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Publication date: 14 September 2010

Yong‐Ming Tang, Yun Chen, Wen‐Zhong Yang, Xiao‐Shuang Yin, Ying Liu and Jin‐Tang Wang

The aim of this paper is to investigate inhibition of copper corrosion by 3,5‐bis(2‐thienyl)‐4‐amino‐1,2,4‐triazole (2‐TAT) in 1 M HCl and 0.5 M H2SO4.

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Abstract

Purpose

The aim of this paper is to investigate inhibition of copper corrosion by 3,5‐bis(2‐thienyl)‐4‐amino‐1,2,4‐triazole (2‐TAT) in 1 M HCl and 0.5 M H2SO4.

Design/methodology/approach

Potentiodynamic polarization curves and electrochemical impedance measurements were carried out on copper in 1 M HCl and 0.5 M H2SO4 containing various concentrations of 2‐TAT, and the effects of temperature were also investigated.

Findings

As an efficient inhibitor, 2‐TAT behaves better in 1 M HCl than in 0.5 M H2SO4. 2‐TAT can be classified as cathodic‐type corrosion inhibitor in 1 M HCl and acts as relatively mixed type in 0.5 M H2SO4. Activation energies in the presence and absence of 2‐TAT were obtained by measuring the temperature independence of corrosion current. Adsorption of the inhibitor on the copper surface was found to obey the Langmuir adsorption isotherm.

Practical implications

This inhibitor could have application in industries where hydrochloric acid solutions are used to remove scale and salts from copper surfaces and may render dismantling unnecessary.

Originality/value

The results from this paper showed that 2‐TAT could be considered as a suitable inhibitor for copper in acidic media.

Details

Anti-Corrosion Methods and Materials, vol. 57 no. 5
Type: Research Article
ISSN: 0003-5599

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