Adsorption and inhibitive properties of ethanol extract of Garcinia kola and Cola nitida for the corrosion of mild steel in H2SO4
Abstract
Purpose
The purpose of this paper is to study the inhibitive and adsorption characteristics of ethanol extract of Garcinia kola and Cola nitida for the corrosion of mild steel in H2SO4 solutions.
Design/methodology/approach
The inhibition efficiencies were evaluated using weight loss and thermometric methods while the adsorption properties were studied using IR spectroscopy.
Findings
The inhibition efficiencies of ethanol extracts of Garcinia kola and Cola nitida were comparable and vary with concentration of the extract, period of immersion and with temperature. The extracts act as adsorption inhibitors because of its phytochemical composition. The extracts are adsorbed spontaneously on the surface of mild steel according to Langmuir adsorption isotherms. The mechanism of physical adsorption is proposed from the trend of the inhibition efficiency with temperature and the values of activation energy and some thermodynamic parameters obtained.
Research limitations/implications
The study provides information on the use of ethanol extract of Garcinia kola and Cola nitida as corrosion inhibitors for mild steel. Electrochemical studies such as polarisation and AC impedance spectra will illuminate the mechanistic aspects of the extract.
Practical implications
Ethanol extract of Garcinia kola and Cola nitida are environmentally friendly inhibitors for the corrosion of mild steel in H2SO4.
Originality/value
These environmentally friendly inhibitors may find possible applications in metal surface anodising and surface coatings.
Keywords
Citation
Eddy, N.O. (2010), "Adsorption and inhibitive properties of ethanol extract of
Publisher
:Emerald Group Publishing Limited
Copyright © 2010, Emerald Group Publishing Limited