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New modified poly(ester amide) resins and their uses as a binder for surface coating with different applications

Ahmed Mohamed (Department of Chemistry, Faculty of Science, Al-Aazhr University, Assuit, Egypt)
Abdelhalim Mustafa (Department of Chemistry, Faculty of Science, Al-Aazhr University, Assuit, Egypt)
M.S.A. Elgaby (Department of Chemistry, Faculty of Science, Al-Aazhr University, Assuit, Egypt)
H. Abd El-Wahab (Department of Chemistry, Faculty of Science (Boys), Al-Aazhr University, Cairo, Egypt)
Said Ahmed Abed (Corrosion Department, General Administration of Researches Labs, Assiut Oil Refining Company (ASORC), Assuit, Egypt)
A. Kazlauciunas (Department of Colour Science, University of Leeds, Leeds, UK and Home Chesham, Buckinghamshire, UK)

Pigment & Resin Technology

ISSN: 0369-9420

Article publication date: 27 October 2020

Issue publication date: 11 March 2021

176

Abstract

Purpose

This paper aims to prepare a new modified poly(ester amide) (PEA) resins and use it as a binder for anticorrosive and antimicrobial coatings.

Design/methodology/approach

New modified PEA compositions were prepared based on 4-amino-N, N-bis(2-hydroxyethyl) benzamide (AHEB) as the ingredient source of the polyol used and evaluated as vehicles for surface coating. The structure of the modifier and PEA resin was confirmed by FT-IR, H¹-NMR, MW, thermogravimetric analysis and scanning electron microscope studies. Coatings of 50±5 µm thickness were applied to the surface of glass panels and mild steel strips by means of a brush. The coating performance of the resins was evaluated using international standard test methods and involved the measurement of phyisco-mechanical properties and chemical resistance.

Findings

The tests carried out revealed that the modified PEA based on AHEB enhanced both phyisco-mechanical and chemical properties. Also, the resins were incorporated within primer formulations and evaluated as anti-corrosive and antimicrobial single coatings. The results illustrate that the introduction of AHEB, within the resin structure, improved the film performance and enhances the corrosion resistance and antimicrobial activity performance of PEA resins.

Practical implications

The modified PEA compounds can be used as binders in paint formulations to improve the chemical, physical, corrosion resistance and antimicrobial activity properties.

Originality/value

Modified PEA resins are cheaper and can be used to replace other more expensive binders. These modified PEA resins can compensate successfully for the presence of many the anticorrosive and antimicrobial paint formulations, and thus, lower the costs. The main advantage of these binders is that they combine the properties of both polyester and polyamide resins based on nitrogenous compound, are of lower cost and they also overcome the disadvantages of both its counterparts. Also, they can be applied in other industrial applications.

Keywords

Citation

Mohamed, A., Mustafa, A., Elgaby , M.S.A., Abd El-Wahab, H., Abed, S.A. and Kazlauciunas, A. (2021), "New modified poly(ester amide) resins and their uses as a binder for surface coating with different applications", Pigment & Resin Technology, Vol. 50 No. 2, pp. 146-156. https://doi.org/10.1108/PRT-06-2020-0060

Publisher

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Emerald Publishing Limited

Copyright © 2020, Emerald Publishing Limited

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