Enhanced lubrication by core-shell TiO₂ nanoparticles modified with PEG-400

Abstract

Purpose

The purpose of this paper is to enhance the characteristics of TiO₂ nanoparticles (NPs). Because these NPs stick together easily and are difficult to distribute evenly, they cannot be used extensively in lubricating oils. Altering TiO₂ was recommended as an alternate way for making NPs simpler to disperse.

Design/methodology/approach

Through dielectric barrier discharge plasma (DBDP)-assisted ball mill diagnostics and modeling of molecular dynamics, TiO₂@PEG-400 NPs were produced using the DBDP-assisted ball mill. The NPs’ microstructure was examined using FESEM, TEM, XRD, FT-IR and TG-DSC. Using the CFT-1 reciprocating friction tester, the tribological properties of TiO₂@PEG-400 NPs as base oil additives were studied. EDS and XPS were used to examine the surface wear of the friction pair.

Findings

Tribological properties of the modified NPs are vastly superior to those of the original NPs, and the lipophilicity value of TiO₂ NPs was improved by 200%. It was determined through tribological testing that TiO₂@PEG-400’s exceptional performance might be attributable to a chemical reaction film made up of TiO₂, Fe₂O₃, iron oxide and other organic chemicals.

Originality/value

This work describes an approach for preventing the aggregation of TiO₂ NPs by coating their surface with PEG-400. In addition, the prepared NPs can enhance the tribological performance of lubricating oil. This low-cost, high-performance lubricant additive has tremendous promise for usage in marine engines to minimize operating costs while preserving navigational safety.

Citation

Wei, Y., Dai, L., Fang, Y., Sheng, C.X. and Rao, X. (2023), "Enhanced lubrication by core-shell TiO₂ nanoparticles modified with PEG-400", Industrial Lubrication and Tribology, Vol. 75 No. 4, pp. 415-423. https://doi.org/10.1108/ILT-12-2022-0365