Search results

This paper aims to evaluate the effect of precursors on the anticorrosion property of silica encapsulated waterborne aluminium pigments (WBAPs).

The silica encapsulated WBAPs were prepared using different siloxanes as precursors. The anchorage and compactness of silica films on aluminium flakes were characterized by optical microscopy, scanning electron microscopy and N2 adsorption-desorption. The anticorrosion property and glossiness of WBAPs were evaluated.

The effect of precursors on anticorrosion property of silica encapsulated WBAPs is reflected from the anchorage and the compactness of silica on aluminium flakes surface. Furthermore, the structure of γ-aminopropyl triethoxysilane benefits the anchorage and the compatibility between pigment and acrylic resin. Neither high nor low ratio of tetraethoxysilane/γ-aminopropyl triethoxysilane is favourable to the anchorage and formation of dense silica film on the aluminium flakes surface. To obtain perfect WBAP, the precursors of silica must be carefully selected.

Only four kinds of precursors were used in this work; other precursors could also be studied.

The investigation results provide theoretical basis to obtain excellent WBAPs.

The method to investigate anticorrosion property of WBAPs that is based on the effect of precursors on the performance of silica was novel.

The purpose of this study is to evaluate the role of encapsulation pH and iron source on the anchorage mode and performance of iron oxide-encapsulated aluminium pigments.

The coloured waterborne aluminium pigments were prepared at pH 5-7.5 by using FeSO₄ and FeCl₃ as iron source. The anchorage mode of iron oxides on aluminium was characterized using optical microscopy, scanning electron microscopy, Fourier transform infrared spectroscopy and X-ray diffraction. Furthermore, the pigmentary performance was characterized through anticorrosion test and multi-angle spectroscopy.

Diaspore and boehmite could form from H₂O₂ oxidizing aluminium. Both low pH and FeSO₄ systems are beneficial for diaspore, inducing green rust anchor on the aluminium to form goethite. Either in FeSO₄ or FeCl₃ system, slightly high pH is beneficial for the formation of boehmite, which occurred together with ferrihydrite to form denser coating with yellowness and excellent anticorrosion property. At pH above 7, the formation of dendritic iron oxide is detrimental to the anticorrosion property and the glossiness.

Only FeSO₄·7H₂O and FeCl₃·6H₂O as iron sources were explored.

The investigation results provide theoretical basis to obtain excellent chromatic waterborne aluminium pigments.

The method for investigation of encapsulation mechanism by surveying the structure of iron oxides on aluminium, which varies with the pH of the system and iron sources, is novel.

Atherosclerosis tends to occur in the distinctive carotid sinus, leading to vascular stenosis and then causing death. The purpose of this paper is to investigate the effect of sinus sizes, positions and hematocrit on blood flow dynamics and heat transfer by different numerical approaches.

The fluid flow and heat transfer in the carotid artery with three different sinus sizes, three different sinus locations and four different hematocrits are studied by both computational fluid dynamics (CFD) and fluid-structure interaction (FSI) methods. An ideal geometric model and temperature-dependent non-Newtonian viscosity are adopted, while the wall heat flux concerning convection, radiation and evaporation is used.

With increasing sinus size, the average velocity and temperature of the blood fluid decrease, and the area of time average wall shear stress (TAWSS)with small values decreases. As the distances between sinuses and bifurcation points increase, the average temperature and the maximum TAWSS decrease. Atherosclerosis is more likely to develop when the sinuses are enlarged, when the sinuses are far from bifurcation points, or when the hematocrit is relatively large or small. The probability of thrombosis forming and developing becomes larger when the sinus becomes larger and the hematocrit is small enough. The movement of the arterial wall obviously reduces the velocity of blood flow, blood temperature and WSS. This study also suggests that the elastic role of arterial walls cannot be ignored.

The hemodynamics of the internal carotid artery sinus in a carotid artery with a bifurcation structure have been investigated thoroughly, on which the impacts of many factors have been considered, including the non-Newtonian behavior of blood and empirical boundary conditions. The results when the FSI is considered and absent are compared.