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This study aims to investigate the thermal performance enhancements of phase change materials (PCMs) through the integration of extended fins and CuO nanoparticles under the impact of solar irradiation. The research focuses on improving the melting behavior and thermal efficiency of PCM-based energy storage systems to facilitate the design of more efficient energy storage solutions.

The analysis is conducted on a top-heated rectangular thermal system filled with pure PCM and nanoparticle-enhanced PCM (NePCM) mixed with 0.01% Wt. CuO nanoparticles, with varying fin configurations considering PCM volume and surface area of fins constraint. The shape of the fin is modified from single to multiple numbers, maintaining the same surface area. The analysis is carried out both experimentally and numerically for the without fin case, and the study is extended numerically (utilizing the finite volume method) considering different sizes and positions of the fins. The study evaluates the impact of nanoparticle inclusion, fin geometry variations and the thermal performance of three different types of PCM (lauric acid, RT-35HC and P-58). Numerical results are validated against the in-house experimental results.

The study successfully validates the numerical simulations with experimental data, enhancing the credibility of the findings for real-world applications. The addition of 0.01% Wt. CuO nanoparticles to PCM resulted in a 16.36% enhancement in energy storage, as observed experimentally, whereas the numerical simulation showed an 8.55% increase. The inclusion of CuO nanoparticles accelerated the melting process across all fin configurations, with a notable enhancement parameter of 16.51% for the single fin arrangement. The introduction of a single fin structure increased the energy storage rate, but further additions of fins led to diminishing returns, with a maximum energy storage rate of 35.19 J/min achieved with CuO-enhanced PCM in the presence of single fin. The study also highlights RT-35HC as the most effective PCM, offering the highest energy storage and fastest melting speed, making it ideal for rapid thermal response applications.

Future research could explore different types and concentrations of nanoparticles as well as a broader range of fin geometries and materials to further enhance the performance of PCM-based energy storage systems. Long-term experimental validation under real-world conditions would also enhance the applicability and reliability of the findings.

This study provides valuable insights into optimizing thermal energy storage systems by combining nanoparticle enhancement and fin geometry optimization. The results offer practical guidance for improving the efficiency and effectiveness of PCM-based energy storage units in various applications.

Mathematical and numerical models are developed to study the melting of a Phase Change Material (PCM) inside a 2D cavity. The bottom of the cell is heated at constant and uniform temperature or heat flux, assuming that the rest of the cavity is completely adiabatic. The paper used suitable numerical methods to follow the interface temporal evolution with a good accuracy. The purpose of this paper is to show how the evolution of the latent energy absorbed to melt the PCM depends on the temperature imposed on the lower wall of the cavity.

The problem is written with non-homogeneous boundary conditions. Momentum and energy equations are numerically solved in space by a spectral collocation method especially oriented to this situation. A Crank-Nicolson scheme permits the resolution in time.

The results clearly show the evolution of multicellular regime during the process of fusion and the kinetics of phase change depends on the boundary condition imposed on the bottom cell wall. Thus the charge and discharge processes in energy storage cells can be controlled by varying the temperature in the cell PCM. Substantial modifications of the thermal convective heat and mass transfer are highlighted during the transient regime. This model is particularly suitable to follow with a good accuracy the evolution of the solid/liquid interface in the process of storage/release energy.

The time-dependent physical properties that induce non-linear coupled unsteady terms in Navier-Stokes and energy equations are not taken into account in the present model. The present model is actually extended to these coupled situations. This problem requires smoother geometries. One can try to palliate this disadvantage by constructing smoother approximations of non-smooth geometries. The augmentation of polynomials developments orders increases strongly the computing time. When the external heat flux or temperature imposed at the PCM is much greater than the temperature of the PCM fusion, one must choose carefully some data to assume the algorithms convergence.

Among the areas where this work can be used, are: buildings where the PCM are used in insulation and passive cooling; thermal energy storage, the PCM stores energy by changing phase, solid to liquid (fusion); cooling and transport of foodstuffs or pharmaceutical or medical sensitive products, the PCM is used in the food industry, pharmaceutical and medical, to minimize temperature variations of food, drug or sensitive materials; and the textile industry, PCM materials in the textile industry are used in microcapsules placed inside textile fibres. The PCM intervene to regulate heat transfer between the body and the outside.

The paper's originality is reflected in the precision of its results, due to the use of a high-accuracy numerical approximation based on collocation spectral methods, and the choice of Chebyshev polynomials basis in both axial and radial directions.

The purpose of this study is to analyze heat transfer for solid–liquid phase change in two inclined cavities assisted with open cell and closed cell porous structures for enhancement of heat transfer and compare them.

The heat transfer analysis is done numerically. The set of conservation equations for mass, momentum and energy for phase change material (PCM) and conduction heat transfer equation for metal frame are solved. Furthermore, temperature and solid–liquid fraction distributions for a cavity filled only with PCM are also obtained for comparison. The porosity is 0.9 for both porous structures. Rayleigh number and inclination angle change from 1 to 10⁸, and from −90° to 90°, respectively.

The present study reveals that the use of closed cell structures not only can make phase change faster than open cell structure (except for Ra = 10⁸ and = 90°) but also provide more stable process. The use of a closed cell porous structure in a cavity with PCM can reduce melting period up to 55% more than a cavity with an open cell porous structure. The rate of this additional enhancement depends on Rayleigh number and inclination angle.

To the best of the authors’ knowledge, this is the first time that the comparison between closed cell and open cell porous structures for heat transfer enhancement in a solid/liquid phase change process is reported. Authors believe that the present study will lead more attentions on the use of closed cell porous structures.

The purpose of this paper is to demonstrate how anomalous diffusion behaviors can be manifest in physically realizable phase change systems.

In the presence of heterogeneity the exponent in the diffusion time scale can become anomalous, exhibiting values that differ from the expected value of 1/2. Here the author investigates, through directed numerical simulation, the two-dimensional melting of a phase change material (PCM) contained in a pattern of cavities separated by a non-PCM matrix. Under normal circumstances we would expect that the progress of melting F(t) would exhibit the normal diffusion time exponent, i.e., F∼t1/2. The author’s intention is to investigate what features of the PCM cavity pattern might induce anomalous phase change, where the progress of melting has a time exponent different from n=1/2.

When the PCM cavity pattern has an internal length scale, i.e., when there is a sub-domain pattern which, when reproduced, gives us the full domain pattern, the direct simulation recovers the normal ∼t1/2 phase change behavior. When, however, there is no internal length scale, e.g., the pattern is a truncated fractal, an anomalous super diffusive behavior results with melting going as t n; n > 1/2. By studying a range of related fractal patterns, the author is able to relate the observed sub-diffusive exponent to the cavity pattern’s fractal dimension. The author also shows, how the observed behavior can be modeled with a non-local fractional diffusion treatment and how sub-diffusion phase change behavior (F∼t n; n < 1/2) results when the phase change nature of the materials in the cavity and matrix are inverted.

Although the results clearly demonstrate under what circumstances anomalous phase change behavior can be practically produced, the question of an exact theoretical relationship between the cavity pattern geometry and the observed anomalous time exponent is not known.

The clear role of the influence of heterogeneity on heat flow behavior is illustrated. Suggesting that modeling heat and fluid flow in heterogeneous systems requires careful consideration.

The novel direct simulation of melting in a two-dimensional PCM cavity pattern provides a clear illustration of anomalous behavior in a classic heat and fluid flow system and by extension provides motivation to continue the numerical investigation of anomalous and non-local behaviors and fractional calculus tools.

The purpose of this paper is to analyze the performance of a data center and thermal management by using phase change material (PCM). Numerical studies were conducted for two dimensional model of data center and installation of PCM at different locations.

Finite volume method was used for the unsteady problem, while impacts of air velocity and PCM location on the flow field, thermal pattern variations and phase change dynamics were evaluated. Three different locations of the PCM were considered while air velocity was also varied during the simulation. Thermal field variations and cooling performance of the system for different PCM location scenarios were compared.

It was observed that the installation of the PCM has significant impacts on the vortex formation, thermal field variation within the system and its performance. The left, right and top wall installation of the PCM changed the thermal patterns near the heat cell of the data centre. The phase change process is fast for the upper wall installation of the PCM, while the discrepancy of the melt fraction dynamics between different air flow at this position is minimum. The case where PCM placed in the upper wall at the highest air velocity is the best configuration in terms of heat storage. The utilization of PCM and changing its locations provide an excellent tool for thermal management and cooling performance of data centre.

Results of this study can be used for initial design and optimization of cooling systems for thermal management of data centers while the importance of the high-performance computing becomes very crucial for the advanced simulations in different technological applications.

The purpose of this paper is to study thermal performance of metal foam/phase change materials composite under the influence of the enclosure aspect ratios (ratio of enclosure height: length). In this study, a compound metal foam/phase change material (PCM), which has been proved to be one of the most promising approaches for thermal conductivity promotion on PCMs, was used.

The PCM is considered initially at its melting temperature. The enclosure for all the cases has a constant volume with various aspect ratios. The left side of the enclosure is suddenly exposed to a thermal source having a constant heat flux, while the other three surfaces are kept thermally insulated. A two-dimensional numerical model considering the non-equilibrium thermal factor, non-Darcy effect and local natural convection was proposed. The coupling between velocity and pressure is solved using the SIMPLEC, and the Rhie and Chow interpolation is used to avoid the checker-board solutions for the pressure.

The effects of foam porosity and aspect ratio of the enclosure on the PCM’s melting time were investigated. The results indicated that enclosure aspect ratio plays a fundamental role in phase change of copper foam/PCM composites. For higher porosities, enclosures with bigger aspect ratios proved to led to optimal melting time. Besides, the best enclosure aspect ratio and foam porosity for a fixed-volume enclosure to have the shortest melting time are 2.1 and 91.66 per cent, respectively. However, for a specific amount of PCM inside a variable volume enclosure, the optimal melting time was for foam with ε = 95 per cent. The achieved results prove the great importance of selection of aspect ratio to benefit both conduction and convection heat transfer simultaneously.

The area of energy storage systems is original.

Phase change energy storage is an important solution for overcoming human energy crisis. This study aims to present an evaluation for the thermal performances of a phase change material (PCM) and a PCM–metal foam composite. Effects of pore size, pore density, thermal conductivity of solid structure and mushy region on the thermal storage process are examined.

In this paper, temperature, flow field and solid–liquid interface of a PCM with or without porous media were theoretically assessed. The influences of basic parameters on the melting process were analyzed. A PCM thermal storage device with a metal foam composite is designed and a thermodynamic analysis for it is conducted. The optimal PCM temperature and the optimal HTF temperature in the metal foam-enhanced thermal storage device are derived.

The results show that the solid–liquid interface of pure PCM is a line area and that of the mixture PCM is a mushy area. The natural convection in the melting liquid is intensive for a PCM without porous medium. The porous medium weakens the natural convection and makes the temperature field, flow field and solid–liquid interface distribution more homogeneous. The metal foam can greatly improve the heat storage rate of a PCM.

Thermal storage rate of a PCM is compared with that of a PCM–metal foam composite. A thermal analysis is performed on the multi-layered parallel-plate thermal storage device with a PCM embedded in a highly conductive porous medium, and an optimal melting temperature is obtained with the exergy optimization. The heat transfer enhancement with metal foams proved to be necessary for the thermal storage application.

The purpose of this study is to examine the effects of inclination angle on the thermal energy storage capability of a phase change material (PCM) within a disc-shaped container. Different container materials are also tested such as plexiglass and aluminium. This study aims to assess the energy storage capacity, melting behaviour and temperature distributions of PCM with a specific melting range (22°C–26°C) for various governing parameters such as inclination angles, aspect ratios (AR) and temperature differences (ΔT) and compare the melting behaviour and energy storage performance of PCM in aluminium containers to those in plexiglass containers.

A finite volume approach was adopted to evaluate the thermal energy storage capability of PCMs. Five inclination angles ranging from 0° to 180° were considered and the energy storage capacity. Also, the melting behaviour of the PCM and temperature distributions of the container with different materials were tested. Two different AR and ΔT values were chosen as parameters to analyse for their effects on the melting performance of the PCM. Conjugate heat transfer problem is solved to see the effects of conduction mode of heat transfer.

The results of the study indicate that as AR decreases, the effect of the inclination angles on the energy storage capacity of the PCM decreases. For lower ΔT, the difference between the maximum and minimum stored energies was 20.88% for AR = 0.20, whereas it was 6.85% for AR = 0.15. Furthermore, under the same conditions, the PCM stored 8.02% more energy in plexiglass containers than in aluminium containers.

This study contributes to the understanding of the influence of inclination angle, container material, AR and ΔT on the thermal energy storage capabilities of PCM in a novel designed container. The findings highlight the importance of AR in mitigating the effect of the inclination angle on energy storage capacity. Additionally, comparing aluminium and plexiglass containers provides insights into the effect of container material on the melting behaviour and energy storage properties of PCM.

This study aims to explore the infrared imaging effect of fabrics coated with phase change material microcapsules (PCM-MCs), which are prepared by the initiation of ultraviolet (UV) light.

PCM-MCs were prepared by UV polymerization using paraffin (PA) as core material, polymethyl methacrylate as wall material and ferric chloride as photoinitiator. The effects of emulsifier dosage and emulsification temperature on the properties of PA emulsion were investigated. Scanning electron microscopy, particle size analysis, infrared spectroscopy, differential scanning calorimetry and infrared imaging test were used to characterize the properties of microcapsules.

The PCM-MCs with good morphology and particle size were prepared with 25 cm of the distance between light source and the liquid. The average particle size was 1.066 µm and the latent heat of phase transition was 19.96 J/g. After 100 accelerated thermal cycles, the latent heat only decreased by 1.8%. It had good heat storage stability and thermal stability. The fabric coated by the microcapsules exhibited a variable temperature hysteresis effect when placed in the sun, and presented a color close to the infrared images of the human palm under the external environment temperature close to the human body temperature.

The PCM-MCs prepared based on UV light initiation showed good thermal properties and its coated fabrics had an infrared decoy effect below the temperature of the human body.

This study explored the application of microcapsules in textiles.

The microcapsules had a certain application potential in infrared decoy effect.

This paper aims to study the synergistic effect of graphene sponge on the thermal properties and shape stability of composite phase change material (PCM).

Graphene oxide sponge is first prepared from an aqueous solution of graphene oxide by freeze-drying method. The oxidized graphene sponge is reduced by hydrazine hydrate. Finally, use vacuum impregnation method to introduce paraffin into graphene sponge to prepare composite PCM.

Graphene sponge is used to improve the shape stability of paraffin wax and improves the thermal conductivity and latent heat of the composite PCM. The thermal conductivity increases by 200 per cent and the composite PCM has excellent reliability in 100 melt-freezing cycles.

A simple way for fabricating composite PCM with high thermal conductivity and latent heat which has the potential to be used as thermal storage materials without container encapsulation has been developed by using graphene sponge and paraffin.

The materials and preparation methods with special structure and properties in this paper provide a new idea for the research of PCM, which can be widely used in the fields of energy conversion and storage.