Phthalonitrile-etherified cardanol-phenol-formaldehyde resin: synthesis, characterization and properties

Abstract

Purpose

The purpose of this study is to investigate the heat resistance and heat-resistant oxygen aging of 4-nitrophthalonitrile-etherified cardanol-phenol-formaldehyde (PPCF) to further use and develop the resin as the matrix resin of high-temperature resistant adhesives and coatings.

Design/methodology/approach

PPCF resin was synthesized by 4-nitrophthalonitrile and cardanol-phenol-formaldehyde (PCF). The structures of PPCF and PCF were investigated by Fourier transform infrared, differential scanning calorimetry and proton nuclear magnetic resonance. In addition, the heat resistance and processability of PPCF and PCF resins were studied by dynamic mechanical analysis, thermogravimetric analysis, scanning electronic microscopy (SEM), X-ray diffraction (XRD) techniques and rheological studies.

Findings

The results reveal that PPCF forms a cross-linked network at a lower temperature. PPCF resin has excellent resistance under thermal aging in an air atmosphere and that it still had a certain residual weight after aging at 500°C for 2 h, whereas the PCF resin is completely decomposed.

Originality/value

4-Nitrophthalonitrile was introduced into PCF resin, and XRD and SEM were used to investigate the high temperature residual carbon rate and heat-resistant oxygen aging properties of PPCF and PCF resins.

Citation

Zhang, D., Liu, X., Bai, X., Wang, G., Rong, L., Zhao, Y., Li, X., Zhu, J. and Mi, C. (2022), "Phthalonitrile-etherified cardanol-phenol-formaldehyde resin: synthesis, characterization and properties", Pigment & Resin Technology, Vol. 51 No. 6, pp. 609-617. https://doi.org/10.1108/PRT-04-2021-0044