Baolian Zhang, Zhenzhen Zhang, Xuening Fei, Yingchun Gu and Lu Yu
The purpose of the study reported in this paper was to prepare modified C.I. Pigment Red (PR) 170 to reduce production cost and improve application performance. The structure of…
Abstract
Purpose
The purpose of the study reported in this paper was to prepare modified C.I. Pigment Red (PR) 170 to reduce production cost and improve application performance. The structure of the modified pigment was characterised. The colour strength, thermal stability, mobility, aqueous dispersability and ultraviolet (UV) resistance of modified pigments were studied.
Design/methodology/approach
Silica fume was added into the diazonium salt solution under acidic condition, followed by the activation to generate new surface. Subsequently, coupling component was dropwise added to the system to form the modified pigments evenly on the surface of silica fume in situ. The structure and properties of the modified pigment were studied by fourier transform infrared spectoscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermal gravity analysis (TG-DTA), UV-visible diffuse reflectance spectra (UV-Vis DRS), and commission internationale de L‘Eclairage (CIE L*a*b*) colour measurements.
Findings
The morphology and particle size of the modified pigment were controlled by the modification of the silica fume, and the organic pigment and silica fume formed a core–shell structure. The properties of the modified pigment including colour strength, thermal stability, mobility, aqueous dispensability and UV resistance were improved significantly.
Research limitations/implications
The effect of the amount of silica fume on the thickness of the organic pigment layer and the effect of the thickness of the organic pigment layer on the properties of the modified pigment need to be studied further.
Practical implications
This paper shows a feasible method of the modification of the PR170 with the silica fume, and the modification can improve the properties of the PR170. The use of silica fume to modify organic pigment can realise the reuse of solid waste and reduce the production cost of the organic pigment.
Social implications
This modification method of the organic pigment is adaptive and it can be adjusted to the modification of other species of the organic pigment.
Originality/value
The modification of the PR170 with the silica fume was carried out in its preparation process, which synchronised the preparation and modification of the organic pigment. The properties of the modified pigment were improved, which were beneficial for their application in inks and coatings.
Details
Keywords
Ming Qiu, Yanwei Miao, Yingchun Li, Long Chen, Rensong Hu and Jianjun Lu
The fabric self-lubricating liners are the key factors impacting the performances of self-lubricating spherical plain bearings. The purpose of this paper is to improve the…
Abstract
Purpose
The fabric self-lubricating liners are the key factors impacting the performances of self-lubricating spherical plain bearings. The purpose of this paper is to improve the friction and wear properties of self-lubricating radial spherical plain bearings by modification of the liners.
Design/methodology/approach
The liners of hybrid woven PTFE/Kevlar fabrics were treated respectively by the LaCl3 and CeO2 solutions. The tribological properties of self-lubricating spherical plain bearings with treated or untreated liners under continuous swaying conditions were investigated with the bearing tester at the swaying frequency of 2.5 Hz and the swaying angle of ±10°. The film formation and wear mechanisms were analyzed based on the observation of worn surfaces with a scanning electron microscope (SEM) and an energy dispersive spectrometer (EDS).
Findings
Results show that the tribological properties of the bearings treated by the LaCl3 or CeO2 solution were improved compared with those of the untreated bearings. In particular, the wear resistance of bearings treated by the CeO2 solution was remarkably improved under higher swaying cycles, but the anti-friction properties and cooling effects of bearings treated by the LaCl3 solution were better under lower swaying cycles. Through SEM analysis, the reasons were analyzed. The bearings with treated liners only produced slight adhesive and abrasive wear, but the bearings with untreated liners produced more serious adhesive and abrasive wear under higher swaying cycles.
Originality/value
The paper proposed a new pretreatment process for the self-lubricating liners. The investigation on the friction and wear behaviors of the bearings is beneficial for prolonging the service lives of the radial spherical plain bearings.
Details
Keywords
Yong Li, Yingchun Zhang, Gongnan Xie and Bengt Ake Sunden
This paper aims to comprehensively clarify the research status of thermal transport of supercritical aviation kerosene, with particular interests in the effect of cracking on heat…
Abstract
Purpose
This paper aims to comprehensively clarify the research status of thermal transport of supercritical aviation kerosene, with particular interests in the effect of cracking on heat transfer.
Design/methodology/approach
A brief review of current research on supercritical aviation kerosene is presented in views of the surrogate model of hydrocarbon fuels, chemical cracking mechanism of hydrocarbon fuels, thermo-physical properties of hydrocarbon fuels, turbulence models, flow characteristics and thermal performances, which indicates that more efforts need to be directed into these topics. Therefore, supercritical thermal transport of n-decane is then computationally investigated in the condition of thermal pyrolysis, while the ASPEN HYSYS gives the properties of n-decane and pyrolysis products. In addition, the one-step chemical cracking mechanism and SST k-ω turbulence model are applied with relatively high precision.
Findings
The existing surrogate models of aviation kerosene are limited to a specific scope of application and their thermo-physical properties deviate from the experimental data. The turbulence models used to implement numerical simulation should be studied to further improve the prediction accuracy. The thermal-induced acceleration is driven by the drastic density change, which is caused by the production of small molecules. The wall temperature of the combustion chamber can be effectively reduced by this behavior, i.e. the phenomenon of heat transfer deterioration can be attenuated or suppressed by thermal pyrolysis.
Originality/value
The issues in numerical studies of supercritical aviation kerosene are clearly revealed, and the conjugation mechanism between thermal pyrolysis and convective heat transfer is initially presented.