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The purpose of this research is to synthesize Al₂O₃-ZnO thick films, study the effect of doping and optical excitation on their sensing properties and introduce an attractive candidate for acetone detection in practice.

ZnO nanoparticles doped with Al₂O₃ were prepared by sol-gel method and characterized via X-ray diffraction and field-emission scanning electron microscopy. The sensing properties to acetone were investigated with an irradiation of UV. The sensing mechanism was also discussed with UV-Vis spectroscopy.

The doping of Al₂O₃ promoted the sensing response and stability of ZnO nanoparticles. The optimum performance was obtained by 4.96 Wt.% Al₂O₃-ZnO. The response to acetone (1,000 ppm) was significantly increased to 241.81, even just at an operating temperature of 64°C. It was also demonstrated that optical excitation with UV irradiation greatly enhanced the sensing response and the sensitivity can reach up to 305.14.

The sensor fabricated from 4.96 Wt.% Al₂O₃-ZnO exhibited excellent acetone-sensing characteristics. It is promising to be applied in low power and miniature acetone gas sensors.

In the present research, the optimum performance was obtained by 4.96 Wt.% Al₂O₃-ZnO at a low operating temperature of 64°C. The sensing properties were enhanced significantly with optical excitation, and the sensing mechanism was discussed with UV-Vis spectroscopy which has been reported rarely before.

The purpose of this paper is to illustrate that some enterprise unions in South China, as strategic labor actors, made local progress in collective bargaining, but further elaborates on why gainful bargaining would require a more systematic understanding of the prevailing industrial structure.

This paper is mainly drawn from intensive site visits and 51 in-depth interviews in 2013 and 2014, and several follow-ups up to 2018. Three cases of collective bargaining, featuring different union strategies of assertive negotiation, informal cooperation and direct confrontation, are discussed in detail.

The study illustrates that viable collective bargaining with worker-supported unions is possible in China. However, the effectiveness of bargaining does not count on this alone; the supply chain structure also imposes significant constraints, mainly by narrowing the bargaining scope of each supplier and differentiating the structural power of their unions. In these cases, institutionalized union coordination beyond individual suppliers is proposed.

These cases began as post-strike bargaining in Japanese auto supply chains and became the frontier of industrial relations in China. The impact of the supply chain in different sectors or regions requires further study.

This paper draws attention to the effect of an “invisible” but increasingly significant factor, industrial structure, on enterprise-level collective bargaining in China, unlike many previous criticisms of unwillingness or incompetence among labor actors.