An important world crop – barley – as a new green inhibitor for acid corrosion of steel
Abstract
Purpose
The purpose of this paper was to test the extract of barley as an environmentally friendly inhibitor for the acid corrosion of steel due to its wide availability as a popular major crop and its richness with different chemical constituents reported in literature (40) like alanine, glycine, serine, aspartic acid, leucine, valine, tyrosine and isoleucine with various number of functional groups that are able to chelate metal cations and to discuss the effect of temperature on its inhibition efficiency.
Design/methodology/approach
Electrochemical impedance spectroscopy (EIS) and polarization measurements were carried out using frequency response analyzer Gill AC instrument. The frequency range for EIS measurements was 0.1 ≤ f ≤ 1 × 103 with an applied potential signal amplitude of 10 mV around the rest potential. Polarization measurements were carried out at a scan rate of 30 mV/min, utilizing a three-electrode cell. A platinum sheet and saturated calomel electrode were used as counter and reference electrodes, respectively. The working electrode was constructed with steel specimens that have the following composition (weight per cent): C, 0.21; S, 0.04; Mn, 2.5; P, 0.04; Si, 0.35; and balance Fe.
Findings
Barley extract could act as an effective corrosion inhibitor for the acid corrosion of steel. The inhibiting action of the barley extract was attributed to its adsorption over the metal surface that blocks the available cathodic and anodic sites. Adsorption isotherms indicated that the adsorbed extract molecules cover one active center over the metal surface.
Originality/value
The research included the first use of an important world crop as an effective corrosion inhibitor that can reduce the corrosion of steel to an extent of 94 per cent.
Keywords
Acknowledgements
The author wishes to thank Professors Dr Beshir Ahmed Abd El-Nabey, Dr Essam Khamis and Dr Ashraf Moustafa, Department of Chemistry, Faculty of Science, Alexandria University, Alexandria, Egypt, for continuous support and providing advanced instruments.
Citation
Saadawy, M. (2015), "An important world crop – barley – as a new green inhibitor for acid corrosion of steel", Anti-Corrosion Methods and Materials, Vol. 62 No. 4, pp. 220-228. https://doi.org/10.1108/ACMM-12-2013-1333
Publisher
:Emerald Group Publishing Limited
Copyright © 2015, Emerald Group Publishing Limited