Polypyrrole in water borne epoxy coating

Abstract

Purpose

The paper aims to discuss the evaluation of anti-corrosive efficiency of conducting polymer, polypyrrole in water borne epoxy-polyamine coatings.

Design/methodology/approach

Polypyrrole (PPy) is synthesised by chemical oxidative polymerisation. The synthesised PPy is characterised by employing FT-IR, XRD, SEM and EDX analysis. The coatings are formulated using water borne epoxy cross-linked with aliphatic polyamine adduct and the effect of PPy on corrosion prevention is studied. PPy was used as anti-corrosive pigment in concentration varying from 1 to 5 wt.%. In addition to anti-corrosive property; mechanical properties, chemical resistance and weathering properties of the coatings containing PPy are studied, thereby obtaining a wholesome data about the quality and performance of these coatings.

Findings

The result obtained through various tests showed that the coating with 1 and 2% PPy exhibited excellent weathering resistance, mechanical properties and improved chemical resistance. Higher percentage loading of PPy (beyond 3 per cent) proves to be disastrous, as extended percolation networks are formed which results in rapid intense corrosion leading to fast coating breakdown.

Research limitations/implications

The anti-corrosion property of the coating can be tested by means of atmospheric exposure such as Florida test which produces a real time evaluation of the anti-corrosive nature of the coating at natural condition rather than accelerated weathering, thereby providing more reliable performance data for intended application purpose.

Practical implications

The results find application in anti-corrosive/performance paints for industrial application.

Originality/value

This research paper presents the results of anti-corrosion behaviour of PPy in water borne epoxy-polyamide coating. Based on this result, a highly effective anti-corrosive coating can be formulated by the addition of small percentage of PPy in combination with other conventional pigments, thereby enhancing corrosion protection. But care must be taken so as to avoid formation of extended percolation network of PPy which leads to rapid coating breakdown.

Citation

Mahanwar, P., Sathyanarayana, A., Bambole, V. and Sabharwal, S. (2013), "Polypyrrole in water borne epoxy coating", Pigment & Resin Technology, Vol. 42 No. 6, pp. 362-373. https://doi.org/10.1108/PRT-05-2011-0039