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This work aims to demonstrate the use of electrochemical chloride extraction (ECE) to remove chloride ions away from the steel rebar in chloride-contaminated mortar and to mitigate the corrosion of the embedded steel.

To simulate salt contamination in concrete, sodium chloride was added at 0.5 per cent by weight of cement in the fresh mortar featuring a water-to-cement ratio of 0.45. The ECE treatments were varied at two electrical current densities (1 and 5 A/m²), using two electrolytes (0.1M NaOH and 0.1M Na₃BO₃ solutions) and for two periods (2 and 4 weeks). The average free chloride concentration in cement mortars before and after ECE treatment was quantified using a customized chloride sensor, whereas the spatial distribution of relevant elements was obtained using energy-dispersive X-ray spectroscopy. The effect of ECE treatment on the electric resistivity of mortar and the corrosion resistance of steel rebar was investigated by electrochemical impedance spectroscopy and potentiodynamic polarization measurements, respectively.

The experimental results reveal that the ECE treatment was effective in removing chlorides and in improving electric resistivity and compressive strength of the mortar, when using the sodium borate solution as the electrolyte. In this case, a 4-week ECE treatment at 1 A/m² decreased the free chloride content in the mortar by 70 per cent, significantly increased the Ca/Si ratio in the mortar near rebar, led to a more refined and less permeable microstructure of the mortar and significantly improved its compressive strength. The ECE treatment was able to halt the chloride-induced corrosion of steel rebar by passivation. A 4-week ECE treatment at 1 A/m² using sodium hydroxide and sodium borate solutions decreased the corrosion rate of rebar by 36 and 34 per cent, respectively.

This electrochemical rehabilitation of steel-reinforced concrete under chloride-contaminated condition is very effective in prolonging its service life.

In this study, the oxidative degradation performance of indigo wastewater based on electrochemical systems was explored. The decolourization degrees, removal rate of chemical oxygen demand and biochemical oxygen demand of the indigo wastewater after degradation were evaluated and optimized treatment conditions being obtained.

The single factor method was first used to select the electrolyte system and electrode materials. Then the response surface analysis based on Box–Behnken Design was chosen to determine the influence of four independent variables such as FeCl₃ concentration, NaCl concentration, decolourization time and voltage on the degradation efficiency.

On the basis of single factor experiment, the electrode material of stainless steel was selected in the double cell, and the indigo wastewater was electrolyzed with FeCl₃ and NaCl electrolytes. The process conditions of electrochemical degradation of indigo wastewater were optimized by response surface analysis: the concentration of FeCl₃ and NaCl was of 16 and 9 g/L, respectively, with a decolourization time of 50 min, voltage of 10 V and decolourization percentage of 98.94. The maximum removal rate of chemical oxygen demand reached 75.46 per cent. The highest ratio of B/C was 3.77, which was considered to be more biodegradable.

Dyeing wastewater is bringing out more and more pollution problems to the environment. However, there are some shortcomings in traditional technologies such as adsorption and filtration. As a kind of efficient and clean water treatment technology, electrochemical oxidation has been applied to the treatments of various types of wastewater. The decolourization and degradation of indigo wastewater is taken as an example to provide reference for the treatment of wastewater in actual plants.

The developed method provided a simple and practical solution for efficiently degrading indigo wastewater.

The method for the electrochemical oxidation technology was novel and could find numerous applications in the degradation of printing and dyeing wastewater.

This paper aims to investigation of processes for Pb²⁺ elimination from water/wastewater as a significant public health issue in many parts of world. The removal of Pb²⁺ ions by various nanocomposites has been explained from water/wastewaters. ZnO-based nanocomposites, as eco-friendly nanoparticles with unique physicochemical properties, have received increased attention to remove Pb²⁺ ions from water/wastewaters.

In this review, different ZnO-based nanocomposites were reviewed for their application in the removal of Pb²⁺ ions from the aqueous solution, typically for wastewater treatment using methodology, such as adsorption. This review focused on the ZnO-based nanocomposites for removing Pb²⁺ ions from water and wastewaters systems.

The ZnO-based nanocomposite was prepared by different methods, such as electrospinning, hydrothermal/alkali hydrothermal, direct precipitation and polymerization. Depending on the preparation method, various types of ZnO-based nanocomposites like ZnO-metal (Cu/ZnO, ZnO/ZnS, ZnO/Fe), ZnO-nonmetal (PVA/ZnO, Talc/ZnO) and ZnO-metal/nonmetal (ZnO/Na-Y zeolite) were obtained with different morphologies. The effects of operational parameters and adsorption mechanisms were discussed in the review.

The findings may be greatly useful in the application of the ZnO-based nanocomposite in the fields of organic and inorganic pollutants adsorption.

The present study is novel, because it investigated the morphological and structural properties of the synthesized ZnO-based nanocomposite using different methods and studied the capability of green-synthesized ZnO-based nanocomposite to remove Pb²⁺ ions as water contaminants.

The current review can be used for the development of environmental pollution control measures.

This paper reviews the rapidly developing field of nanocomposite technology.

This study aims to explore suitable anode materials used in the electrochemical system for indigo dyeing wastewater, to achieve optimal treatment performances.

The single factor experiment was used to explore the optimum process parameters for electrochemical decolorization of indigo dyeing wastewater by changing the applied voltage, electrolysis time and electrolyte concentration. At the voltage of 9 V, the morphology of flocs with different electrolytic times was observed and the effect of electrolyte concentration on decolorization rate in two electrolyte systems was also investigated. Further analysis of chemical oxygen demand (COD) removal rate, anode weight loss and sediment quantity after electrochemical treatment of indigo dyeing wastewater were carried out.

Comprehensive considering the decolorization degree and COD removal rate of the wastewater, the aluminum electrode showed the best treatment effect among several common anode materials. With aluminum electrode as an anode, under conditions of applied voltage of 9 V, electrolysis time of 40 min and sodium sulfate concentration of 6 g/L, the decolorization percentage obtained was of 94.59% and the COD removal rate reached at 84.53%.

In the electrochemical treatment of indigo dyeing wastewater, the aluminum electrode was found as an ideal anode material, which provided a reference for the choice of anodes. The electrodes used in this study were homogenous material and the composite material anode needed to be further researched.

It provided an effective and practical anode material choice for electrochemical degradation of indigo dyeing wastewater.

Combined with the influence of applied voltage, electrolysis time and electrolyte concentration and anode materials on decolorization degree and COD removal rate of indigo dyeing wastewater, providing a better electrochemical treatment system for dyehouse effluent.

The purpose of this paper was to compare the electrochemical homogeneity of AZ91D after various heat treatment processes, and its influence on the growth, composition, microstructure and corrosion resistance of phosphate conversion coatings.

The electrochemical activity of different heat-treated Mg alloys was evaluated via scanning vibrational electrode technique; the characterization of the microstructure and phase composition of coatings was conducted using a scanning electron microscope and X-ray diffraction. The corrosion resistance was evaluated by electrochemical tests and accelerated neutral salt spray tests.

T6 treatment increased the electrochemical homogeneity, while T4 treatment decreased the microstructure homogeneity of AZ91D magnesium alloy, due to the existence of residual Al-Mn impurity phase. The phosphate conversion coating (PCC) on T6 heat-treated Mg alloys showed the most compact microstructure and the best corrosion resistance, while the coating on the T4 heat-treated Mg alloy exhibited the worst microstructure and corrosion resistance.

The microstructure and protectiveness of coatings are related to the homogeneousness of Mg alloy: an Mg substrate with a more heterogeneous electrochemical reactivity yields a PCC with less protectiveness, which could be explained by the difference of precipitation kinetics at the metal/electrolyte interface.

This study aims to investigate the corrosion resistance and electrochemical dissolution behavior of superalloys treated by different oxidation treatments.

Ni-based superalloys were subjected to oxidation treatment at 1000 °C for 10 h, 1150 °C for 10 h and 1200 °C for 20 h. The microstructure, electrochemical dissolution behavior, elemental distribution, as well as compactness and composition of the oxide layer, were studied.

The results show that both the thickness and the granular oxide size of the oxide layer on Ni-based superalloys increase with longer oxidation times and higher temperatures. The electrochemical dissolution efficiency of Ni-based superalloys decreases with increasing oxidation time and temperature. The reduced electrochemical dissolution efficiency observed in Ni-based superalloys oxidation-treated at 1200 °C for 20 h is primarily attributed to the thicker oxide layer, which contains the highest Cr oxide content.

The findings contribute to the advancement of recycling and utilization of Ni-based superalloy scrap.

Inconel 617 alloy is widely used in industry due to its superior high temperature properties. After long periods of operation, the alloy microstructure changes. One of the methods to regain the alloy microstructure is heat treatment at elevated temperatures. In the present study, electrochemical and mechanical responses of Inconel 617 alloy over 30,000 hours of operation as a transition‐piece in agas turbine engine are examined. The heat treatment process at two different temperature levels is applied when refurbishing the alloy microstructure. The electrochemical tests are conducted to investigate the corrosion response of the alloy before and after the heat treatment process. Fatigue and tensile tests are carried out for the workpieces subjected to the electrochemical tests. SEM is introduced to examine the fractured surfaces.

The purpose of this paper is to consider the effect of heat treatment on alloying element distribution and the electrochemical properties of Al‐5Zn‐0.03In anodes.

The Al‐5Zn‐0.03In alloy anodes are treated at 510°C for 10 h, then cooled in water. Electron probe microanalysis of JXA‐8800 and EDAX quantitative energy dispersive X‐ray analysis is used to examine the microstructure of the anodes before and after heat treatment, and the electrochemical properties of the anodes are tested.

By heat treatment, the solubility of Zn in aluminum is increased while the solubilities of Fe and Si are changed only slightly. The quantity of the Al‐Zn intermetallic compounds is evidently decreased and the Al‐Fe‐Si intermetallic compound is preserved. Strip segregation along grain boundaries is changed to spherical particulates. The attack of aluminum anodes initiates and propagates in grain boundaries and interdendritic zones, which are enriched in In and Zn, so the current efficiency of the aluminum anodes is related to the degree of corrosion taking place at grain boundaries and the extent of exfoliation of grains. The greater the extent of Al‐Zn metallic compounds that are present at grain boundaries, the more sensitive to grain boundary corrosion is the alloy and the greater the degree of desquamation of grains, the lower is the current efficiency of the aluminum anode.

The results of this paper clarify the role of water‐quenching affect on the microstructure and electrochemical properties of Al‐Zn‐In anodes.

The purpose of this study is to explore the possibility of enhancing the tribological and electrochemical performances of alumina coating using monoclinic zirconia addition and post-heat treatment.

Al₂O₃ and Al₂O₃-ZrO₂ coatings were deposited on plain steel by flame-wire spraying. The influence of zirconia addition and post-treatment (900? for two hours) on phase composition and mechanical, tribological and electrochemical behaviors was investigated. Sliding dry tests were performed using a ball-on-disc test rig with WC-Co as the counter body. Polarization and impedance electrochemical responses were conducted under a 3.5 Wt.% NaCl solution.

X-ray diffraction measurements revealed an increase in the a-Al₂O₃ phase after heat treatment. Sliding dry tests showed that the abrasive wear mechanism was predominant for all coatings, leading to a good correlation between hardness and wear rates. However, the friction behavior had an opposite trend: the higher the hardness, the higher the coefficient of friction. The addition of zirconia significantly affected the corrosion resistance, which was more positive than the heat treatment effect.

Post-treatment showed beneficial effects on the wear and corrosion performance of alumina-based coatings, with a particularly noticeable improvement for the coating containing 30 Wt.% ZrO₂. These improvements were more pronounced for the Al₂O₃-ZrO₂ coating than the pure alumina Al₂O₃ coating.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-05-2024-0190/

The purpose of this paper is to investigate the electrochemical treatment of textile dye wastewater in the presence of NaCl electrolyte by using aluminium electrodes.

The electrochemical treatment of textile dye wastewater was optimized using response surface methodology (RSM). RSM‐based D‐optimal design was employed to construct statistical models relating turbidity and designed effective parameters known as current density, electrolyte concentration and electrolysis time. The experimental plan consists of a three‐factor (three numerical) matrix.

The results show that the current density has significant effect on the reduction of turbidity. Besides, electrolysis time is the most influential factor on the turbidity. In order to enhance the electrochemical treatment performance, no coagulant addition or further physicochemical processes were employed.

Industrial certain textile dye wastewater in Turkey is used to determine optimal values.