Shape recovery characteristics of shape memory cyanate ester/epoxy composite reinforced with calcium sulfate whisker
ISSN: 0369-9420
Article publication date: 16 January 2020
Issue publication date: 22 September 2021
Abstract
Purpose
The purpose of this paper is to study the influence of calcium sulfate whiskers (CSWs) on the thermodynamic properties and shape memory properties of epoxy/cyanate ester shape memory composites.
Design/methodology/approach
To improve the mechanical properties of shape memory cyanate ester (CE)/epoxy polymer (EP) resin, high performance CSWs were used to reinforce the thermo-induced shape memory CE/EP composites and the shape memory CSW/CE/EP composites were prepared by molding. The effect of CSW on the mechanical properties and shape memory behavior of shape memory CE/EP composites was investigated.
Findings
After CSW filled the shape memory CE/EP composites, the bending strength of the composites is greatly improved. When the content of CSW is 5 Wt.%, the bending strength of the composite is 107 MPa and the bending strength is increased by 29 per cent compared with bulk CE/EP resin. The glass transition temperature and storage modulus of the composites were improved in CE/EP resin curing system. However, when the content of CSW is more than 10 Wt.%, clusters are easily formed between whiskers and the voids between whiskers and matrix increase, which will lead to the decrease of mechanical properties of composites. The results of shape memory test show that the shape memory recovery time of the composites decreases with the decrease of CSW content at the same temperature. In addition, the shape recovery ratio of the composites decreased slightly with the increase of the number of thermo-induced shape memory cycles.
Research limitations/implications
A simple way for fabricating thermo-activated SMP composites has been developed by using CSW.
Originality/value
The outcome of this study will help to fabricate the SMP composites with high mechanical properties and the shape memory CSW/CE/EP composites are expected to be used in space deployable structures.
Keywords
Acknowledgements
This work is supported by the research funds from the National Natural Science Foundation of China (No. 51805400), the research fund from the Natural Science Foundation of Shaanxi Province (No. 2017JQ5002), and the China Postdoctoral Science Foundation (No. 2016M600765).
Conflict of interest: The authors declare no conflict of interest.
Citation
Wang, Y., Zhang, Y., Zhang, J., Ye, J. and Tian, W. (2021), "Shape recovery characteristics of shape memory cyanate ester/epoxy composite reinforced with calcium sulfate whisker", Pigment & Resin Technology, Vol. 50 No. 5, pp. 384-393. https://doi.org/10.1108/PRT-09-2019-0087
Publisher
:Emerald Publishing Limited
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