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Phosphonic acids are good complexing agents. However, they are not good as inhibitors except for a very few. Synergistic inhibition is offered in the presence of metal cations like Ca²⁺, Mg²⁺, Zn²⁺ and others in neutral media. The zinc ion is an ideal choice. The part of zinc ions are now replaced by polymers, azoles to prepare eco‐friendly inhibitor formulations. They are also used as corrosion inhibitors in concrete, coatings, rubber blends, acid cleaners, anti‐freeze coolants, etc. Discusses the various applications of phosphonic acids and their action mechanisms.

The inhibitor 5‐mercapto‐3‐p‐nitrophenyl‐1‐2‐4‐triazole has 92.75 per cent inhibition efficiency in controlling corrosion of copper in neutral aqueous environment, containing 300 ppm Cl^‐, a situation where the chloride concentration of the cooling water system will usually be not greater than 300 ppm. A discussion of mechanistic aspects of corrosion inhibition is based, in a holistic way, on the results obtained from the classical weight loss method, potentiostatic polarisation study, AC‐impedance study, UV‐visible absorption study and different surface examination techniques like FTIR, XRD and ESCA. The protective film is found to be of unimolecular thickness and to consist of Cu (I) – inhibitor complex cuprous chloride, CuCl or CuCl₂^‐ complex ion or both and no oxide of copper on the surface.

To develop a new corrosion inhibitor formulation for carbon steel in low chloride environments.

Corrosion inhibition efficiencies were evaluated by the weight loss method and by impedance measurement studies. The nature of the inhibition process was evaluated using potentiostatic polarization studies. The nature of the protective film was investigated using X‐ray diffraction, X‐ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy. The concept of synergistic effect was used in the development of the new synergistic inhibitor formulation.

A new corrosion inhibitor formulation, containing tertiary butyl phosphonate (TBP), zinc ions and citrate, has been developed to control the corrosion of carbon steel in low chloride environments. This inhibitor formulation was found to offer a maximum inhibition efficiency of 96 per cent in a neutral pH test environment. It was interesting to observe that the binary system, consisting of higher concentrations of the TBP and zinc ions, offered only 79 per cent inhibition efficiency. The ternary system, consisting of relatively lower concentrations of the phosphonate, zinc ions and citrate offered a higher (96 per cent) efficiency. This ternary inhibitor system also was found to be efficient in acidic as well as basic environments in the pH range 5‐8. The inhibitor combination was determined to function as a “mixed”‐type inhibitor, though being predominantly cathodic. A plausible explanation of the mechanism of corrosion inhibition is proposed.

The ternary inhibitor formulations based on phosphonate, zinc ions and another environmentally friendly synergists like citrate will be quite useful for corrosion inhibition of carbon steel in cooling water systems as they contain relatively less concentrations of phosphonate and zinc ions.

The research paper presents the results of a new synergistic inhibitor formulation and also discusses the mechanistic aspects of corrosion inhibition.

This paper aims to reduce environment pollution caused by benzotriazole. The authors chose one of the best inhibitors from 2-aminobenzimidazole, 2-methylbenzimidazol, 2-mercaptobenzimidazole and benzimidazole in combination with benzotriazole.

The electrochemical measurement indicated that 2-methylbenzimidazol had the best inhibition behavior. Then, it was mixed with benzotriazole. Techniques such as field emission scanning electron microscopy, atomic force microscopy, Raman spectroscopy and optical contact angle measurements were used.

The results showed that the inhibition efficiency was up to 99.98%, when the mixture concentration was 20 mmol/L and the molar ratio 1:1.

1-benzotriazole was mixed with 2-methylbenzimidazol for the first time. During the exist of methyl, 2-methylbenzimidazol has the better inhibition; this point was ignored by researchers.

The study aims to verify and establish the result of the most suitable optimization approach for higher performance and lower emission of a variable compression ratio (VCR) diesel engine. In this study, three types of test fuels are taken and tested in a variable compression ratio diesel engine (compression ignition). The fuels used are conventional diesel fuel, e-diesel (85% diesel-15% bioethanol) and nano-fuel (85% diesel-15% bioethanol-25 ppm Al₂O₃). The effect of bioethanol and nano-particles on performance, emission and cost-effectiveness is investigated at different load and compression ratios (CRs). The optimum performance and lower emission of the engine are evaluated and compared with other optimization methods.

The test engine is run by diesel, e-diesel (85% diesel-15% bioethanol) and nano-fuel (85% diesel-15% bioethanol-25 ppm Al₂O₃) in three different loadings (4 kg, 8 kg and 12 kg) and CR of 14, 16 and 18, respectively. The optimum value of energy efficiency, exergy efficiency, NO_X emission and relative cost variation are determined against the input parameters using Taguchi-Grey method and confirmed by response surface methodology (RSM) technique.

Using Taguchi-Grey method, the maximum energy and exergy efficiency, minimum % relative cost variation and NO_X emission are 24.64%, 59.52%, 0 and 184 ppm, respectively, at 4 kg load, 18 CR and fuel type of nano-fuel. Using RSM technique, maximum energy and exergy efficiency are 24.8% and 62.9%, and minimum NO_X emission and % cost variation are 208.4 ppm and –6.5, respectively, at 5.2 kg load, 18 CR and nano-fuel. The RSM is suggested as the most appropriate technique for obtaining maximum energy and exergy efficiency, and minimum % relative cost; however, for lowest possible NO_X emission, the Taguchi-Grey method is the most appropriate.

Waste rice straw is used to produce bioethanol. 4-E analysis, i.e. energy, exergy, emission and economic analysis, has been carried out, optimized and compared.

The purpose of this paper is to construct a self-assembled double layer of organosilane on the surface of stainless steel and to investigate its corrosion inhibitive capability.

A monolayer of 3-glycidoxypropyltrimethoxysilane (GPTMS) was grafted onto an oxidized AISI 430SS (AISI 430 stainless steel) surface substrate from dry toluene solution. The hydrolysis of 1H,1H,2H,2H-perfluorodecyltriethoxysilane (PFDS) molecules was used to anchor a second organic layer from mixed water-ethanol solution. The adsorption behavior and corrosion inhibition properties of the monolayer and also the bilayer were investigated by potentiodynamic polarization, scanning electron microscope (SEM), Fourier transformed infrared spectroscopy (FTIR) and contact angle measurements.

The GPTMS/PFDS bilayer was successfully deposited onto the oxidized AISI 430SS surface. The optimal assembling time for the filming of the first GPTMS monolayer is 6 hours. Suitable values of pH and temperature of the PFDS self-assembly solution were pivotal to the successful deposition of the second layer. Compared to the GPTMS monolayer, the GPTMS/PFDS bilayer exhibited a significant enhancement of the corrosion inhibition performance of AISI 430SS in NaCl solution.

The contact angle value measured on the bilayer-modified surface was somewhat lower than the reported value of a complete fluorinated surface. However, further optimization of the assembling condition is needed to obtain more orderly and denser films.

This paper provides useful information regarding the preparation of an organosilane bilayer on the surface of stainless steel and its corrosion inhibition properties in NaCl solution. It illustrates potential application prospects of GPTMS/PFDS bilayers for surface treatment of stainless steel.

This study aims to investigate the effect of changes in iron content in 70/30 copper–nickel alloy on the corrosion process.

70Copper–30Nickel-xFe-1Mn (x = 0.4,0.6,0.8,1.0 Wt.%) alloy were prepared by the high frequency induction melting furnace. The scanning electron microscope, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy were used to analyze the morphology and component of the corrosion product film.

The results show that the corrosion resistance of 70/30 copper–nickel alloy added with 1.0%Fe is the best, and the film is divided into inner dense Cu2O composite film and outer hydration loose layer; XRD showed that after adding 1.0% Fe, the content of Cu2(OH)3Cl in the corrosion product film was significantly reduced, while the content of Cu2O remained unchanged; XPS showed that nickel accumulates in the inner layer of corrosion product film; the stage growth mode of the film, the role of nickel in it and the enrichment mechanism of iron in the inner film were summarized and discussed.

The changes in the composition and structure of the corrosion product film caused by the iron content are revealed, and the mechanism of the difference in corrosion resistance is discussed.

The purpose of this paper is to perform the evaluation of copper susceptibility to corrosion in industrial cooling systems. Microstructure and defects of copper are observed, while divergences from optimum structure are discussed.

Various types of corrosion are examined. Electrochemical techniques such as electrochemical impedance spectroscopy and potentiodynamic polarisation are applied in these materials, using corrosion inhibitors. Microscopic observations and electrochemical measurements are interpreted according to possible mechanistic scenarios.

It is evident that, under specific conditions (e.g. high pH), water cooling ingredients can enhance corrosion, leading to significant copper mass loss from the inner surface of the pipe and thus leading to failure.

Evaluation of copper corrosion in cooling industrial systems was done, as well as studies of copper corrosion in sodium chloride.

To study and compare the inhibition effects of eco‐friendly inhibitors of sodium silicate and 1‐hydroxyethylidene 1,1 diphosphonic acid (HEDP) in corrosion control and prevention of soft water discolouration (red water) in carbon steel pipelines.

Electrochemical impedance and Tafel polarization measurements were used to study corrosion inhibition properties. The experiments were carried out under different concentration ratios of inhibitors. Different hydrodynamic conditions were applied to simulate pipeline fluid flow. Scanning electron microscopy (SEM) and EDAX analysis were used for surface studies.

It was observed that corrosion inhibitor combinations under static conditions showed synergistic effects at low concentrations. The inhibition efficiency and synergistic behaviours of inhibitors were enhanced as the electrolyte turbulence was increased. In addition, the inhibitor concentration value required to reach maximum inhibition decreased. It was found that at 20 ppm sodium silicate and 5 ppm HEDP, co‐inhibition efficiencies increased significantly to more than 90 per cent and the corrosion rate decreased far below 1 mpy as the electrode rotational speed was increased. Surface studies using SEM revealed the formation of a compact and uniform film of co‐inhibitors.

The results of this paper can be used for the development of effective, non‐toxic and economically attractive corrosion inhibitor formulations for soft water transmission pipelines.

The observed synergistic behaviour can be due to the incorporation of the silicate gel‐like network through organic phosphorous bonds. The hydrodynamic condition of the electrolyte leads to enhancement of inhibition efficiency, which indicates that the corrosion inhibition was mass transfer controlled.

Nowadays, ample industries are fascinated to look for high strength and light weight materials for the development of robust parts. Because of light weight and high stiffness to weight ratio; usage of aluminum parts is growing rapidly, especially in automotive engineering. Process improvement of Al alloys and their grain structure refinement is the current area of interest in casting companies. In this research work, an investigation has been carried out to enhance the process improvement of die casting by optimization of various significant parameters and their refinement of grains by the effect of Nb-C novel grain refiner.

L27 orthogonal array (OA) has been considered to optimize the preferred casting input parameters such as molten metal temperature (°C), die temperature (°C), injection pressure (bar), Al-3.5Nb-1.5 C novel grain refiner and Ni alloying additions as key process parameters in order to increase the quality and efficiency of Al-9Si-3Cu aluminum alloy die casting by reducing the porosity formation.

It was observed that the porosity values have significantly decreased from 0.88% to 0.25% particularly at 0.1 wt.% of new grain refiner and 0.5 wt. % of Al-6Ni master alloy. As per the ANOVA results, it was observed that Al-3.5FeNb-1.5 C grain refiner (F value 2609.22), Al-6Ni alloying addition (F value 1329.13), molten metal temperature (F value 1002.43) and, injection pressure (F value 448.06) are the factors that significantly affects the porosity, whereas die temperature was found to be insignificant. The results show that new grain refiner is one the most significant factor among the other selected parameters. The contribution of the new grain refiner to the variation of mean casting porosity is around 57.74%. confidence interval (CI) has also been estimated as 0.013 for 95% consistency level to validate the predicted range of optimum casting porosity of aforesaid alloy.

To the best of the authors' knowledge, no study has been conducted in the past to investigate the combined effect of these die casting parameters and composition factors for the development of Al-Si robust cast parts. The paper represents original research and provides new information for the fabrication of die casting parts.