Xie Xuejun, Yuanlin Zhang, Rui Wang, Yu Zhang and Mianzhao Ruan
The hollow copper wires of the generator are seriously corroded in cooling water. This paper aims to explore the mechanism of copper corrosion by thermodynamic calculation and…
Abstract
Purpose
The hollow copper wires of the generator are seriously corroded in cooling water. This paper aims to explore the mechanism of copper corrosion by thermodynamic calculation and kinetic experiments and to find out the precise pH range for preventing corrosion of copper in stator internal water and dual internal water cooled generators.
Design/methodology/approach
Thermodynamic and kinetic studies were carried out for the purpose of preventing the corrosion of hollow conducting copper wires in the internal cooling water. Thermodynamic calculation results demonstrate hollow copper wires electrochemically corroded by oxygen rather than acids (H+) and find out a precise anti-corrosion pH range. Kinetic experiments research on the effect of the pH value and oxygen concentration on corrosion and protection methods of copper in desalted water.
Findings
Research results demonstrate that, in the internal cooling water, hollow copper wires are electrochemically corroded by oxygen, rather than acids (H+). The method of preventing copper from corrosion in the desalted water is to control the pH value of the stator cooling water and the dual water inner cooling water between 7.86-8.86 and 7.86-9.26, respectively.
Originality/value
The thermodynamic calculation and potentiometric-pH diagram are used to obtain the accurate pH range of the inner cooling water and inner cooling water in the inner cooling water system. The kinetic experiments provide data support for the effect of temperature, pH value and oxygen concentration.
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Xie Xuejun*, Xiao Peng*, He Jie, Xiao Wen, Fu Qiang and Zou Pinguo
– To study the inhibition effect and mechanism of the Momordica charantia extract (BM) to 20 A carbon steel in 5 per cent HCl.
Abstract
Purpose
To study the inhibition effect and mechanism of the Momordica charantia extract (BM) to 20 A carbon steel in 5 per cent HCl.
Design/methodology/approach
The weight loss, polarization curve, infrared spectrum (IR) analysis and X-ray photoelectron spectrum (XPS) analysis were carefully investigated to indicate the inhibition effect and mechanism of the BM to 20 A carbon steel in 5 per cent HCl.
Findings
BM was composed of C, N and O. Functional groups such as N–H and C=O were found in BM. The inhibition efficiency increased with the increasing concentration of BM. BM behaved as a mixed-type inhibitor, and the inhibition of BM to 20 A carbon steel might be its adsorption through the coordinate covalent bonding among the lone pair electrons of N and O and the empty 3d orbits of Fe, and the adsorption on the surface of 20 A carbon steel obeyed the Langmuir isotherm equation.
Research limitations/implications
The inhibition of the BM to 20 A carbon steel in 5 per cent HCl.
Practical implications
BM could be used in 5 per cent HCl to prevent 20 A carbon steel from corrosion.
Social implications
BM could be used in the chemical cleaning of the boilers to prevent the thermal equipments from corrosion.
Originality/value
The inhibition effect and mechanism of the BM to 20 A carbon steel were studied by the weight loss, polarization curve, IR analysis and XPS analysis. BM was composed of C, N and O. Functional groups such as N–H and C=O were found in BM. BM behaved as a mixed-type inhibitor. The inhibition efficiency increased with the increasing concentration of BM, and the adsorption on the surface of 20 A carbon steel obeyed the Langmuir isotherm equation.
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Xuejun Xie, Ling Pang, Shunan Cao, Wanqin Yang, Min Yan, Xunjie Gong and Keru Peng
The purpose of this paper is to present a study of corrosion inhibition of carbon steel in hydrochloric acid by some benzene nitriles using the quantum chemistry calculation.
Abstract
Purpose
The purpose of this paper is to present a study of corrosion inhibition of carbon steel in hydrochloric acid by some benzene nitriles using the quantum chemistry calculation.
Design/methodology/approach
The molecular structure and inhibition mechanism, and the relationship between inhibition efficiency of some benzene nitriles on carbon steel in the hydrochloric acid, were studied from a microcosmic viewpoint using the quantum chemistry calculation.
Findings
The calculation results showed that the inhibition efficiency of benzene nitriles on carbon steel in hydrochloric acid could be expressed by σN and ELUMO, and the greater σN absolute value and the lesser the value of ELUMO, then the greater the efficiency of the inhibitor. The regression equation for benzene nitriles is: η=2.665056−0.4447122ELUMO−10.92817σN r=0.9953128.
Originality/value
The paper offers insights into the application of the quantum chemistry calculation.
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Xie Xuejun, He Jie, Lv Ke and Pan Ling
The purpose of this paper is to study the inhibitive property of the mixture of an imidazole derivative (IMA) and benzotriazole (BTA) to the copper in deionised water.
Abstract
Purpose
The purpose of this paper is to study the inhibitive property of the mixture of an imidazole derivative (IMA) and benzotriazole (BTA) to the copper in deionised water.
Design/methodology/approach
Static mass‐loss tests, electrochemical tests and surface analysis are used to study the inhibitive property of the mixture of an IMA and BTA to copper in deionised water.
Findings
There is a synergistic inhibitive effect on inhibition of the copper by the IMA and BTA in deionised water, and the mixture of the IMA and BTA is an effective inhibitor that mainly hinders the anode reaction.
Practical implications
The mixture of the IMA and BTA is an effective inhibitor and can be used to prevent copper from corrosion in deionised water.
Originality/value
The mixture of the IMA and BTA is an effective inhibitor and should be suitable for use in the cooling water of an electricity generator unit to prevent corrosion of the copper conductors.
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Xie Xuejun, Yang Wanqin, Cao Shunan, Pan Ling, Gong Xunjie and Peng Keru
To study the corrosion behavior and discuss the corrosion mechanism of No. 20 carbon steel in water in the presence of sulfide ions.
Abstract
Purpose
To study the corrosion behavior and discuss the corrosion mechanism of No. 20 carbon steel in water in the presence of sulfide ions.
Design/methodology/approach
The mass‐loss method, electrochemical tests and surface analysis were used to study the corrosion behavior and discuss the corrosion mechanism of No. 20 carbon steel in water in the presence of sulfide ions.
Findings
General corrosion occurred when No. 20 carbon steel was immersed in both test solutions (concentrated sample with S2− added to 0.8 mg/L, and pure concentrated sample with no S2− added). The presence of S2− in test solutions accelerated the corrosion rate of No. 20 carbon steel.
Practical implications
In order to prevent No. 20 carbon steel in water with S2− from corroding, S2− must be removed.
Originality/value
It was found that the presence of S2− in test solutions accelerated the corrosion rate of No. 20 carbon steel in this paper. Therefore, when water containing sulfide ions is used as the source of make‐up water and cooling water, S2− in water must be removed to prevent the pipelines and facilities from corroding. This means the research results can offer theoretical guidelines for the prevention of pipelines and facilities in the power plant from corroding.
Xie Xuejun, Cao Shunan, Pan Ling, Gong Xunjie and Peng Keru
The inhibition mechanism and the relationship between the inhibition efficiency of para‐chlorobenzene nitriles on carbon steel in hydrochloric acid, and their molecular structure…
Abstract
The inhibition mechanism and the relationship between the inhibition efficiency of para‐chlorobenzene nitriles on carbon steel in hydrochloric acid, and their molecular structure, were studied by microscopy and quantum chemistry calculations. The inhibition of carbon steel was achieved by chemisorption of the para‐chlorobenzene nitriles onto the surface of the carbon steel. The greater was the σN (absolute value) and the less the ELUMO value, the greater was the inhibition efficiency.
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Xuejun Xie, Lijun Du, Ling Pan, Shunan Cao, Min Yan and Wanqin Yang
This paper aims to study the corrosion behaviour of copper alloys HSn70‐1 + As and B30 in water with sulphide.
Abstract
Purpose
This paper aims to study the corrosion behaviour of copper alloys HSn70‐1 + As and B30 in water with sulphide.
Design/methodology/approach
The mass‐loss method, electrochemical tests and surface analysis were used to study the corrosion behaviour of copper alloys HSn70‐1 + As and B30 in water with sulphide.
Findings
Dezincification corrosion occurred on HSn70‐1 + As both in water with or without sulphide, and sulphide in water accelerated corrosion, while for the copper alloy B30, the corrosion rates were very small both in water with or without sulphide, although corrosion was also accelerated by sulphide in water.
Practical implications
In order to prevent copper alloys HSn70‐1 + As and B30 in water with sulphide from corroding, S2− must be removed.
Originality/value
It was found that sulphide in water accelerated the corrosion of copper alloys HSn70‐1 + As and B30 in this paper. Therefore, when water containing sulphide is used as the source of make‐up water and cooling water, S2− in water must be removed to prevent the pipelines and facilities from corroding. This means that the research results can offer theoretical guidelines for the prevention of pipelines and facilities in the power plant from corroding.
Xiaoqian Ye, Ling Li and Xuejun Tan
Drawing on recent literature and empirical data, the purpose of this paper is to explore the relationships between perceived organizational support (POS), perceived…
Abstract
Purpose
Drawing on recent literature and empirical data, the purpose of this paper is to explore the relationships between perceived organizational support (POS), perceived overqualification (POQ) and turnover intentions (TI) in repatriates working in multinational corporations (MNCs).
Design/methodology/approach
Survey data were collected from 145 repatriates who had been contacted beforehand from MNCs in China. Structural equation modeling and hierarchical regression are used to examine the data.
Findings
It is shown that POQ and POS both affect repatriates TI, with POQ having the stronger effect, while POS plays a mediatory role between POQ and TI. Specifically, under the same POQ, repatriates TI will decrease as the POS increases.
Research limitations/implications
The study design is cross-sectional and based on self-reporting, which makes causal explanations of the results difficult.
Practical implications
POQ and POS are both shown to influence TI, with POQ having the greater effect. This means managers can offset the effect of repatriates POQ on TI by providing better support and assistance, which can help MNCs reduce repatriates TI and retain employees.
Originality/value
This paper examines the antecedents of TI, and adds valuable new insights to the literature on repatriation through its research data, offering further evidence that managers in transnational corporations should pay more attention to organizational support policy on repatriates in order to reduce their turnover.
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The purpose of this paper is to develop a systematic understanding of the mechanisms through which high-performance work systems (HPWSs) facilitate the incremental and radical…
Abstract
Purpose
The purpose of this paper is to develop a systematic understanding of the mechanisms through which high-performance work systems (HPWSs) facilitate the incremental and radical innovative capabilities of organizations. Using a knowledge-based view of the firm, the paper introduces the mediating role of intellectual capital (composed of human, organizational and social capital) while examining this issue.
Design/methodology/approach
Data were collected using a questionnaire survey approach from 164 firms in the People's Republic of China. The paper used analyses based on structural equation modeling to measure the main constructs and test the hypothesized relationships among the variables.
Findings
The results indicate that HPWSs contribute to both the incremental and radical innovative capabilities of organizations. In addition, intellectual capital mediates the relationships between HPWSs and different types of innovative capabilities. Specifically, organizational and social capital mediate the relationship between HPWSs and incremental innovative capability, whereas social capital mediates the relationship between HPWSs and radical innovative capability.
Originality/value
The study supports and expands on the strategic human resource management (SHRM) literature and knowledge-based view of the firm in terms of whether, why and how HPWSs can develop a competitive advantage on the basis of innovation.
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Xuejun Fan and De Du
Focusing on the spillover effects between the CSI 500 stock index futures market and its underlying spot market during April to September 2015, the purpose of this paper is to…
Abstract
Purpose
Focusing on the spillover effects between the CSI 500 stock index futures market and its underlying spot market during April to September 2015, the purpose of this paper is to explore whether Chinese stock index futures should be responsible for the 2015 stock market crash.
Design/methodology/approach
Using both linear and non-linear econometric models, this paper empirically examines the mean spillover and the volatility spillover between the CSI 500 stock index futures market and the underlying spot market.
Findings
The results showed the following: the CSI 500 stock index futures market has significant one-way mean spillover effect on its spot market. The volatility in CSI 500 stock index futures market also has a significant positive spillover effect on its spot stock market, and the mean value of dynamic correlation coefficient between the two market volatility is 0.4848. The spillover effect of the CSI 500 stock index futures market on the underlying spot market is significantly asymmetric, characterized by relatively moderate and slow during the period of the markets rising, yet violent and rapid during the period of the markets falling. The findings suggest that although the stock index futures itself was not the “culprit” of Chinese stock market crash in 2015, its existence indeed accelerated and exacerbated the stock market’s decline under the imperfect trading system.
Originality/value
Different from the existing literature mainly focusing on CSI 300 stock index futures, this paper empirically examines the impact of the introduction of CSI 500 stock index futures on 2015 Chinese stock market crash for the first time.