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This study aims to assess the pitting resistance of austenitic stainless steel welded joints fusion zone (FZ) with high density of inclusions before and after surface treatment, including potentiostatic pulse technique (PPT) and pickling.

The potentiodynamic polarization tests and critical pitting temperature tests were carried out for estimating pitting resistance. The PPT and pickling were performed as surface treatment. Scanning electron microscope (SEM) and energy dispersive spectrometer were used for characterize the microstructure and elemental distribution. Electron back-scattered diffraction (EBSD) was used to assess the portion of phases and morphology of grains.

The weld metal exhibits a higher degree of alloying compared to the base metal, and it contains d-phase and sulfur-containing inclusions. Sulfur-containing inclusions serve as initiation sites for pitting, and they diminish the pitting resistance of weld metal. Both PPT and pickling can remove sulfur-containing inclusions, but PPT causes localized dissolution of the weld metal matrix around the inclusions, while pickling does not. Because of the high density of inclusions, certain pits initiated by PPT are significantly deeper, which makes the formation of stable pitting easier. Because of the high density of inclusions, certain pits initiated by the PPT are deeper. This characteristic facilitates the progression of these initial defects into fully developed, stable pits.

Analysis of pitting initiation in shielded metal arc welding FZ with PPT and ex situ SEM tracking observation. Explanation of why the PPT surface treatment is not able to enhance the pitting resistance of stainless steel with a high inclusion density.

This study aims to evaluate the influence of pulsed cathodic protection on calcareous deposit formation on structures submerged in the synthetic sea water.

Chronoamperometric and C_HF methods have been used to evaluate the influence of pulsed cathodic protection on decreasing the required cathodic current for protection and also decreasing the surface coverage. The morphology of the formed deposits was evaluated using scanning electron microscopy. Chemical analyses of the formed deposits were performed using energy dispersive X‐ray spectrometer and X‐ray diffraction.

It was observed that pulse frequency influenced both the structure and the composition of the deposits. The most compact aragonite layer was obtained at high frequencies and at a high off‐time. It was clearly shown that by applying currents with less than 100 Hz frequency, the deposits formed on the sample involved CaCO₃ (aragonite) and Mg(OH)₂ (brucite). However, the kinetics of deposits formed when applying pulse current have been improved, compared to deposits formed by conventional cathodic protection. The reason is that large electrode overpotential favors nucleation through a decrease in the energy of nucleus formation. On the other hand, by intensive decrease of surface potential, repulsion of aggressive anions such as SO₄²⁻ and Cl⁻ occurs. These anions inhibit the formation of aragonite deposits.

In order to have a better investigation of electrodeposition processes in the shorter time, the use of more advanced techniques and analysis methods such as XPS is recommended. Furthermore, EHD techniques could be used for measurements of thickness of the layers.

The pulsed cathodic protection method is a relatively new method for the protection of buried and submerged structures. Recently, many researches have investigated that the influence of this technique on increasing the throwing power, decreasing interference effects on neighboring structures and increasing the uniformity of current distribution under cathodic protection.

Very little attention has been paid in the past to the effect of pulsed CP on deposit formation. The present paper, therefore, contributes useful understanding of the mechanism and advantages of such deposits in improving the effectiveness and lowering the operational cost of cathodic protection in use on offshore structures.

A comprehensive range of instruments is offered extending from 150 volts at 1·6 amps to 20 volts at 100 amps.

A general survey is made of the techniques currently employed in corrosion studies. The application of both physical‐chemical and physical techniques is discussed. The majority of the techniques described could be used at some time or other by any corrosion laboratory either directly or indirectly. It is only by making such a wide coverage that a detailed picture of a corrosion process can be understood and the significance of alloying and corroding media (be it gas or liquid) appreciated.

The purpose of this paper is to present a novel five‐electrode electrochemical corrosion sensor. Health degradation by the corrosion of steel in civil engineering is a persistent problem. Structural health monitoring (SHM) techniques, including embedded sensors, can greatly improve the quantification of the steel corrosion information, which can lead to promote assessments of structural safety and serviceability. To integrate the corrosion monitoring system in future, the corrosion sensor and the monitoring methods have been explored here in advance. Also, the corrosion monitoring system has been applied preliminarily in the investigation of reinforcing concrete (RC) beams.

First, a novel five‐electrode electrochemical corrosion sensor has been developed as the hardware to provide the platform for corrosion monitoring methods. Second, half‐cell potential of the RC beams has been measured before and after corrosion. Third, galvanostatic step method has been used to excite the steel‐concrete system, and the transient response of the system has been obtained and analyzed. Finally, wavelet transform algorithm has been established to analyze the electrochemical noise (EN) data of the steel bars in RC beams.

The results show that the corrosion sensor can be used effectively as the hardware to support the electrochemical measuring techniques. Much valuable information which is extracted by analyzing the potential response to the galvanostatic pulse excitation can be applied to determine the general corrosion state of the reinforcing steel. For pitting corrosion, the energy distribution plot of EN can be adopted as a benchmark method to identify the presence of the corrosion pit.

The paper provides the key techniques for a SHM system to realize corrosion monitoring of large‐scale RC structures in the future.

Introduction Although investigation of a corrosion problem using only one or two techniques can give useful information, the most complete picture of the processes involved, and thus the best approach for a satisfactory solution of the problem, often only results from the use and interpretation of a combination of techniques. In this respect, the Corrosion Centre is fortunate in having a wide range of long‐established and modern facilities at its disposal, enabling reasonable investigations to be carried out on many different types of corrosion problems. These techniques are used primarily for research and teaching purposes, but many of them can be made available to industrial users. Table 1 gives an indication of some of the techniques to which the Centre has access and briefly mentions some of their possible applications in corrosion studies.

SYMPOSIUM Ferrare, Italy. Fischer, Germany. The inhibition by means of electrolytic layers is characterised in that they prevent the passage of metal in the diffusion layer and in the electrolyte layer.

A study has been carried out employing a vibratory motor, offering amplitudes of 0·4–4 mm at 50 Hz in acid copper sulphate as a model electrolyte in which α‐Al2O3 particles are suspended for co‐deposition, yielding a composite electrodeposit. Using a horizontal disc vibrator at the bottom of the container, perforated discs have been shown to give superior agitation and a laminar/turbulent transition has been identified. Incorporation of particles is a maximum at the transition. In the laminar regime Sh‐Re0·037 and in the turbulent regime Sh‐Re0·82. Mass transport enhancement was measured for a variety of disc and tank diameters and enhancement factors for electrodeposition of 3–40 times were obtained. In these circumstances a modified Reynolds number Re1 was employed Re1 = 100 ad2(d1−d2)/υd2 and, assuming a conventional dependence upon Sc, a full correlation of the type Sh1 = constant Re1a Sc0·33 was obtained where the constant took values of 10–40 and ‘a’ took values of 0·83–1·1 depending upon precise location within the tank of the mass transfer probe.

The novel structures and properties of nanostructure and nanomaterials give people perfect artistic expression of feeling and sense, then the nanoart discipline is developed and is closely related on the nanotechniques. The many achieved novel nanostructures with strong anti-corrosion prepared by the anodization have been reviewed. The paper would raise public awareness of nanotechnology, nanomaterial and their impact on our lives.

Anodization is a very effective and simple technique to form various nanostructures of metal oxide. It includes hard anodization, mild anodization and pulse anodization. Many measures have been introduced anodization process to improve the quality of formed nanostructure and enhance its properties, such as anti-corrosion.

The formation mechanism of anodic aluminum oxide (AAO) by using the mild, hard and pulse anodization has been discussed. The pretexture process and many other measures have been taken in mild and hard anodization to improve the regularity of pore array and greatly accelerate the formation rate of AAO. The pulse anodization has been used to prepare the multilayer Y-branched AAO film, which exhibits steady rich and vivid structure colors and gives a very good artistic expression. Furthermore, many other metal oxide nanostructures such as TiO₂ and CuO have also been fabricated using the anodization techniques.

Various nanostructures of metal oxide prepared by anodization have been reviewed and are itself a perfect artwork in mesoscale. Also, many nanostructures have exhibited steady, rich and vivid structure colors and give people a very good artistic expression.

The purpose of this paper is to present current state of understanding on jet electrodeposition manufacturing; to compare various experimental parameters and their implication on as deposited features; and to understand the characteristics of jet electrodeposition deposition defects and its preventive procedures through available research articles.

A systematic review has been done based on available research articles focused on jet electrodeposition and its characteristics. The review begins with a brief introduction to micro-electrodeposition and high-speed selective jet electrodeposition (HSSJED). The research and developments on how jet electrochemical manufacturing are clustered with conventional micro-electrodeposition and their developments. Furthermore, this study converges on comparative analysis on HSSJED and recent research trends in high-speed jet electrodeposition of metals, their alloys and composites and presents potential perspectives for the future research direction in the final section.

Edge defect, optimum nozzle height and controlled deposition remain major challenges in electrochemical manufacturing. On-situ deposition can be used as initial structural material for micro and nanoelectronic devices. Integration of ultrasonic, laser and acoustic source to jet electrochemical manufacturing are current trends that are promising enhanced homogeneity, controlled density and porosity with high precision manufacturing.

This paper discusses the key issue associated to high-speed jet electrodeposition process. Emphasis has been given to various electrochemical parameters and their effect on deposition. Pros and cons of variations in electrochemical parameters have been studied by comparing the available reports on experimental investigations. Defects and their preventive measures have also been discussed. This review presented a summary of past achievements and recent advancements in the field of jet electrochemical manufacturing.