Anees Khadom and Khalid Rashid
This paper aims to study the corrosion inhibition of mild steel in 2.5 M HCl solution by kiwi juice at different temperatures, inhibitor concentration and immersion times.
Abstract
Purpose
This paper aims to study the corrosion inhibition of mild steel in 2.5 M HCl solution by kiwi juice at different temperatures, inhibitor concentration and immersion times.
Design/methodology/approach
Box–Wilson experimental design is used for runs distribution and the corrosion rate values are evaluated by weight loss technique.
Findings
Corrosion rate increased with temperature according to Arrhenius equation, and the inhibitor adsorbed according to Langmuir adsorption isotherm. Second-order polynomial model is used for data fitting. The optimum conditions were estimated with maximum inhibitor efficiency of 96.1 per cent. Fourier transform infrared analysis showed that the peaks correspond to phenols, and quercitine is the main component. Microstructural, hardness and theoretical quantum studies are also performed.
Originality/value
This is one of the first steps in the direction of understanding the corrosion control problems from different views. Kinetics, surface morphology, optimization and mathematical views are taken in to account.
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Khalid Rashid and Anees Khadom
The purpose of this study is to investigate the corrosion inhibition of mild steel alloy in 2 M H3PO4 solution by the pomegranate peel extract as a friendly inhibitor was studied…
Abstract
Purpose
The purpose of this study is to investigate the corrosion inhibition of mild steel alloy in 2 M H3PO4 solution by the pomegranate peel extract as a friendly inhibitor was studied at various temperatures, inhibitor concentrations and immersion times.
Design/methodology/approach
A weight loss method was used to evaluate the corrosion rate. The experimental Taguchi design method was used for the distribution of experiments. The experimental design gave results which were impossible to show graphically. However, this problem was solved effectively with the aid of regression analysis.
Findings
Corrosion rate increased with temperature according to Arrhenius equation. It was found that the efficiency of inhibition was increased with an increase in the concentration of inhibitor and immersion time. However, this diminishes with increased temperature. According to Langmuir isotherm, the inhibitor was adsorbed physically on steel surface. The negative sign of estimated heat of adsorption suggests a stable spontaneous inhibition process. Combination of mathematical and statistical analysis was proposed to demonstrate the results of corrosion rate with high correlation coefficients. In addition, Fourier transform infrared spectrometer examinations confirmed that the organic inhibitor consists of phenolic components as main materials.
Originality/value
Using unconventional approach for evaluation of environmentally friendly inhibitor for corrosion of mild steel in phosphoric acid solution.
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Aprael S. Yaro, Anees A. Khadom and Hadeel F. Ibraheem
The aim of this paper is to investigate peach juice as a cheap, raw, green and non‐toxic anti‐corrosion material for mild steel corrosion in hydrochloric acid at different…
Abstract
Purpose
The aim of this paper is to investigate peach juice as a cheap, raw, green and non‐toxic anti‐corrosion material for mild steel corrosion in hydrochloric acid at different temperatures.
Design/methodology/approach
The corrosion inhibition of mild steel in 1 M HCl solution in the presence of peach juice at temperature range of 30‐60°C and concentration range of 5‐50 cm3/l was studied using weight loss and polarization techniques. The inhibition effect, adsorption characteristics, mathematical and electrochemical modeling of peach juice were addressed.
Findings
Results show that inhibition efficiency rose with the increase of inhibitor concentration and temperature up to 50°C, while at temperatures above 50°C the values of efficiency decreased. The inhibitor adsorbed physically on metal surface and followed the Langmuir adsorption isotherm. Monolayer formed spontaneously on the metal surface. Maximum inhibition efficiency obtained was about 91 percent at 50°C in the 50 cm3/l inhibitor concentration.
Originality/value
This work is an attempt to find a new, safe to environment, non‐toxic corrosion inhibitor. Peach juice is a readily available material in Iraq and Middle East markets.
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Dr Priyanka Verma, Dr Deepa Gupta and Dr Mukul Gupta
Environmental, Social and Governance (ESG) reporting is crucial for organizations, especially in the current era where sustainability holds significant importance. Proper…
Abstract
Environmental, Social and Governance (ESG) reporting is crucial for organizations, especially in the current era where sustainability holds significant importance. Proper utilization of ESG reporting offers long-term benefits and enhances overall corporate well-being. This study explores fundamental aspects of ESG reporting, elucidating the reporting process, its advantages and requirements. An analysis highlights key impacts on businesses and their influence on consumer behaviour. The disclosure of ESG reporting and its determinants, such as business size and profitability, is discussed. Additionally, the study underscores the role of promoting diversity and inclusion as a Corporate Social Responsibility (CSR) function. Global firms undertake diverse initiatives to advance sustainability. The study emphasizes the triple bottom line theory as a strategy for sustainable development. ESG is recognized as a valuable tool for ensuring sustained growth and development in businesses. The research underscores the imperative for businesses to adopt sustainable measures consistently. Overall, the findings stress the significance of ESG reporting in the contemporary business landscape, linking it to corporate success, responsibility and the pursuit of sustainable practices.
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S.A. Mashi, S.A. Yaro and P.N. Eyong
Contamination of the environment by heavy metals is a phenomenon of global importance today. When present in high concentrations in the environment, heavy metals may enter the…
Abstract
Purpose
Contamination of the environment by heavy metals is a phenomenon of global importance today. When present in high concentrations in the environment, heavy metals may enter the food chain from soils and result in health hazards. Accumulation in street dust is one major way through which heavy metals may find their way into soils and subsequently living tissues of plants, animals and human beings. In this paper, the magnitude and sources of some heavy metals (Cu, Mn, Fe, Cd, Pb and Zn) in street dust samples in and around Gwagwalada, Nigeria, were assessed.
Design/methodology/approach
Street dust samples were collected from 12 sites with and without varying levels of human activities (blacksmithing, motor repair works, metal working and fabrication, vehicular traffic and residential development) in the area and analysed by atomic absorption spectrophotometry to determine the magnitude and sources of accumulation of the above heavy metals in street dust in the study area.
Findings
The mean concentrations were found to be 210, 79, 97, 3.9, 120 and 96 μg g−1 respectively, for Pb, Zn, Cu, Cd, Fe and Mn across the various sampling sites. Samples collected from sites with human activities were found to contain concentrations of the metals that are generally higher than those in background areas (without human activities). However, metal working and fabrication, and motor repair works were found to have a stronger influence on the accumulation of the metals in the dust samples than vehicular traffic.
Practical implications
The results indicate that, contrary to what is expected, based on the observations made in several areas by many researchers elsewhere, metal working and fabrication, and motor repair works have a stronger influence on the accumulation of the metals in the dust samples than vehicular traffic in the study area.
Originality/value
Provides information on heavy metal contamination of the environment in an area of Nigeria.
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Yuanpeng Cheng, Yu Bai, Zili Li and JianGuo Liu
The purpose of this paper was to investigate the corrosion behavior of X65 steel in the CO2/oil/water environment using mass loss method, potentiodynamic polarization technique…
Abstract
Purpose
The purpose of this paper was to investigate the corrosion behavior of X65 steel in the CO2/oil/water environment using mass loss method, potentiodynamic polarization technique and characterization of the corroded surface techniques.
Design/methodology/approach
The weight loss analysis, electrochemical study and surface investigation were carried out on X65 steel that had been immersed in the CO2/oil/water corrosive medium to understand the corrosion behavior of gathering pipeline steel. The weight loss tests were carried out in a 3L autoclave, and effects of flow velocity, CO2 partial pressure and water cut on the CO2 corrosion rate of X65 steel were studied. Electrochemical studies were carried out in a three-electrode electrochemical cell with the test temperature of 60°C and CO2 partial pressure of 1 atm by recording open circuit potential/time and potentiodynamic polarization characteristics. The surface and cross-sectional morphologies of corrosion product scales were characterized using scanning electron microscopy. The phases of corrosion product scales were investigated using X-ray diffraction.
Findings
The results showed that corrosion rates of X65 steel both increased at first and then decreased with the increase of flow velocity and CO2 partial pressure, and there were critical velocity and critical pressure in the simulated corrosive environment, below the critical value, the corrosion products formed on the steel surface were loose, porous and unstable, higher than the critical value, the corrosion product ?lms were dense, strong adhesion, and had a certain protective effect. Meanwhile, when the flow velocity exceeded the critical value, oil film could be adsorbed on the steel surface more evenly, corrosion reaction active points were reduced and the steel matrix was protected from being corroded and crude oil played a role of inhibitor, thus it influenced the corrosion rate. Above the critical CO2 partial pressure, the solubility of CO2 in crude oil increased, the viscosity of crude oil decreased and its fluidity became better, so that the probability of oil film adsorption increased, these factors led to the corrosion inhibition of X65 steel reinforced. The corrosion characteristics of gathering pipeline steel in the corrosive environment containing CO2 would change due to the presence of crude oil.
Originality/value
The results can be helpful in selecting the suitable corrosion inhibitors and targeted anti-corrosion measures for CO2/oil/water corrosive environment.
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Osuani Fyneface Idema, Malik Abdulwahab, Innocent Okechi Arukalam, Ifeyinwa Ekeke, Chigoziri N. Njoku, Chioma Anyiam, Benedict Onyeachu and Emeka Emmanuel Oguzie
Hexavalent chromium has been a benchmark corrosion inhibitor before it was phased out because of its carcinogenic properties. However, because it was phased out, many alternative…
Abstract
Purpose
Hexavalent chromium has been a benchmark corrosion inhibitor before it was phased out because of its carcinogenic properties. However, because it was phased out, many alternative corrosion inhibitors have been introduced but failed to meet the performance of this benchmark inhibitor. Consequently, benzotriazole (BTA) was reported to exhibit chromate-like inhibition performance. Subsequently, Intelli-ion was reported by researchers to exhibit chromate-like performance also with claims of being a unique alternative. This paper aims to review the inhibition performance of these two alternatives. Above all, promotes the unique inhibition performance of Intelli-ion that makes it suitable for application in many sectors.
Design/methodology/approach
In this paper, the corrosion inhibition performances of BTA and Intelli-ion were compared systematically by reviewing some related literatures based on the opinion of the authors.
Findings
Different methodologies for measuring the inhibition performance of BTA showed that it’s an inhibitor of choice. However, the cut edge corrosion performance of Intelli-ion and BTA corrosion inhibitors on galvanized steel of 55% Wt.% Al, 44% Wt.% Zn and 1% Wt.% Si in 5 Wt.% NaCl solution was compared when subjected to scanning vibrating electrode technique (SVET) for 24 h. The results showed faint blue-colored region depicting negative cathodic current density for the Intelli-ion while there was a high-intensity of red-colored region depicting a positive anodic current density for BTA. In other words, the Intelli-ion inhibitor had a better overall cut-edge corrosion inhibition performance than the BTA inhibitor.
Originality/value
This paper compares and further, summarizes the corrosion inhibition performance of Intelli-ion and BTA by evaluating SVET results from the literature. In addition, it serves as an overview and reference for the unique inhibition performance of Intelli-ion when applied in field applications.
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The purpose of this paper was to test the extract of barley as an environmentally friendly inhibitor for the acid corrosion of steel due to its wide availability as a popular…
Abstract
Purpose
The purpose of this paper was to test the extract of barley as an environmentally friendly inhibitor for the acid corrosion of steel due to its wide availability as a popular major crop and its richness with different chemical constituents reported in literature (40) like alanine, glycine, serine, aspartic acid, leucine, valine, tyrosine and isoleucine with various number of functional groups that are able to chelate metal cations and to discuss the effect of temperature on its inhibition efficiency.
Design/methodology/approach
Electrochemical impedance spectroscopy (EIS) and polarization measurements were carried out using frequency response analyzer Gill AC instrument. The frequency range for EIS measurements was 0.1 ≤ f ≤ 1 × 103 with an applied potential signal amplitude of 10 mV around the rest potential. Polarization measurements were carried out at a scan rate of 30 mV/min, utilizing a three-electrode cell. A platinum sheet and saturated calomel electrode were used as counter and reference electrodes, respectively. The working electrode was constructed with steel specimens that have the following composition (weight per cent): C, 0.21; S, 0.04; Mn, 2.5; P, 0.04; Si, 0.35; and balance Fe.
Findings
Barley extract could act as an effective corrosion inhibitor for the acid corrosion of steel. The inhibiting action of the barley extract was attributed to its adsorption over the metal surface that blocks the available cathodic and anodic sites. Adsorption isotherms indicated that the adsorbed extract molecules cover one active center over the metal surface.
Originality/value
The research included the first use of an important world crop as an effective corrosion inhibitor that can reduce the corrosion of steel to an extent of 94 per cent.
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Sarfo Mensah, Collins Ameyaw and William Appiah Yeboah
The lack of carbon emission reduction strategies specifically devised for buildings in urban areas in developing countries has affected the global course of tackling carbon…
Abstract
Purpose
The lack of carbon emission reduction strategies specifically devised for buildings in urban areas in developing countries has affected the global course of tackling carbon emissions. The purpose of this study is to identify the causes of carbon emissions from buildings in urban settings in Ghana and generate specific reduction strategies.
Design/methodology/approach
The study was conducted with reference to Kumasi Metropolis, an urban area in Ghana. Adopting a survey research design, data obtained from 106 built environment professionals (BEP) were analyzed using Garrett’s mean ranking and factor analysis (FA) techniques.
Findings
Urban buildings’ carbon emissions in the study area are attributable to construction, demolition energy consumption, technological and economic factors. The strategies emerging from the study emphasize organizational and governmental policy and regulatory factors, as well as the adoption of indigenous sustainable materials and technology.
Practical implications
BEPs and construction industry regulatory bodies will have to consider socioeconomic characteristics of a specific location in the development of organizational and localized carbon emission reduction policies.
Social implications
Local authorities who plan economic activities such as trading and associated taxation in urban areas in developing countries should consider the climate change implications of such socioeconomic activities.
Originality/value
This is one of the first studies that has conceived carbon emission causes and reduction strategies within the context of a typical developing country’s urban setting to overcome the pragmatic challenges associated with past carbon emission reduction frameworks.
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Mohammed Elalaoui Belghiti, Ayssar Nahlé, Abdeslam Ansari, Yasser Karzazi, S. Tighadouini, Yassir El Ouadi, A. Dafali, Belkheir Hammouti and Smaail Radi
This paper aims to study the inhibition effect of 2-pyridinealdazine on the corrosion of mild steel in an acidic medium. The inhibition effect was studied using weight loss…
Abstract
Purpose
This paper aims to study the inhibition effect of 2-pyridinealdazine on the corrosion of mild steel in an acidic medium. The inhibition effect was studied using weight loss, electrochemical impedance spectroscopy, and Tafel polarization measurements.
Design/methodology/approach
Weight loss measurements, potentiodynamic tests, electrochemical impedance spectroscopy, X-ray diffraction and spectral and conformational isomers analysis of A (E-PAA) and B (Z-PAA) were performed were investigated.
Findings
2-pyridinealdazine (PAA) acts as a good inhibitor for the corrosion of steel in 2.0 M H3PO4. The inhibition efficiency increases with an increase in inhibitor concentration but decreases with an increase in temperature.
Originality/value
This paper is intended to be added to the family of azines which are highly efficient inhibitors and can be used in the area of corrosion prevention and control.