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Study of corrosion of copper in industrial cooling systems

Ioannis A Kartsonakis (School of Chemical Engineering, National Technical University of Athens, Zographos, Greece)
Elias P. Koumoulos (School of Chemical Engineering, National Technical University of Athens, Zographos, Greece.)
Antonis Karantonis (School of Chemical Engineering, National Technical University of Athens, Zographos, Greece.)
Costas A. Charitidis (School of Chemical Engineering, National Technical University of Athens, Zographos, Greece.)
S Dessypris (Department of Technical Support and Infrastructures, Hellenic Telecemmunications Organization, Maroussi, Greece.)
A Monos (Department of Technical Support and Infrastructures, Hellenic Telecemmunications Organization, Maroussi, Greece.)

International Journal of Structural Integrity

ISSN: 1757-9864

Article publication date: 5 October 2015

220

Abstract

Purpose

The purpose of this paper is to perform the evaluation of copper susceptibility to corrosion in industrial cooling systems. Microstructure and defects of copper are observed, while divergences from optimum structure are discussed.

Design/methodology/approach

Various types of corrosion are examined. Electrochemical techniques such as electrochemical impedance spectroscopy and potentiodynamic polarisation are applied in these materials, using corrosion inhibitors. Microscopic observations and electrochemical measurements are interpreted according to possible mechanistic scenarios.

Findings

It is evident that, under specific conditions (e.g. high pH), water cooling ingredients can enhance corrosion, leading to significant copper mass loss from the inner surface of the pipe and thus leading to failure.

Originality/value

Evaluation of copper corrosion in cooling industrial systems was done, as well as studies of copper corrosion in sodium chloride.

Keywords

Acknowledgements

C.A. Charitidis, I.A. Kartsonakis and E.P. Koumoulos acknowledge the financial support of the research project “SELF-HEALING NANOMATERIALS FOR PROTECTION OF METAL ALLOYS”, CODE 3456 & ACRONYM: “SHELL”, for the National Action “ARISTEIA” of the Operational Program “Education and Lifelong Learning”, by the European Union - European Social Fund (ESF) and National Funds through the Operational Program “Education and Lifelong Learning” (ELL).

Citation

Kartsonakis, I.A., Koumoulos, E.P., Karantonis, A., Charitidis, C.A., Dessypris, S. and Monos, A. (2015), "Study of corrosion of copper in industrial cooling systems", International Journal of Structural Integrity, Vol. 6 No. 5, pp. 617-635. https://doi.org/10.1108/IJSI-10-2013-0039

Publisher

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Emerald Group Publishing Limited

Copyright © 2015, Emerald Group Publishing Limited

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