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The purpose of this study was to prepare colour pigments for use as spectrally selective coatings for solar absorbers.

Nano-particles cobalt and nickel oxides were prepared by sol–gel techniques. These oxides were prepared with its molar ratios and annealed at 200, 400, 600 and 800°C. The structure of the pigments was characterized by infrared spectrometer, differential scanning calorimetry analysis, X-ray diffraction, transmission electron microscope and scanning electron microscope.

Encapsulated cobalt and nickel oxides were completely formed at 800 and 600°C, and its colour was black and dark green, respectively. The results confirmed that black and green pigments combined selectivity with colour. Optical properties such as absorption and reflection were affected by the firing temperatures on cobalt and nickel oxides–gel polymers. All synthesized pigments consisted of nano-particles.

The prepared samples used in the present work were synthesized from cobalt chloride and nickel acetate. The salts were dispersed in polyacrylamide as a precursor.

The prepared metal oxides had good solar properties.

Colour becomes more important for thermal solar collectors, and it has attracted interest. This might be related to a generally growing attention towards architectural integration of solar energy systems into building. Architects would prefer different colours besides black, even if lower efficiency would have to be accepted.

A mixed metal oxide-based spinel ceramic pigment has been successfully synthesized incorporating inorganic, high-temperature stable furnace cement as an inbuilt binder. Step by step synthesis was done for the spinel and cement mix formulations.

The pigment mix was synthesized by a solid-solid method where the inorganic binder was incorporated in the mix. The results suggested that CoCuMn-based spinel ceramic pigment with cement mix could be obtained at an annealing temperature of 1,100ºC for 1 h and the size, morphology and crystallinity of spinel mix were greatly influenced by the calcination temperature.

The pigment mix synthesized was applied as a coating to different substrates such as aluminum, glass and Mild steel. The results revealed that spectral selectivity of TSSS paint coatings based on the CoMnCu spinel ceramic mix was much better than that of solvent-based coatings for high-temperature applications. The presence of cement as an inorganic binder makes the functioning and application of paint easy as it becomes that of a waterborne type.

Ease of application, stability at high temperatures, best absorptivity at the solar selective spectrum and excellent adhesion properties for the selected surface are the key features of the designed pigment system. The applied pigment mix was studied as a coating to get the results for solar selective system.

This paper aims to examine the fire retardant property potentials of cow horn ash particles (CHAp) bio-additive and aluminium trihydrate (AH), a traditional inorganic fire-retardant additive, respectively, in banana peduncle fibre (BPF) reinforced polyester composites. An attempt was made to comparatively analyse the fire retardant capacity potentials of CHAp, a bio-material waste that is readily available, at no cost, as a potential fire retardant material for composites manufacture with a conventional inorganic fire retardant additive (AH).

The fibre used in this research was derived from the banana peduncle. The matrix is unsaturated polyester. A scanning electron microscope was used to analyze the particle size of the carbonized CHAp. The composites were compounded using 0%, 2.5%, 5%, 7.5% and 10% of CHAp and AH, respectively. A cone calorimeter instrument was used in the analysis to obtain combustion information of CHAp and AH formulated polyester-BPF composites. Test samples were cut to the dimensions of 100 × 100 mm. All materials are conditioned at 23 ± 30 °C and the relative humidity of 50 ± 5% for 24 h before testing. The samples were wrapped with aluminium foil around the back and edges before placing the samples on the holder and then into the cone calorimeter. The samples were backed with a non-combustible insulating refractory material (brick). The samples were orientated horizontally and exposed to irradiances of 50 kW/m² at a temperature of approximately 6000 °C. The samples were pilot ignited and ran in triplicate; the average readings of the three runs were taken.

The results obtained from the analysis depicted similar fire retardant properties for formulations with CHAp and AH, respectively. Composites formulated with CHAp exhibited delayed ignition time of 25%, increased end of burning time of 14.24% and reduced total heat release rate of 9.07% for the developed composites. The developed BPF/CHAp/polyester composites yield composites with fire retardancy, which would find relevance in the engineering material industry.

CHAp, therefore, would suffice as an alternative to the inorganic, expensive and non-environmental friendly, conventional fire retardant additives used in composites manufacture.

This study aims to investigate unripe carob pod as a source of antioxidant molecules useful in the eco-friendly synthesis of a gelatin conjugate. This one was involved in the preparation of gummies able to produce remarkable human health benefits.

Eco-friendly strategies (ultrasound-assisted extraction, low temperatures and eco-friendly solvents) were employed in the extraction of active molecules. Antioxidant molecules were involved in the grafting reaction with gelatin chains (ascorbic acid/hydrogen peroxide couple as initiator system). Gelatin conjugate represents a useful material able to prepare gummies with remarkable rheological and antioxidant performances over time.

Experimental results confirmed that the green approach allowed the achievement of extracts with remarkable antioxidant properties due to the presence of phenolic moieties. Gelatin conjugate synthesis preserved these functionalities, usefully exploited in the preparation of gummies with significant structural and biological features.

Compared to the literature data the preparation of the gummies with outstanding biological properties was performed by employing functional gelatin synthesized by an eco-friendly approach.

This study aims to identify the bioactive compounds in the Onion (Allium burdickii [A.B]) bulb using Raman and Fourier transform infrared spectroscopy (FTIR) spectroscopy. It assessed the extraction conditions of bioactive compounds from A.B. while evaluating the best extraction conditions.

The research opted for an experimental qualitative approach. It examined the extraction conditions of A.B., namely, temperature (°C), time (min) and mass-to-liquor ratio (M:R) using ultraviolet-visible spectrophotometry. Identification of bioactive compounds present in the dye was performed using Raman spectroscopy and the validation of the results was done by FTIR spectroscopy.

The study determined the best extraction conditions (time, temperature, M:R) for A.B bulb. The study confirmed the presence of bioactive compounds.

The limitation was quantification of bioactive compounds in A.B bulb.

The findings prove that the A.B. bulb can provide a sustainable source of bioactive compounds (functionalized compounds). The study provides suitable extraction conditions for A.B. and further elaborates on the techniques for identifying bioactive compounds in A.B. bulb extracts.

The study provides A.B. as a source of bioactive compounds and a clean dye for textile coloration.

To the best of the authors’ knowledge, there is no documented study on the qualitative analysis of bioactive compounds in A.B using Raman and FTIR. Therefore, the study fulfils the identified need to ascertain alternative procedures for the analysis of bioactive compounds.

Thermoplastic polymer fabrics are normally heat set to make them dimensionally stable. These fabrics in garment panel form may again be exposed to heat during the processes such as bonding, sublimation printing and cause to change their dimensions. The purpose of this paper is to investigate the response of polyester yarns in knitted fabrics to heat setting and post-heat treatments.

In this study, the thermal shrinkage behaviour of heat set polyester knitted fabrics when subjected to post-heat treatment processes are analyzed using differential scanning calorimetry (DSC) and analysis of fabric shrinkage. DSC is a thermo-analytical technique that measures the difference in the amount of heat needed to increase the temperature of the sample and the reference. A heat flux versus temperature curve is one of the results of a DSC experiment. The polymer structure and morphology of polyester heat-treated and post-heat–treated fabrics were determined by examining the DSC thermograms.

Heat setting and post-heat setting causes the effective temperature of polyester to change. Effective temperature occurred around 160°C for fabrics heat set at low temperatures and increases as the heat setting temperature increases. Post-heat treatments cause to elevate the effective temperature. Shrinkage of fabrics below the effective temperature is not statistically significant while the shrinkage at higher temperatures is significant. Effective temperature is the main determinant of thermal shrinkage behaviour of polyester.

The study reveals the significance of the effective temperature of polyester on heat treatments and post-heat treatments. The study revealed that heat-setting temperature is a primary determinant of the thermal stability of polyester fabric that are subjected to heat treatments.

In recent years, the textile industry has been required to develop new methods and technologies through introduction of some new materials in various processes rather than employing the same conventional chemicals. The aim of this research was to investigate the changes induced on the cotton fibre by the nanoclay treatment using a pre‐treatment method.

The fibres were dyed with basic and direct dyes after the nanoclay pre‐treatment. Technical measurements were studied including Fourier‐transform infrared spectroscopy (FTIR), UV‐visible spectrophotometer, differential scanning calorimetry (DSC), thermal degradation analysis (TGA), scanning electron microscopy (SEM), moisture regain measurement (MRM), tensile strength test (TST), reflectance spectroscopy (RS) and fastnesses evaluation.

The intensity of the major peaks in FTIR spectra of the nanoclay treated sample is in favour of the chemical changes of the cellulose functional groups. Basic dyes showed a higher dyeability on the clay pre‐treated samples compared to raw materials. The results of the colour measurements showed that the more concentration of the clay mineral was used, the darker the colour of the dyed sample was. Some interesting results were obtained in the research.

The nanoclay and a dispersing agent used in the present context were used as received. Besides, the type of the dispersing agent is important for preparation of a colloidal dispersion of nanoclay.

The method developed in this research provides a simple and practical solution for improving the dyeability of cotton with direct and basic dyes.

The method for enhancing the dyeability of cotton is novel and can be used in cotton processing with new properties.

The thermal history during laser exposure determines part properties in selective laser sintering (SLS). The purpose of this study is to introduce a new measurement technique based on a CO₂ laser unit combined with a high-speed DCS. A first comparison of the thermal history during laser exposure measured with Laser-high-speed-(HS)-differential scanning calorimetry-(DSC) and in SLS process is shown.

This Laser-HS-DSC allows an imitation of the SLS-process in a very small scale, as the sample is directly heated by a CO₂ laser. For this study, the laser power and the impact time is varied for determining temperature and achieved heating rates. Consequently, the temperature levels measured by the Laser-HS-DSC are compared with measurements in SLS-process.

The influence of laser power and impact time on resulting maximum temperatures und heating rates during laser exposure are investigated. With increasing laser power and impact time the maximum temperature rises up to approximately 450°C without material degradation. The heating rate increases up to an impact time of 3 ms and stays almost equal for higher durations.

The Laser-HS-DSC experiments are based on few particles limiting a complete comparison with SLS process. In SLS, one volume element is exposed several times. In this study the PA12 material was exposed only once.

For the first time, laser sintering experiments can be transferred to a laboratory scale to analyze the influence of laser exposure on resulting temperature field during laser exposure without superimposing effects.

This work aimed to prepare black transition metal oxide pigments to be used as solar absorbers in the solar selective and other industrial paints.

Mixed metal oxide CoCuMnO_x spinel pigments were synthesised via the sol‐gel route. These oxides, namely (I‐Co_0.50Cu_0.25Mn_0.25)O_x, (II‐Co_0.25Cu_0.50Mn_0.25)O_x and (III‐Co_0.25Cu_0.25Mn_0.50)O_x, were prepared with different molar ratios and annealed at 600, 800 and 900°C, respectively. The prepared oxides were characterised by infrared spectrometer (IS), differential scanning calorimetry analysis (DSC), X‐ray diffraction (XRD) and transmission electron microscope (TEM).

The prepared pigments have a spinel structure with the composition CoCuMnO_x. All synthesised pigments consisted of nano particles ranged from 10 to 80 nm. The optical properties showed high absorption and moderately low reflectance in the solar wavelength range.

The prepared samples, used in the present work, were synthesized from cobalt sulphate, copper chloride and manganese chloride. The salts were dispersed in polyacrylamide as a precursor.

The prepared samples were thermally stable and had good optical properties. They could be used as absorber materials in the painting of solar collectors.

These thermally stable mixed metal oxides could be used in the painting of solar collectors. The three mixed metal oxides could be used as absorber materials for heating solar collectors due to their high absorption and moderately low reflectance in the solar wavelength range.

This paper aims to provide a flexible polyurethane (PU) film with visible light trapping ability, photothermal conversion and energy storage performance by covalently bonded a visible light absorbing dye into the polymer through copolymerization.

For this target solution copolymerization of diphenyl-methane-diisocyanate (MDI), poly(1,4-butylene adipate) (PBA2000), polyethylene glycol (PEG) of different molecular weight, self-made dye, 1,4-butanediol (BuOH) was carried out in a flame-dried flask under an inert nitrogen (N₂) atmosphere. First, an isocyanate-terminated prepolymer of dried PEG, MDI and PBA2000 was prepared in dimethylformamide and stirred for 1 h at 35°C. Then, self-made dye and 1, 4-butanediol (BuOH) were added and heated at 85°C for 3 h to get photothermal conversion polyurethane (PTPU) solution. Allowed the solution to dry at room temperature for seven days and then at 65°C for 12 h to get PTPU films.

The flexible PU films with photothermal conversion and energy storage performances were successfully synthesized and the functional films presented both excellent energy storage and mechanical property when the molecular weight of PEG was in the range of 6,000∼10,000.

The materials that were used in this research paper had a reasonably low cost. Also, the procedures for the synthesis of dye and polymers were extremely easy because there was no need for high pressure or temperature and no dangerous solvents were used.

The photothermal conversion property and mechanical performance of the synthesized flexible PU films were characterized. The results have proved that these films were soft and elastic, and have certain photothermal conversion and energy storage ability, thus can be used in the surface finishing of special fabric and leather.

Visible light trapping photothermal conversion PU flexible film with energy storage capability was prepared for the first time.