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Coag-flocculation behavior of Brachystegia eurycoma coagulant (BEC) in respect of pH variation in coal washery effluent has been investigated at room temperature using various dosages of unblended BEC. Coag-flocculation parameters such as order of reaction α, rate constant (K and Ks), coagulation period, τ_1/2 e.t.c were determined. Turbidity measurement was employed using the single angle nephelometric method while BEC processing was based on work reported by Adebowale and Adebowale. Maximum parameter values are recorded at K of 6.6667×10^-3m³/kg.s; dosage of (0.2 and 0.4kg/m³), pH2 and τ_1/2 of 1.7293s while the minimum values are recorded at 5.00×10^-4m³/kg.s, dosage of 0.3kg/m³, pH 6 and τ_1/2 of 23.0572s. Minimum value of coag-flocculation efficiency is >98%; thus establishing BEC as a potential effective coag-flocculant. Parameters obtained lie within the range of previous works and confirm that the theory of perikinetics holds for coag-flocculation of the coal washery effluent using BEC at the experimental conditions.

Fluted pumpkin seed shell, an abundant and inexpensive natural resource in Nigeria, was used as a precursor to adsorbent production for the removal of suspended and dissolved particle (SDP) from initially coagulated coal washery effluent (CWE). Key parameters such as contact time, adsorbent dose, pH and temperature were investigated using batch mode. The adsorption equilibrium, thermodynamics and kinetics of SDP on H₃PO₄ treated shell (FPA) and NH₄Cl treated shell (FPS) were examined at specified temperatures. Equilibrium data sufficiently fit the Langmuir isotherm model (R² > 0.99; SSE < 0.09). The pseudo-second order kinetic model provides the best correlation (R²>0.99;SSE<0.1) with the experimental data. The evaluated ΔG○ and ΔH○ indicate the spontaneous and endothermic nature of the process. This study demonstrates that pumpkin seed shell could be utilized as low cost, renewable, ecofriendly bioadsorbent for the removal of SDP from CWE.

Chrysophylum albidium seed shell was utilized as an adsorbent for suspended and dissolved particle removal from coagulated coal washery effluent. Several parameters were investigated using batch mode and 2³ full factorial central composite designs (CCD) (for optimization purposes). There exist single generality in optimal values for acid treated shell (ASAA) and salt treated shell (ASAS) at pH 6.8, 30°C, 10g/L dose, 30 min equilibrium time and 1g adsorbent mass for batch mode and CCD, respectively. Equilibrium data sufficiently fit the Langmuir isotherm (R² > 0.99 and SSE (%) ≤ 0.093). Pseudo-second order kinetics provides best correlation (R² > 0.99 and SSE (%) < 0.1) with experimental data. Thermodynamics constants (ΔG°, ΔH° and ΔS°) were respectively evaluated as -122.190 KJ/mol, 69005.967 J/mol and 228.146 Jmol^-1K^-1 for ASAA and -1537.455 KJ/mol, 68008.026 J/mol and 229.523 Jmol^-1K^-1 for ASAS. The shell biomass promises high potential as an efficient adsorbent since the adsorption process was favorable, endothermic and spontaneous.

Chitin Derived Coag-flocculant (CDC), is a cheap, abundant and eco-friendly deacetylated cationic polymer applied in this study at a pilot scale for the treatment of Brewery Effluent (BRE). The study investigates the influence of varying BRE pH on the coag-flocculation kinetics and behavior of the aggregation process at varying CDC dosages. The best coag-flocculation performance is recorded at rate constant, K_m, of 0.0003 l/mg·min, half life, τ1/2, of 0.6846 min, pH of 4, dosage of 100 mg/l and efficiency, E (%) of 99.8791. Minimum efficiency (%) > 96 was achieved at 3 minutes of coag-flocculation, establishing CDC as an effective water treatment agent at the conditions of the experiment.

The purpose of this paper is to investigate fast pyrolysis of maple fruit as an energy sources. This could serve as a solution to the energy sources problem.

Fast pyrolysis of maple fruit (samara) was achieved in a fixed bed reactor. The pyrolysis experiments have been conducted on the sample of maple seeds to particularly determine the effects of pyrolysis temperature, particle size and sweep gas flow rate on the pyrolysis product yields.

The oil of maple fruit from fast pyrolysis has good properties to be a potential candidate as a biofuel or as a source of chemicals. In addition to being environmentally desirable, it can reduce the energy cost, e.g. that Turkey imports a majority of its energy.

The use of maple fruit for fast pyrolysis and pyrolysis conditions impact on the yields of pyrolysis liquid can be considered as novel aspects of this paper.