Synthesis of 5‐arylazo‐2‐(arylidenehydrazino)‐thiazole disperse dyes for dyeing polyester fibres

Abstract

Purpose

The purpose of this paper is to synthesise some new 5‐arylazothiazole disperse dyes and study their application in dyeing polyester fibres.

Design/methodology/approach

A series of 5‐arylazo‐2‐(arylidenehydrazino)‐4‐substituted‐thiazole dyes were prepared by cyclocondensation of hydrazonoyl bromides with various thiosemicarbazone derivatives.

Findings

The dyed fibres exhibit very good washing, perspiration, sublimation and light fastness properties with little variation in the moderate to good rubbing fastness. The ease of preparation and the acceptable fastness properties makes these dyes particularly valuable.

Research limitations/implications

In the present paper, the synthesis of 5‐arylazo‐2‐(arylidenehydrazino)‐thiazole disperse dyes was achieved by one step pathway. In addition, the variations in substituents on the aryl and thiazole moieties could also be studied.

Practical implications

The new arylazo‐thiazole disperse dyes are superior in terms of yield, purity, colour strength, and having fastness properties of an order acceptable for commercial utilisation.

Originality/value

The synthesised disperse azo dyes are superior in terms of preparation, yield, purity, and fastness properties.

Citation

Abdel‐Latif, E., Amer, F.A., Metwally, M.A. and Khalifa, M.E. (2009), "Synthesis of 5‐arylazo‐2‐(arylidenehydrazino)‐thiazole disperse dyes for dyeing polyester fibres", Pigment & Resin Technology, Vol. 38 No. 2, pp. 105-110. https://doi.org/10.1108/03699420910940608