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Wettability and microstructure transformations of YAG ceramic brazing to kovar alloy with AgCuTi filler alloy

Wei Lin (Key Lab for Robot and Welding Automation of Jiangxi Province, School of Advanced Manufacturing, Nanchang University, Nanchang, China)
Cheng Wang (Key Lab for Robot and Welding Automation of Jiangxi Province, School of Advanced Manufacturing, Nanchang University, Nanchang, China)
Qingyi Zou (Jiluan Academy, Nanchang University, Nanchang, China)
Min Lei (Nanchang University, Nanchang, China)
Yulong Li (Nanchang University, Nanchang, China)

Soldering & Surface Mount Technology

ISSN: 0954-0911

Article publication date: 25 November 2024

Issue publication date: 2 January 2025

37

Abstract

Purpose

This paper aims to conduct work to obtain high-quality brazed joint of YAG ceramic and kovar alloy.

Design/methodology/approach

Wetting and spreading behavior of AgCuTi filler alloy on YAG ceramic and kovar alloy under vacuum (2∼3 × 10–4 Pa) and argon conditions was investigated and compared. Then, YAG ceramic was brazed to kovar alloy under a high vacuum of 2∼3 × 10–4 Pa; the influence of holding time on the interface structure of the joint was investigated.

Findings

The wettability of AgCuTi on YAG is poor in the argon atmosphere, the high oxygen content in the reaction layer hinders the formation of the TiY2O5 reaction layer, thereby impeding the wetting of AgCuTi on YAG; in the vacuum, a contact angle (?=16.6°) is obtained by wetting AgCuTi filler alloy on the YAG substrate; the microstructure of the YAG/AgCuTi/kovar brazed joint is characterized to be YAG/Y2O3/(Fe, Ni)Ti/Ag(s, s) + Cu(s, s)/Fe2Ti + Ni3Ti/Fe2Ti/kovar; at 870 °C for the holding time of 10 min, a (Fe, Ni) Ti layer of approximately 1.8 µm is formed on the YAG side.

Originality/value

Wetting and spreading behavior of the brazing filler alloy under different conditions and the influence of the holding time on the interface microstructure of the joint were studied to provide references for obtaining high-quality brazed joints.

Keywords

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 52065043), the Science and Technology Innovation High Level Talent Project of Double Thousand Plan of Jiangxi Province (jxsq2019201048), the Natural Science Foundation of Chongqing, China (CSTB2022NSCQ-MSX1346 and CSTB2023NSCQ-MSX1047), the National Natural Science Foundation of China (Grant No. 52105354).

Citation

Lin, W., Wang, C., Zou, Q., Lei, M. and Li, Y. (2025), "Wettability and microstructure transformations of YAG ceramic brazing to kovar alloy with AgCuTi filler alloy", Soldering & Surface Mount Technology, Vol. 37 No. 1, pp. 50-59. https://doi.org/10.1108/SSMT-07-2024-0036

Publisher

:

Emerald Publishing Limited

Copyright © 2024, Emerald Publishing Limited

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