Monitoring the anticorrosion performance of developed epoxy-based paint formulations on metallic surfaces by electrochemical impedance spectroscopy

Abstract

Purpose

This study aims to investigate the impact of varying solid ratios in epoxy-based formulations on their corrosion resistance. The amounts of epoxy resin in the formulations were kept constant, and the behavior of paints with varying filler ratios was compared. It also examines the tensiometric and rheological properties of these formulations.

Design/methodology/approach

Three distinct epoxy-based formulations cured with amine compounds were prepared. The formulations underwent various testing protocols to evaluate their performance: coating tests: coated panels with cross lines were exposed to humidity and corrosive atmospheres. Tensiometric Measurements: Conducted using pendant and sessile drop methods. Rheological characterizations: ıncluded flow tests, oscillatory amplitude sweeps and three-interval thixotropy tests. Corrosion resistance assessment: after the panels were immersed in methanol for one week, measurements were taken using electrochemical impedance spectroscopy. Additional tests: neutral salt spray (NSS) and humidity testing.

Findings

The study observed that the coated panels, after exposure to NSS and humidity testing, demonstrated corrosion resistance within acceptable limits as defined by the ISO 12944-6 standard. Results indicate that the epoxy-based formulations show potential for improvements in paints and coatings, suggesting promising advancements in their anticorrosion performance.

Originality/value

This research provides insights into how the solid ratios in epoxy-based formulations influence their performance, particularly in terms of corrosion resistance, tensiometric and rheological properties. The findings contribute to the development of more effective epoxy resin-based coatings for industrial applications.

Citation

Sariogullari, H., Demirkurt, M. and Yılmazer, Z. (2024), "Monitoring the anticorrosion performance of developed epoxy-based paint formulations on metallic surfaces by electrochemical impedance spectroscopy", Pigment & Resin Technology, Vol. ahead-of-print No. ahead-of-print. https://doi.org/10.1108/PRT-05-2024-0055