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The purpose of this paper is to study the antirust, tribological performance and anti-wear (AW) mechanism of the of soybean lecithin (SL) as a kind of multifunctional lubricant additive.

As a kind of multifunctional lubricant additive, the antirust performance of SL was tested according to ASTM D 665, and meanwhile, its tribological performances were also evaluated by Optimol SRV-I oscillating reciprocating friction and wear tester and four ball tester. The worn steel surfaces were investigated by scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS).

The results showed that the SL exhibited excellent antirust properties in different base stock, and could effectively improve the AW and extreme pressure (EP) performances. The results of SEM and XPS indicated that a protective film was formed between steel-steel friction pair during the tribological test.

This paper first investigated the antirust properties and the tribological mechanism of the SL as a kind of multifunctional lubricant additive, which can be very useful and will promote the application of SL in lubricant industry.

The purpose of this paper is to investigate the tribological properties of Si₃N₄ sliding against Dy−sialon ceramics lubricated by two novel phosphazenes bridged fluorophenoxycyclotriphosphazene (coded as L‐2P) and metal halide‐stabilized linear phosphazene derivatives (coded as LMZn‐3). The traditional phosphazene tetrakis (3‐trifluoromethylphenoxy)‐bis(4‐fluorophenoxy) – cyclotriphosphazene (X‐1P) was also tested as the reference.

The lubricity characteristics of phosphazene derivatives were evaluated on an Optimol SRV oscillating friction and wear tester. The morphology of the worn sialon surface was analyzed with a scanning electron microscope (SEM) and X‐ray photoelectron spectroscope (XPS).

The two novel phosphazenes are effective lubricants for Dy−sialon and show superior tribological properties to traditional phosphazene X‐1P and glycerol. Among all lubricants, linear phosphazene LMZn‐3 exhibits the lowest wear volume loss at 20°C or 100°C. Moreover, LMZn‐3 and L‐2P show much better antiwear ability than X‐1P under higher load than 60N. The decreased friction coefficient and wear volume of Dy−sialon ceramics under lubrication of the phosphazene lubricants are attributed to the tribochemical products mainly consisting of organic oxyfluoride or carbonfluoride species and silicon fluoride.

The paper deals with only limited compounds. The paper works on the subject progressively to explore more combinations for better tribological properties.

The phosphazene derivatives present better tribological performance used as base oils and additives.

There are few data about other phosphazene with different structures, such as bridged cyclotriphosphazene and metal halide‐stabilized linear phosphazene, used as lubricants for ceramics materials.

The purpose of this paper is to study the influences of test conditions to the tribological behavior of LaF₃ nanoparticles as an additive to a polyalphaolefin (PAO).

An Optimol‐SRV4 oscillating friction and wear tester (SRV) were used to investigate the tribological properties of LaF₃ nanoparticles as an additive in a polyalphaolefin (PAO). The 3‐D morphologies and wear loss volume of the worn scar were measured using a surface profilometer. The chemical state and the intensity of La and F elements on worn surface after friction test was investigated with X‐ray photoelectron spectroscopy to interpret the possible mechanisms of friction‐reduction and anti‐wear with LaF₃ nanoparticles.

The experimental results show that LaF₃ nanoparticles added to PAO exhibit excellent load‐carrying capacity, anti‐wear and friction‐reduction properties. LaF₃ nanoparticles deposited on the worn surface under lower test temperature during the friction test, and higher applied load, higher test frequency and longer test duration are propitious to the deposition of LaF₃ nanoparticles accumulated on the rubbing surface. Under higher temperature, a complicated tribo‐chemical reaction occurred during the friction process, the tribo‐chemical reaction product of La₂O₃ deposit on worn surface, which also exhibits good lubricating performance.

This paper investigates the tribological properties of LaF₃ nanoparticles as green oil additive in poly‐alpha‐olefin (PAO) under variable temperature, applied load, sliding speed and sliding duration. The results could be very helpful for the further applications of LaF₃ nanoparticles additives in industry.

The purpose of this paper is to study the tribological performance and anti‐wear mechanism of Cu nanoparticles as lubricating oil additives.

An end‐face wear testing apparatus is used to measure the tribological properties of Cu nanoparticles as lubricating oil additives and using a commercial SJ 15W/40 gasoline engine oil for comparison. Electrical contact resistance (ECR) is measured on a universal nano and micro tester‐2 tribometer to detect the formation of tribo‐film generated by Cu nanoparticulate additive. The worn steel surfaces are investigated by scanning electron microscope (SEM), energy dispersive spectra (EDS) and X‐ray photoelectron spectroscopy (XPS).

The results show that Cu nanoparticles used as an oil additive can improve the anti‐wear and friction‐reduction performance of SJ 15W/40 gasoline engine oil remarkably. The results of SEM, EDS and XPS show that a deposit film containing metallic copper can form on the worn surface, which has a film thickness of about 120 nm.

This investigation establishes a baseline of Cu nanoparticles used as lubricating oil additives under face‐to‐face contact work conditions. Thus, the results are reliable and can be very useful for further applications of Cu nanoparticle additives in industry.

The aim of this paper was to inhibit the serious corrosion of conventional ionic liquids, a series of new ionic liquids (ILs) containing the triazole functionality, as the anti-corrosion groups were synthesized in this work.

It is well known that nitrogen and sulfur containing organic compounds have been traditionally used as corrosion inhibitors. Among them, triazole derivatives are most often used as corrosion inhibitors. To alleviate the corrosion of the ILs and further improve the anti-wear property, the authors prepared a series of imidazolium ILs modified with the triazole functionality in the present study.

The corrosion behavior of the ILs was evaluated with the iron disk corrosion test and their tribological properties were investigated on an Optimol SRV IV oscillating friction and wear tester at elevated temperatures. The results showed that the ILs with the triazole functionality could effectively reduce the corrosion and exhibit a smaller friction coefficient and wear volume than the unmodified counterpart. The ILs containing the triazole functionality can be used as the single component anti-corrosion base oils even at elevated temperatures.

The results showed that the ILs with the triazole functionality could effectively reduce the corrosion and exhibit a smaller friction coefficient and wear volume than the unmodified counterpart. The ILs containing the triazole functionality can be used as the single component anti-corrosion base oils even at elevated temperatures.

The purpose of this paper is to synthesize a series of cyclophosphazene derivatives with better tribological properties.

To improve the adsorptivity to substrate, a series of cyclophosphazene derivatives substituted with ionic liquids were synthesized. The lubricity characteristics of phosphazene derivatives were evaluated on an Optimol SRV IV oscillating friction and wear tester. Scanning electron microscope and X‐ray photoelectron spectroscope analyses were conducted to examine the morphology and chemical composition of the wear scars and the possible tribochemical changes involved in the friction process.

Alkoxycyclophosphazene derivatives substituted with ionic liquids synthesized in the present work show better antiwear ability and load‐carrying capacity in steel‐steel contacts. The density of ion pairs plays an important role on tribological properties.

The paper deals with only a limited compounds and steel‐steel contacts. The paper works on the subject progressively to explore more combinations for better tribological properties.

All the cyclophosphazene derivatives present better tribological performance and could be used as base oils, such as hard disk surface lubricants.

Ionic liquids are introduced to cyclophosphazene derivatives in this paper. This is a new method to improve the tribological properties of cyclophosphazene derivatives.

The purpose of this paper is to examine the tribological behavior of the synthetic chlorine‐ and fluorine‐containing silicon oil as an aerospace lubricant.

The chlorinated‐phenyl and methyl terminated silicone oil (CPSO), chlorinated‐phenyl and trifluorinated‐propyl with methyl terminated silicone oil (FCPSO) were prepared. Their physical properties such as saturated vapor pressure and the evaporation weight loss were evaluated. The tribological properties of the silicon oils under moderate load were investigated with an Optimol SRV oscillating friction and wear tester, as well as Four‐ball friction and wear tester according to the standard method of ASTM D 4172 under higher load. The elemental composition generated on steel ball surface were analyzed on a scanning electron microscope with a Kevex energy dispersive X‐ray analyzer attachment (SEM/EDS), and the chemical nature of elements on worn surface lubricated with FCPSO were studied by X‐ray photoelectron spectrometer (XPS).

It is found that the CPSO and FCPSO show good tribological behavior for steel/CuSn alloy tribological pairs and are superior to hosphazene (X‐1P) and perfluoropolyether in terms of friction‐reduction ability and anti‐wear performance. The anti‐wear performance of FCPSO as lubricants for steel‐steel contacts is superior to CPSO. The EDS results showed existence of F and Si on the worn surface with lubrication of FCPSO, while XPS results indicated the occurrence of tribochemical reaction of FCPSO with friction pair during sliding process with the formation of FeCl₂, FeF₂ and the absorption silicon oil films on the lubricated metal surface.

The results substantiate that chemical reactive elemental such as chlorine or fluorine, which is substituted into silicon oil, helps to improve the anti‐wear and load‐carrying capacity of the liquid lubricant. So the excellent thermal stability, low‐temperature fluidity, very low‐saturated vapor pressure and excellent lubricity for steel/CuSn alloy of the silicon oil of FCPSO and CPSO make it an attractive alternative to conventional liquid lubricant for space mechanism.

The purpose of this paper is to study the tribological performance of tri(hydroxymethyl)propane esters containing boron and nitrogen as lubricant additives in rapeseed oil.

Thermal degradation tests were performed to analyze their thermal stability using a thermo‐gravimetric analyzer. Two four‐ball testers were used to measure the tribological properties of tri(hydroxymethyl)propane esters containing boron and nitrogen as lubricant additives in rapeseed oil. The worn surfaces of steel balls were investigated by scanning electron microscope (SEM) and X‐ray photoelectron spectroscopy (XPS).

The results show that the tri(hydroxymethyl)propane esters containing boron and nitrogen have excellent thermal stability, good antiwear performance, improve the load‐carrying capacity, and possess friction‐reducing behavior especially at 98 N when they are used as additives in rapeseed oil. The results of XPS show that the adsorption and tribochemical reactions have been occurred to form a complex boundary lubrication film.

The paper illustrates two novel tri(hydroxymethyl)propane esters which contain B and N elements used as additives in rapeseed oil. The results are useful for further applications in advanced environment friendly lubricating oils and additives.

In order to formulate ashless GL‐5 gear oils and high‐pressure antiwear hydraulic oils, the performances of extreme‐pressure (EP) and antiwear (AW), and the thermal and hydrolytic stability of series ashless P‐containing additives with different chemical structures are investigated by four‐ball EP test, high‐temperature oxidation test and hydrolytic stability test.Design/methodology/approach – Series ashless P‐containing EP and AW additives with different chemical structures were designed and selected, their EP and AW performances, high‐temperature oxidation, hydrolytic stability compared with the traditional zinc dialkyldithiophosphate (ZDDP) additive were investigated according to relative testing standards, and their applied performances compared with the traditional ZDDP additive were investigated using the CRC L‐37 gear oil rear axle test, Deniso T‐5D Vane Pump test and Deniso P‐46 Piston Pump test.Findings – The results indicate that two ashless neutral thiophosphate esters exhibit excellent EP and AW performances, high‐temperature oxidation and hydrolytic stability. The application performance of these P‐containing additives is also examined by CRC L‐37 rear axle test. The results show that only the oil samples with the addition of neutral thiophosphate esters correspondingly to API GL‐5 automotive gear oil can pass the CRC L‐37 gear oil rear axle test successfully. The results of further Deniso T‐5D Vane Pump and Deniso P‐46 Piston Pump tests prove that the ashless neutral thiophosphate ester is a very effective EP/AW additive for high‐pressure antiwear hydraulic oil. In one sentence, the neutral thiophosphate ester is the excellent ashless EP/AW additive and the useful substitute for ZDDP.Research limitations/implications – From the results, the neutral thiophosphate ester is the excellent ashless EP/AW additive and the useful substitute for ZDDP, however, their tribological mechanicsm and their synergic effect with the other additives used in the test base oil for the applied performance tests may be done in the future works.Practical implications – These results may be useful for the researchers to formulate some ashless high EP/AW industrial oils.Originality/value – This paper proves that the two ashless neutral thiophosphate esters exhibit excellent EP and AW performances, high‐temperature oxidation and hydrolytic stability, and is the useful substitute for ZDDP for formulating ashless GL‐5 gear oils and high‐pressure AW hydraulic oils.

The purpose of this paper is to study the tribological behavior and mechanism of water‐soluble bismuth dithiophosphate as the additive of water‐based cutting fluid in aluminum alloy tapping.

Comparable investigation has been made on the lubrication performance of bismuth dithiophosphate and sodium dithiophosphate in aluminum alloy tapping. The aluminum alloy‐machined surface finish was observed on scanning electron microscope. The films on the work‐piece‐machined surface and the tap tool working surface were analyzed by X‐ray photoelectron spectroscopy.

The results indicated that the water medium containing 1 wt% the prepared water‐soluble bismuth dithiophosphate exhibited better tapping efficiency than the liquid paraffin containing 2.5 wt% chlorinated paraffin and 2.5 wt% sulfurized olefin. The bismuth sulfide component in the reaction film on the tap working surface plays a leading role in elevating the tapping efficiency and improving the machined surface finish.

The paper is restricted to the lubrication performance of bismuth dithiophosphate as the water‐based cutting fluid additive in 2024 aluminum alloy tapping.

The test method adopted is very close to the machined method applied in industry. The test results show that the bismuth dithiophosphate can obviously improve the tapping efficiency and the machined surface finish. Thus, it can be applied to the aluminum alloy cutting in automotive and aviation.

An attempt has been made to identify the chemical reaction film sourced from bismuth element and dithiophosphate group on the work‐piece‐machined surface and the tool working surface and their contribution to enhancing the tapping efficiency and improving the machining surface finish. This is helpful to the designers and the practitioners of the additives of metalworking fluid.