Hongqiang Fan, Shuying Li, Zhicong Shi, Xuefei LV and Zongchang Zhao
The aim of this paper is to investigate the synergism effect between lanthanum salt (La(NO3)3) and benzotriazole (BTAH) on the corrosion inhibition of commercial brass and to…
Abstract
Purpose
The aim of this paper is to investigate the synergism effect between lanthanum salt (La(NO3)3) and benzotriazole (BTAH) on the corrosion inhibition of commercial brass and to further study the inhibition mechanism.
Design/methodology/approach
Potentiodynamic polarization curves were carried out on bare brass and brass treated with additions of optimum concentration of BTAH, La salt and La salt+BTAH to the basal deposition solutions in 3.5 wt. percent sodium chloride solution. The inhibition mechanism of the composite conversion coatings on brass obtained in optimal deposition techniques were investigated by electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM), X‐ray diffraction (XRD), and FT‐IR reflection spectra.
Findings
A “Critical La(NO3)3 content” and “Critical BTAH content” were both observed, at which the coatings prepared performs the highest protectiveness, and La(NO3)3 and BTAH had an excellent synergism effect on the corrosion inhibition of brass. The corrosion mechanisms for uncoated and coated brass are different. A remarkable enhancement of the brass's corrosion protection was obtained by the formation of composite conversion coatings consisted of Cu(I)BTA and La coordinate thing except for Cu2O and La2O3, which acted as a barrier avoiding the release of metal ions and inhibited the diffusion of the oxygen.
Originality/value
The results from this paper showed that La(NO3)3 and BTAH could be used together to prepare the novel composited conversion coatings on commercial brass for the good corrosion inhibition.
Details
Keywords
This study seeks to understand how accountant stereotypes have been constructed and reconstructed at the macro-national and the structural level in Chinese society.
Abstract
Purpose
This study seeks to understand how accountant stereotypes have been constructed and reconstructed at the macro-national and the structural level in Chinese society.
Design/methodology/approach
This qualitative investigation into China's social construction of accountant stereotypes employs Becker's (1963) labelling theory. Viewing stereotyping as a socially constructed practice, this study draws on a post-positivistic, reflexive epistemology in conducting 28 semi-structured interviews with accountants and related actors.
Findings
Chinese accountant stereotypes are constructed and reconstructed according to the rules created and enforced in different cultural-political periods. The accountant stereotypes constructed during the ancient Confucian period (500 BC – 1948) were replaced during 1949 and 2012 when the political focus shifted towards propagating socialism and later promoting economic growth. They also show how Confucian stereotypes of accountants resurfaced in 2013 but were reconstructed by the central government's cultural confidence policy of propagating Confucianism.
Originality/value
Empirically, prior literature has focused on what the accountant stereotype is and how accountants respond to such stereotypes, but it has neglected the ways in which these accountant stereotypes are politically and culturally constructed, diffused and legitimated. This paper fills in the gap by understanding the social practice of accountant stereotyping in a previously unexplored political-cultural context, namely Chinese society. In theoretical terms, by offering the first use of Becker's (1963) labelling theory in the accounting literature, it furthermore enhances our understanding of how accountants' identities and social standing are shaped by social rules.