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Article
Publication date: 24 May 2022

Yaojie Zheng, Sun Huili, Luchun Yan, Xiaolu Pang, Alex A. Volinsky and Kewei Gao

High-strength martensitic steels having strong hydrogen embrittlement (HE) susceptibility and the metal carbide (MC) nanoprecipitates of microalloying elements such as Nb, V, Ti…

400

Abstract

Purpose

High-strength martensitic steels having strong hydrogen embrittlement (HE) susceptibility and the metal carbide (MC) nanoprecipitates of microalloying elements such as Nb, V, Ti and Mo in the steel matrix can effectively improve the HE resistance of steels. This paper aims to review the effect of MC nanoprecipitates on the HE resistance of high-strength martensitic steels.

Design/methodology/approach

In this paper, the effects of MC nanoprecipitates on the HE resistance of high-strength martensitic steels are systematically described in terms of the types of MC nanoprecipitates, the influencing factors, along with numerical simulations.

Findings

The MC nanoprecipitates, which are fine and semicoherent with the matrix, effectively improve the HE resistance of steel through the hydrogen trapping effects and microstructure optimization, but its effect on the HE resistance of steel is controlled by its size, number and distribution state.

Originality/value

This paper summarizes the effects and mechanisms of MC nanoprecipitates on HE performance of high-strength martensitic steel and provides the theoretical basis for corrosion engineers to design high-strength martensitic steels with excellent HE resistance and improve production processes.

Details

Anti-Corrosion Methods and Materials, vol. 69 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

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Article
Publication date: 11 April 2022

Yaojie Zheng, Huili Sun, Luchun Yan, Huisheng Yang, Kewei Gao, Xiaolu Pang and Alex A. Volinsky

The purpose of this study is to investigate the effect of ferrite on hydrogen embrittlement (HE) of the 17-4PH stainless steels.

330

Abstract

Purpose

The purpose of this study is to investigate the effect of ferrite on hydrogen embrittlement (HE) of the 17-4PH stainless steels.

Design/methodology/approach

The effects of ferrite on HE of the 17-4PH stainless steels were investigated by observing microstructure and conducting slow-strain-rate tensile tests and hydrogen permeability tests.

Findings

The microstructure of the ferrite-bearing sample is lath martensite and banded ferrite, and the ferrite-free sample is lath martensite. After hydrogen charging, the plasticity of the two steels is significantly reduced, along with the tensile strength of the ferrite-free sample. The HE susceptibility of the ferrite-bearing sample is significantly lower than the ferrite-free steel, and the primary fracture modes gradually evolved from typical dimple to quasi-cleavage and intergranular cracking. After aging at 480°C for 4 h and hydrogen charging for 12 h, the 40.9% HE susceptibility of ferrite-bearing samples was the lowest. In addition, the hydrogen permeation tests show that ferrite is a fast diffusion channel for hydrogen, and the ferrite-bearing samples have higher effective hydrogen diffusivity and lower hydrogen concentration.

Originality/value

There are a few studies of the ferrite effect on the HE properties of martensitic precipitation hardening stainless steel.

Details

Anti-Corrosion Methods and Materials, vol. 69 no. 3
Type: Research Article
ISSN: 0003-5599

Keywords

Available. Open Access. Open Access
Article
Publication date: 19 March 2024

Chun Tian, Gengwei Zhai, Mengling Wu, Jiajun Zhou and Yaojie Li

In response to the problem of insufficient traction/braking adhesion force caused by the existence of the third-body medium on the rail surface, this study aims to analyze the…

251

Abstract

Purpose

In response to the problem of insufficient traction/braking adhesion force caused by the existence of the third-body medium on the rail surface, this study aims to analyze the utilization of wheel-rail adhesion coefficient under different medium conditions and propose relevant measures for reasonable and optimized utilization of adhesion to ensure the traction/braking performance and operation safety of trains.

Design/methodology/approach

Based on the PLS-160 wheel-rail adhesion simulation test rig, the study investigates the variation patterns of maximum utilized adhesion characteristics on the rail surface under different conditions of small creepage and large slip. Through statistical analysis of multiple sets of experimental data, the statistical distribution patterns of maximum utilized adhesion on the rail surface are obtained, and a method for analyzing wheel-rail adhesion redundancy based on normal distribution is proposed. The study analyzes the utilization of traction/braking adhesion, as well as adhesion redundancy, for different medium under small creepage and large slip conditions. Based on these findings, relevant measures for the reasonable and optimized utilization of adhesion are derived.

Findings

When the third-body medium exists on the rail surface, the train should adopt the low-level service braking to avoid the braking skidding by extending the braking distance. Compared with the current adhesion control strategy of small creepage, adopting appropriate strategies to control the train’s adhesion coefficient near the second peak point of the adhesion coefficient-slip ratio curve in large slip can effectively improve the traction/braking adhesion redundancy and the upper limit of adhesion utilization, thereby ensuring the traction/braking performance and operation safety of the train.

Originality/value

Most existing studies focus on the wheel-rail adhesion coefficient values and variation patterns under different medium conditions, without considering whether the rail surface with different medium can provide sufficient traction/braking utilized adhesion coefficient for the train. Therefore, there is a risk of traction overspeeding/braking skidding. This study analyzes whether the rail surface with different medium can provide sufficient traction/braking utilized adhesion coefficient for the train and whether there is redundancy. Based on these findings, relevant measures for the reasonable and optimized utilization of adhesion are derived to further ensure operation safety of the train.

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Article
Publication date: 30 July 2024

Yuting Lv, Xing Ouyang, Yaojie Liu, Ying Tian, Rui Wang and Guijiang Wei

This paper aims to investigate the differences in hot corrosion behavior of the GTD222 superalloy and TiC/GTD222 composite in a mixed salt of 75% Na2SO4 and 25% K2SO4 at 900°C.

62

Abstract

Purpose

This paper aims to investigate the differences in hot corrosion behavior of the GTD222 superalloy and TiC/GTD222 composite in a mixed salt of 75% Na2SO4 and 25% K2SO4 at 900°C.

Design/methodology/approach

The GTD222 superalloy and TiC/GTD222 nickel-based composite were prepared using selective laser melting (SLM). Subsequently, the hot corrosion behavior of the two alloys was systematically investigated in a salt mixture consisting of 75% Na2SO4 and 25% K2SO4 (Wt.%) at 900°C.

Findings

The TiC/GTD222 composite exhibited better hot corrosion resistance compared to the GTD222 superalloy. First, the addition of alloying elements led to the formation of a protective oxide film on the TiC/GTD222 composites 20 h before hot corrosion. Second, TiC/GTD222 composite corrosion surface has a higher Ti content, after 100 h of hot corrosion, the composite corrosion surface Ti content of 10.8% is more than two times the GTD222 alloy 4% Ti. The Ti and Cr oxides are tightly bonded, effectively resisting the erosion of corrosive elements.

Originality/value

The hot corrosion behavior of GTD222 superalloy and TiC/GTD222 composites prepared by SLM in a mixed salt of 75% Na2SO4 and 25% K2SO4 was studied for the first time. This study provides insights into the design of high-temperature alloys resistant to hot corrosion.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 6
Type: Research Article
ISSN: 0003-5599

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Article
Publication date: 5 December 2023

Yuting Lv, Yaojie Liu, Rui Wang, Hongyao Yu, Zhongnan Bi, Guohao Liu and Guangbao Sun

This paper aims to design a novel TiC/GTD222 nickel-based high-temperature alloy with excellent hot corrosion resistance by incorporating appropriate amounts of C, Al and Ti…

131

Abstract

Purpose

This paper aims to design a novel TiC/GTD222 nickel-based high-temperature alloy with excellent hot corrosion resistance by incorporating appropriate amounts of C, Al and Ti elements into GTD222 alloy.

Design/methodology/approach

The composite material was prepared using the selective laser melting (SLM) technology, followed by a hot isostatic pressing (HIP) treatment. Subsequently, the composite underwent a hot corrosion test in a 75% Na2SO4 + 25% NaCl mixed salt environment at 900 °C.

Findings

The HIP-SLMed TiC/GTD222 composite exhibits a relatively low weight loss rate. First, the addition of alloying elements facilitates the formation of multiple protective oxide films rich in Al, Ti and Cr. These oxide films play a crucial role in enhancing the material’s resistance to hot corrosion. Second, the HIP treatment results in a reduction of grain size in the composite and an increased number of grain boundaries, which further promote the formation of protective films.

Originality/value

The hot corrosion behavior of the TiC/GTD222 nickel-based composite material prepared through SLM and HIP processing has not been previously studied. This research provides a new approach for designing nickel-based superalloys with excellent hot corrosion resistance.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

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