Search results

The purpose of this paper is to generate nitrogen-containing groups in the cotton fabric surface via low-temperature nitrogen plasma as an eco-friendly physical/zero-effluent process. This was done for rendering cotton dye-able with Acid Blue 284, which in fact does not have any direct affinity to fix on it.

Dyeing characteristics of the samples such as color strength (K/S), fastness properties to light, rubbing and perspiration and durability, as well as tensile strength, elongation at break, whiteness, weight loss and wettability in addition to zeta potential of the dyed samples, were determined and compared with untreated fabric. Confirmation and characterization of the plasma-treated samples via chemical modifications and zeta potential was also studied using Fourier transform infrared spectroscopy (FTIR) and Malvern Zetasizer instrumental analysis.

The obtained results of the plasma-treated fabric reflect the following findings: FTIR results indicate the formation of nitrogen-containing groups on cotton fabrics; notable enhancement in the fabric wettability, zeta potential to more positive values and improvement in the dyeability and overall fastness properties of treated cotton fabrics in comparison with untreated fabric; the tensile strength, elongation at break, whiteness and weight % of the plasma treated fabrics are lower than that untreated one; and the durability of the plasma treated fabric decreased with increasing the number of washing cycles.

The novelty addressed here is rendering cotton fabrics dye-able with acid dye via the creation of new cationic nitrogen-containing groups on their surface via nitrogen plasma treatment as an eco-friendly and efficient tool with a physical/zero-effluent process.

The incompatibility of natural fibers with polymer matrices is one of the key obstacles restricting their use in polymer composites. The interfacial connection between the fibers and the matrix was weak resulting in a lack of mechanical properties in the composites. Chemical treatments are often used to change the surface features of plant fibers, yet these treatments have significant drawbacks such as using substantial amounts of liquid and chemicals. Plasma modification has recently become very popular as a viable option as it is easy, dry, ecologically friendly, time-saving and reduces energy consumption. This paper aims to explore plasma treatment for improving the surface adhesion characteristics of sisal fibers (SFs) without compromising the mechanical attributes of the fiber.

A cold glow discharge plasma (CGDP) modification using N₂ gas at varied power densities of 80 W and 120 W for 0.5 h was conducted to improve the surface morphology and interfacial compatibility of SF. The mechanical characteristics of unmodified and CGDP-modified SF-reinforced epoxy composite (SFREC) were examined as per the American Society for Testing and Materials standards.

The cold glow discharge nitrogen plasma treatment of SF at 120 W (30 min) enhanced the SFREC by nearly 122.75% superior interlaminar shear strength, 71.09% greater flexural strength, 84.22% higher tensile strength and 109.74% higher elongation. The combination of improved surface roughness and more effective lignocellulosic exposure has been responsible for the increase in the mechanical characteristics of treated composites. The development of hydrophobicity in the SF had been induced by CGDP N₂ modification and enhanced the size of crystals and crystalline structure by removing some unwanted constituents of the SF and etching the smooth lignin-rich surface layer of the SF particularly revealed via FTIR and XRD.

Chemical and physical treatments have been identified as the most efficient ways of treating the fiber surface. However, the huge amounts of liquids and chemicals needed in chemical methods and their exorbitant performance in terms of energy expenditure have limited their applicability in the past decades. The use of appropriate cohesion in addition to stimulating the biopolymer texture without changing its bulk polymer properties leads to the formation and establishment of plasma surface treatments that offer a unified, repeatable, cost-effective and environmentally benign replacement.

The authors are sure that this technology will be adopted by the polymer industry, aerospace, automotive and related sectors in the future.

The wool scales present on the fibre surface give rise to certain unwanted effects in textile wet processing, for example, felting and poor wettability. In the past, the removal of scale was done either through physical/chemical degradation of the scales or by deposition of polymer on the scales. In modern treatments, a combination of both methods are usually carried out. Because the deposition of polymer on the fibre surface depends greatly on the surface characteristics of the fibre, therefore, the surface properties of modified fibres are important factors for polymer application. On the other hand, the modified surface may also result in improved wettability of the fibre. The present paper investigated the surface physico-chemical properties of wool fibres subjected to different surface modification treatments.

In this paper, Soxhlet extracted (dichloromethane extracted) wool fibres (21 J..lm diameter) were modified by potassium permanganate / salt treatment, sodium metabisulphite treatment and plasma treatments (oxygen, nitrogen, 25% hydrogen and 750% nitrogen gas mixture). The study of wool fibre surface physico-chemical properties included contact angle measurement with different solvents, critical surface tension, surface free energy and saturated adsorption value. Experimental analysis showed that these properties were imQroved after the surface modification treatments, and the results were calculated quantitatively and discussed.

This review deals with the pros and cons of ultraviolet (UV) radiation on human beings and the role of textile clothing and the chemicals used for textiles to protect from their harmful effects.

UV radiation (UVR) which has further divided into UVA, UVB, and UVC. Almost 100% of UVC and major portion of UVB are bounced back to stratosphere by ozone layer while UVA enters the earth atmosphere. Excessive exposure of solar or artificial UVR exhibit potential risks to human health. UVR is a major carcinogen and excessive exposure of solar radiation in sunlight can cause cancer in the lip, skin squamous cell, basal cell and cutaneous melanoma, particularly in people with the fair skin.

This article aims to provide a comprehensive overview of the harmful effects of UVR on human skin, factors affecting UV irradiance and factors affecting UV protection offered by textile clothing.

Effect of fiber properties, yarn properties, fabric construction, fabric treatments and laundering has been reviewed along with the identification of gaps in the reported research. A comparison of inorganic and organic UV absorbers has also been given along with different testing and evaluation methods for UV protective clothing.

Silicon-containing groups were introduced into fluoroacrylate polymer to further improve the comprehensive performance of pressure-sensitive adhesive (PSA) for expanded polytetrafluoroethylene (ePTFE) bonding.

A series of silicon-containing fluorinated acrylic copolymers were synthesized through free radical solution polymerization with vinyloxy trimethylsilane, allyltrimethylsilane, 3-(trimethoxysilyl)propyl methacrylate or 1,3,5-tris(3,3,3-trifluoropropyl) methylcyclotrisiloxane as silicon monomers, and comprehensive performance of the copolymers was evaluated based on Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), gel permeation chromatography, glass transition temperatures (T_g), differential scanning calorimetry, thermogravimetric analysis, water contact angle, the track, 180° peel strength, and shear holding power.

Based on the FTIR and XPS results, it is confirmed that the silicon monomers were successfully introduced into the fluorinated acrylate copolymer. XPS analysis indicated that the silicon groups had the tendency to enrich on the surface of the film, thereby reducing the F content on the film surface. The glass transition temperatures (T_g) of the PSAs increased when silicon monomers were introduced, while the thermal stability declined. The contact angles of the acrylic PSA films were increased with the introduction of silicon monomers. From the perspective of bonding performance, the track, 180° peel strength and shear holding power decreased to varying degrees compared to silicon-free PSA, except significantly elevated holding power with MPS as the silicon monomer.

Silicon-containing fluorinated acrylic copolymers were synthesized, and the comprehensive performance was evaluated as PSAs of ePTFE for the first time.

Previous studies showed that the feltability and wettability of wool fabrics were improved after the application of plasma treatment. In the present paper, further study on the plasma treatment was carried out to investigate its effect on other fabric properties including (i) performance properties (tearing strength, tensile strength and elongation), (ii) aesthetic properties (pilling resistance and crease recovery) and (iii) comfort properties (air permeability, wettability and antistatic).

Pure wool 2/1 twill fabrics were treated by plasma using three non-polymerising gases namely oxygen, nitrogen and 25% hydrogen / 75% nitrogen gas mixture. The operation conditions, i.e. power, pressure and treatment duration, were the same for all plasma treatments. Different tests were conducted to investigate the effect of plasma treatment on the properties of treated fabrics.

The results of experiments showed that plasma treatment did give different degrees of influence on the properties of wool fabric. In addition, the effectiveness of different gases plasma treatment was compared of which the gas mixture plasma gave the best modification effect.

The purpose of this study is to check the effectivity of plasma in the natural dyeing of polyester fabric using four natural dyes – Turkey red, Lac, Turmeric and Catechu using plasma and alum mordant. The surface modification on the polyester fabric by plasma along with the use of benign mordant alum is studied. The enhancement of dyeability in polyester fabric with natural dyes is the main focus. Due to surface modification, the wettability increases, which leads to better dye uptake. Better dye uptake and better dye adherence are the main objectives.

Plasma-mediated natural dyeing is the main design of this research work. The effect of plasma treatment on surface modification of synthetic fabric polyester and its subsequent effects on their dyeing with different natural dyes, namely, Turkey red, Lac, Turmeric and Catechu are studied. The dyeability was further enhanced by the use of alum as mordant. The main focus is on the betterment of natural dyeing of polyester fabric using sustainable natural dyes resources for dyeing and to reduce wastewater contamination from the usage of toxic additive chemicals for cleaner production.

Plasma-mediated and alum-mordanted dyeing method facilitated very good dyeability of all the four natural dyes, namely, Turkey red, Lac, Turmeric and Catechu. Color strength (K/S) values and fastness properties of plasma-treated samples were far better than untreated samples. The synergistic effect of plasma and alum mordanting has made natural dyeing of polyester very easy with very good fastness results. Natural dyeing of polyester after 2 min of plasma treatment showed excellent and desirable results. The process is also easy to be adapted by industries.

As polyester is hydrophobic, natural dyeing of polyester fabric is not very easy, but with plasma-mediated natural dyeing, it becomes a very facile dyeing method; thus, there are no limitations. Use of plasma has reduced the need for any chemical additives which are usually added during the dyeing process.

This process of natural dyeing of polyester fabric can be scaled up to industrial dyeing with natural dyes. Plasma pretreatment of the fabric followed by premordanting with alum has facilitated the natural dyeing well.

Use of plasma in place of chemical modifiers can be a green and environmentally friendly approach for sustainable coloration of polyester fabric, providing a clean wet processing for textiles dyeing.

The synergistic effect of plasma-mediated and alum-mordanted natural dyeing of polyester has not been attempted by any researcher. To the best of the authors’ knowledge, this is for the first time that pretreatment with atmospheric plasma followed by alum mordanting of polyester fabric has shown very good dye uptake and fastness properties as the dye molecules could penetrate well after 2 min of the plasma treatment.

The purpose of this paper is to present the results of a study on friction characteristics of plasma, salt‐bath and gas nitrided layers produced in AISI 304 type austenitic and AISI 420 type martensitic stainless steels.

Plasma nitriding processes were carried out with DC‐pulsed plasma in 80% N₂+20% H₂ atmosphere at 450°C and 520°C for 8 h at a pressure of 2 mbar. Salt‐bath nitriding was performed in a cyanide‐cyanate salt‐bath at 570°C for 1.5 h. Gas nitriding was also conducted in NH₃ and CO₂ atmosphere at 570°C for 13 h. Characterization of all nitrided samples has been carried out by means of microstructure, microhardness, surface roughness measurement and friction coefficient. The morphologies of the worn surfaces of the nitrided samples were also observed using a scanning electron microscope. Friction characteristics of the nitrided samples have been investigated using a ball‐on‐disc friction and wear tester with a WC‐Co ball as the counterface under dry sliding conditions.

The plasma nitrided and salt‐bath nitrided layers on the 420 steel surfaces were much thicker than on the 304 steel surfaces. However, there was no obvious and homogeneous nitrided layer on the gas nitrided samples' surface. The plasma and salt‐bath nitriding techniques significantly increased the surface hardness of the 304 and 420 samples. The highest surface hardness of the 304 nitrided samples was obtained by the plasma nitrided technique at 520°C. On the other hand, the highest surface hardness of the 420 nitrided layers was observed in the 450°C plasma nitrided layer. Experimental friction test results showed that the salt‐bath and 450°C plasma nitrided layers were more effective in reducing the friction coefficient of the 304 and 420 stainless steels, respectively.

The relatively poor hardness and hence wear resistance of austenitic and martensitic stainless steels needs to be improved. Friction characteristic is a key property of performance for various applications of austenitic and martensitic stainless steels. This work has reported a comparison of friction characteristics of austenitic 304 and martensitic 420 stainless steels, modified using plasma, salt‐bath and gas nitriding processes. The paper is of significances for improving friction characteristics, indirectly wear performances, of austenitic and martensitic stainless steels.

The purpose of this study is to select a proper surface treatment to enhance wear resistance of engine camshafts. The camshaft is a relevant part of a diesel engine which works under torsion, fatigue and wear efforts. They are usually manufactured by casting, forging or machining from forged bar of low alloy steels, and in most cases, the machined surfaces are quenched and tempered by induction heating. After that, in many cases, to withstand the efforts imposed on the active surfaces and improve tribology and fatigue properties, the industry used for decades, thermochemical technologies such as salt bath or gaseous nitriding and nitrocarburizing processes.

This paper studied the effects of plasma nitriding and plasma nitrocarburizing, on the tribological behaviour of the steel SAE 1045HM3 proposed to produce camshafts. After the plasma treatments, the change in surface roughness was measured; the modified layers were studied by X-ray techniques and its thickness by optical microscopy. The diffusion zone was evaluated by Vickers microhardness determinations. Tribology tests were performed by pin-on-disc configuration using WC ball as a counterpart.

Results show that plasma nitrided samples present the best tribological behaviour compared with the nitrocarburized ones; also, the influence of the roughness produced by the thermochemical processes appears to be important.

Although both the plasma treatments have been applied for many years, and also reported separately in the scientific literature, there was no information comparing these two treatments for carbon steels, and also, there is not much about tribology in lubricated conditions of nitrided and nitrocarburized carbon steels. In fact, it is not proved that the porosity of the nitrocarburized layer is beneficial for wear resistance in lubricated conditions. In this paper, it was proved that at least in the tested conditions, it is not.

Gas or plasma nitrocarburizing is usually recommended for this kind of applications, although the modified layer is porous. This paper attempts to prove that nitriding could be better than nitrocarburizing, even with a thinner white layer.

The purpose of this paper is to evaluate the effect of nitrogen and air atmospheres on the solderability testing of plasma‐treated hot air solder level (HASL) finish printed circuit boards (PCBs).

In this paper, the soldering performance of plasma‐treated HASL finish PCBs in nitrogen and air atmospheres have been evaluated using the wetting balance technique. The results were compared with the performance of conventionally flux‐treated samples soldered in air and nitrogen atmospheres and non‐flux treated samples soldered in air. Auger chemical analysis results were also compared with the solderability test results in order to obtain a complete profile of the plasma‐treated and non‐treated surfaces.

The results of the auger chemical analysis show high organic (carbon) levels in the control samples and a significant drop in organic levels in the plasma‐treated samples. The significant drop in the level of carbon leads to a decrease in contact angle and an increase in both surface energy and solder wettability. The results indicate that plasma cleaning of PCBs prior to soldering is a viable alternative to the conventional use of flux.

The paper indicates that the soldering performance of plasma‐treated PCBs in air and nitrogen atmosphere are comparable. The findings give the motivation for the use of plasma‐assisted dry cleaning for fluxless soldering.