two types of UTIPs, a metro railway and a bridge in the Wuhan City, China, were selected as cases, with a questionnaire distributed among the public to collect their sense of trust towards the development of these projects. The data were analyzed through structural equation modeling (SEM).
Findings
This study reveals that social trust positively influences public acceptance, directly or indirectly through perceived benefit and -risks and self-efficacy. However, the emphasis on social trust about competence and integrity of the authorities varies with the types of projects. Self-efficacy worked as the “mirror of trust” reflecting people's attitude towards social trust in the authorities on their ability and morality.
Originality/value
The value of the paper lies in discussing social trust from multiple dimensions in the field of urban infrastructures, which provides new insights into specific mechanisms for shaping public acceptance in project management towards the development of UTIPs.