Manal El-Zawahry and Hager Gamal
This paper aims to focus on the aqueous extraction of natural dye from haematoxylum campechianum L. bark for finishing the bio-mordant cotton fabrics producing value-added…
Abstract
Purpose
This paper aims to focus on the aqueous extraction of natural dye from haematoxylum campechianum L. bark for finishing the bio-mordant cotton fabrics producing value-added, environment-friendly textile products, for biomedical applications.
Design/methodology/approach
The study focuses on the creation of eco-friendly bio-mordant cotton fabric using gallic acid and gelatin, Al3+ and Fe2+ salts and metal mordant. The optimal pH for extraction, structural characterization and phytochemical analysis of the extracted dye were estimated using UV-visible spectrophotometer, FTIR and qualitative analysis. Variations in electrolyte concentration and pH medium were also considered. The study also examines build-up properties, colorimetric values and fastness characteristics of the colored fabrics.
Findings
All the dyed fabrics exhibit very good to excellent in terms of antimicrobial resistance against S. aureus and C. allbicans.
Practical implications
Pre-mordant cotton fabrics with Fe2+ and a combination of metal and bio-mordant show higher antibacterial resistance against P. aerugionsa. Further, bio-mordant and a combination of both mordant exhibit excellent UV protection and antioxidant activity performance compared to that of undyed fabrics.
Originality/value
This work opens up a huge potential for producing healthy bioactive-colored fabrics used in medical textiles and other usages.
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Fatma Abdelghaffar, Rehab A. Abdelghaffar, Safia A. Mahmoud and Badria M. Youssef
This paper aims to improve the adsorption capacity of sugarcane bagasse (SCB) as a low-cost, attractive and effective adsorbent for dye removal from wastewater.
Abstract
Purpose
This paper aims to improve the adsorption capacity of sugarcane bagasse (SCB) as a low-cost, attractive and effective adsorbent for dye removal from wastewater.
Design/methodology/approach
SCB is a cellulosic material; it was chemically modified with compounds containing cationic groups. The adsorption efficiency of unmodified and modified SCB was investigated with anionic dyes by studying various factors that affect modified SCB and adsorption.
Findings
X-ray diffraction, FT-IR spectra and nitrogen content were used to confirm the effect of existence of quaternary ammonium groups on modified SCB. The morphological structure of the modified and unmodified SCB has been demonstrated using electronic scanning microscopy.
Research limitations/implications
The modified SCB was chemically treated by Quat 188, which is commercially available in the solution of 3-chloro-2-hydroxypropyltrimethyl ammonium chloride.
Practical implications
Grafting cationic function groups on the surface of sugarcane by cationization treatment enhances its adsorption efficiency for anionic dyes.
Originality/value
The main value of this research was indicating a clear difference in the appearance of unmodified and modified SCB surfaces. Furthermore, it can be determined that the modified SCB absorbs more of the dyes.
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H.Z. Shams, Y.A. Youssef, F.A. Mohamed, M.M. El‐Zawahry, M.H. Helal and E.A. El‐Kharadly
The purpose of this paper is to evaluate the efficiency of modifying reactive azo dyes using pyrazolo[1,2‐a]pyrazole fused systems as the chromophoric moiety which could satisfy…
Abstract
Purpose
The purpose of this paper is to evaluate the efficiency of modifying reactive azo dyes using pyrazolo[1,2‐a]pyrazole fused systems as the chromophoric moiety which could satisfy many and varied criteria drawn from economic, synthetic, physicochemical and fastness properties.
Design/methodology/approach
Six novel heterocyclic disazo reactive dyes were prepared, containing monofunctional sulphatoethylsulphone (SES) and hetero‐bifunctional monochlorotriazine (MCT)/SES reactive groups. Dyes intermediates based on 4‐arylazo‐1,5‐dioxopyrazolo[1,2‐a]pyrazole chromophoric moieties are initially synthesised and coupled with two different diazonium salts having the aforementioned reactive groups, thus yielding the new target reactive dyes. The synthesised dyes are applied to cotton, wool and silk fabrics under the typical exhaust dyeing conditions and their dyeing properties were investigated.
Findings
The results assessed for dyeing indicate high‐quality dyeing properties. However, the heterobifunctional MCT/SES dyes showed higher exhaustion and fixation values, colour yields and fastness properties than those of the monofunctional SES dyes.
Research limitations/implications
The method developed provided a simple and practical procedure for producing fused pyrazolo[1,2‐a]pyrazole disazo chromophoric systems that afford valuable reactive dyes. In addition, the dyes intermediates based on 4‐arylazo‐1,5‐dioxopyrazolo[1,2‐a]pyrazole as well as their disazo counterparts could be applied as acid dyes to wool and silk.
Originality/value
The method for producing novel disazo reactive dyes could find numerous applications for affording a variety of reactive dyes with different binding linkages and structural reactivity. These could be valuable as reactive dyes with different colour shades.
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M.M. El-Zawahry, H. M. Helmy and A. Abou-Okeil
Enzymatic treatment of jute fabrics with neutral cellulase enzymes is investigated systematically. The factors affecting enzymatic treatment including, time, liquor ratio…
Abstract
Enzymatic treatment of jute fabrics with neutral cellulase enzymes is investigated systematically. The factors affecting enzymatic treatment including, time, liquor ratio, temperature and enzyme concentration are also examined. The hydrolyzed pretreated surfaces of jute fabrics were characterized by scanning electron microscope (SEM), weight loss (WL) and wettability (Wet) tests. WL% and Wet were found to increase as the time, temperature and cellulase concentration increased. SEM images showed that the surface of the treated fabrics was smoother and more polished than that of the untreated fabrics after being subject to optimal treatment conditions.
In contrast, rough surface, fibrillation, surface pilling and multicellular were observed in the images of the untreated fabrics. The dyeing behavior of both untreated and enzymatically treated jute fabrics with reactive dyes was also evaluated under different dyebath conditions. The measured exhaustion and fixation percent showed a significant enhancement of the dyeability of biopolished pretreated fabrics compared to untreated fabrics. The results of fastness properties also indicate good washing, perspiration and rubbing fastness.
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L.K. El-Gabry and M.M. El-Zawahry
Nylon 6 fabric is pretreated with tannic acid and subsequently dyed with a cationic dye, Rhodamine B, from an aqueous dye solution and emulsion phase. The emulsion phase of…
Abstract
Nylon 6 fabric is pretreated with tannic acid and subsequently dyed with a cationic dye, Rhodamine B, from an aqueous dye solution and emulsion phase. The emulsion phase of n-hexadecane is emulsified by isopropyl alcohol and stabilized by Rhodamine B/tannic acid complex. Different factors affecting pretreatment and dyeing process have been studied. Changes of moisture regain, tensile strength, elongation and binding stiffness of the pretreated fabric are investigated.
The FTIR spectra of tannic acid pretreatment of nylon are also examined. The pretreated fabric with 10% owf tannic acid shows a slight increase in the tensile strength and elongation percentage. A higher moisture regain and binding stiffness are observed with increases in the amount of tannic acid. The results also indicate that the pretreatment for cationic dyed nylon 6 fabrics with tannic acid promote a higher dye uptake and cationic dye-based emulsion system with better fastness properties relative to those of the dye solution based system. A further improvement in wet fastness is secured by an aftertreatment of all dyed fabrics with a commercial anionic fluorescent whitening agent, Uvitex® RSB 150%.
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Shimaa S.M. Elhadad, Hany Kafafy, Hamada Mashaly and Ahmed Ali El-Sayed
The purpose of this study is to use liposome technology in the treatment of fabrics textiles because of its efficient energy saving, reducing time and temperature.
Abstract
Purpose
The purpose of this study is to use liposome technology in the treatment of fabrics textiles because of its efficient energy saving, reducing time and temperature.
Design/methodology/approach
The newly prepared lecithin liposome was used to encapsulate dyes for the purpose of increasing dyeing affinity. Different ratios of commercially available lecithin liposomes (1%, 3%, 5% and 7%) were used simultaneously in the dyeing of cotton and wool fabrics. The treated fabrics (cotton and wool fabrics) were confirmed using different analytical procedures such as scanning electron microscope (SEM), Fourier-transition infrared spectroscopy, ultraviolet protection factor, colour strength (K|S) measurements and fastness measurements.
Findings
The results show that increasing liposome ratios in dyeing baths leads to increased dyeing affinity for cotton and wool fabrics compared with conventional dyeing without using liposomes. In addition to that, the colour strength values, infrared spectra, SEM and fastness properties of non-liposome-dyed fabrics and liposome-dyed fabrics were investigated.
Originality/value
The research paper provides broad spectrum of green encapsulation fabrics using liposome technology to perform the dye stability, dye strength and fastness.
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Khaled Mostafa, Heba Ameen and Ahmed Medhat
The purpose of this paper is to generate nitrogen-containing groups in the cotton fabric surface via low-temperature nitrogen plasma as an eco-friendly physical/zero-effluent…
Abstract
Purpose
The purpose of this paper is to generate nitrogen-containing groups in the cotton fabric surface via low-temperature nitrogen plasma as an eco-friendly physical/zero-effluent process. This was done for rendering cotton dye-able with Acid Blue 284, which in fact does not have any direct affinity to fix on it.
Design/methodology/approach
Dyeing characteristics of the samples such as color strength (K/S), fastness properties to light, rubbing and perspiration and durability, as well as tensile strength, elongation at break, whiteness, weight loss and wettability in addition to zeta potential of the dyed samples, were determined and compared with untreated fabric. Confirmation and characterization of the plasma-treated samples via chemical modifications and zeta potential was also studied using Fourier transform infrared spectroscopy (FTIR) and Malvern Zetasizer instrumental analysis.
Findings
The obtained results of the plasma-treated fabric reflect the following findings: FTIR results indicate the formation of nitrogen-containing groups on cotton fabrics; notable enhancement in the fabric wettability, zeta potential to more positive values and improvement in the dyeability and overall fastness properties of treated cotton fabrics in comparison with untreated fabric; the tensile strength, elongation at break, whiteness and weight % of the plasma treated fabrics are lower than that untreated one; and the durability of the plasma treated fabric decreased with increasing the number of washing cycles.
Originality/value
The novelty addressed here is rendering cotton fabrics dye-able with acid dye via the creation of new cationic nitrogen-containing groups on their surface via nitrogen plasma treatment as an eco-friendly and efficient tool with a physical/zero-effluent process.
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Lamiaa Kamal El-Gabry, Mohamed Fathy Nasr and Amira Adel Abou El-Kheir
This work aims to increase the dyeability of nylon 6 with basic dyeing through the treatment of the fibre with available and cheap nanomaterials, namely; nano bentonite using an…
Abstract
Purpose
This work aims to increase the dyeability of nylon 6 with basic dyeing through the treatment of the fibre with available and cheap nanomaterials, namely; nano bentonite using an economic and simple method.
Design/methodology/approach
Different amounts of nano clay, namely, nano bentonite were dispersed in distilled water using an ultrasonic homogenizer for 1 h. Nylon fabrics were treated with different concentrations of dispersed nano bentonite (1%, 2%, 3%, 4%, 5% wt/v). After half an hour, the samples were padded using SVETEMA laboratory padding system. The padding pressure was adjusted at 3 bar to allow a pickup of 100%. The padded samples were dried at 80°C for 5 min and cured at 160°C for 3 min using ROACHES laboratory thermos-fixation. The cured samples were then washed with running water and left to dry at room temperature.
Findings
The obtained results indicated that the modification of polyamide 6 fibres with nano bentonite had a great impact on their dyeing properties. The obtained shades, absorption behaviour and fastness properties were significantly enhanced. Based on these results, it was concluded that polyamide fabrics could be successfully dyed with basic dyes using economical dyeing conditions.
Originality/value
This paper introduces a new method the loaded the nano-clay on the synthetic fibres, which are nylon 6 to enhance the dyeability with cationic dyes using the physical method without changing the structure of the fibres.
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Fatma Mohamed and Y.A. Youssef
The purpose of this paper is to synthesise, characterise and find out properties of some new bifunctional reactive azo dyes using pyrazolo[1,2‐a]pyrazole 3‐carboxylic acid fused…
Abstract
Purpose
The purpose of this paper is to synthesise, characterise and find out properties of some new bifunctional reactive azo dyes using pyrazolo[1,2‐a]pyrazole 3‐carboxylic acid fused systems as the chromophoric moiety, bearing good colour strength, lightfastness, and other favourable properties.
Design/methodology/approach
The dyes are synthesised by diazotisation, coupling and cyclisation reactions. Firstly, synthesised 4‐arylazo‐1,5‐dioxopyrazolo[1,2‐a]pyrazole 3‐carboxylic acid chromophoric moieties and coupled with diazonium salts having the aforementioned reactive groups, thus yielding the new target reactive. The synthesised dyes were applied to cotton and wool fabrics under the typical exhaust dyeing conditions and their dyeing properties were investigated. The structures of these dyes are characterised and confirmed by melting point, elemental analysis, infrared, ultraviolet‐visible spectroscopy (UV/VIS) and nuclear magnetic resonance (1H‐NMR) data.
Findings
The wavelength of maximum absorptions, molar extinction coefficients are strongly dependent on the electron donating ability of the substituents on the coupling moiety. The absorption bands of these dyes move towards longer wavelength as the polarity of the solvents and electron density of substituents on the coupling moiety increase. The dyes applied on cotton and wool showed higher exhaustion and fixation values, colour yields and fastness properties.
Research limitations/implications
The method developed provided a simple producing fused pyrazolo[1,2‐a]pyrazole disazo chromophoric systems based on 4‐arylazo‐1,5‐dioxopyrazolo[1,2‐a]pyrazole 3‐carboxylic acid as well as reactive dyes applied on wool and cotton dyes.
Originality/value
In this paper, three series of pyrazolo[1,2‐a]pyrazole derivatives dyes are synthesised and characterised. They have not been registered in the literature previously.
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Fatma A. Mohamed, Saadia A. Abd El-Megied, Mahmoud S. Bashandy and Hassan M. Ibrahim
This study aims to synthesise and characterise new reactive dyes based on thiazole derivatives which act as chromophoric moieties. These dyes were applied to cotton fabric…
Abstract
Purpose
This study aims to synthesise and characterise new reactive dyes based on thiazole derivatives which act as chromophoric moieties. These dyes were applied to cotton fabric, resulting in the dyed fabrics exhibiting good colour strength, light fastness and other fastness properties. The antibacterial activity of the dyed cotton fabric was evaluated against gram-negative and gram-positive bacteria.
Design/methodology/approach
The dyes were synthesised in two steps. First, the coupling compound was formed by adding H-acid solution to cyanuric chloride in an ice bath at pH 5 then adding 4-aminobenzenesulphonic acid portion-wise at room temperature and at pH 6-7. Second, different diazonium salts 4-phenylthiazol-2-amine (2a) and 4-(4-methoxyphenyl) thiazol-2-amine (2b) were coupled with the coupling compound at pH 5. The resultant monochlorotriazine (MCT)-reactive dyes (6a, 6b) were formed. The synthesised dyes were applied onto cotton fabric under typical exhaust dyeing conditions and their dyeing properties were investigated.
Findings
High antimicrobial activity, dye exhaustion and fixation yield on cotton fabric were recorded for each dye. All dyes showed high stability against washing, rubbing, perspiration and light fastness.
Research limitations/implications
Dyeing of cotton fabric with these dyes which have higher fastness, higher exhaustion and higher antibacterial activity is considered one of the most important reactive dyes species.
Practical implications
The preparation procedure showed the synthesis of the novel MCT-reactive dyes derived from thiazole derivatives followed by the application of these dyes on cotton fabrics.
Social implications
Use of reactive dyes will bring a number of benefits to society including higher fastness and higher antibacterial activity so, and these dyes can be used for dyeing cotton.
Originality/value
In this work, the new reactive dyes derived from thiazole derivatives were synthesised and their structures were confirmed by the analytical and spectral data. Such compounds are considered to be excellent reactive dyes with different colour shades and higher antibacterial activity.