Search results

The purpose of this study was to select an atmospheric corrosion evaluation methodology and to establish a range of relative corrosion penetration and/or progress values, which could be used as reference in the selection of materials for the civil construction industry.

Salt spray, field tests, accelerated cyclic tests and accelerated field tests were used to evaluate atmospheric corrosion resistance of civil construction materials. The cyclic accelerated test and the field test with saline solution spray were found to be appropriate for atmospheric corrosion resistance evaluation.

The corrosion resistance of aluminium killed mild steel, aluminium killed copper added steel, and electrogalvanized steels, all phosphatized and painted, were evaluated by field and accelerated corrosion tests. Of the materials studied, aluminium killed mild steel showed the least resistance to atmospheric corrosion. The use of aluminium killed copper added steel is recommended for material specification in the civil construction industry.

Salt sprays are not adequate to evaluate atmospheric corrosion resistance. There are other cyclic tests that could be tested in future work.

Brazilian technical standards, which specify the metallic materials used in the civil construction industry, will be changed in order to include the construction steel corrosion resistance evaluation methodology, which is proposed in this paper. As a result, the tendency of the construction materials lifetime is set to increase.

This paper contributes to the improvement of the Brazilian Technical Standard by the inclusion of an atmospheric corrosion resistance requirement.

We present a critical literature review debating Brazilian research on social and environmental accounting (SEA). The aim of this study is to understand the role of politics in the construction of hegemonies in SEA research in Brazil. In particular, we examine the role of hegemony in relation to the co-option of SEA literature and sustainability in the Brazilian context by the logic of development for economic growth in emerging economies. The methodological approach adopts a post-structural perspective that reflects Laclau and Mouffe’s discourse theory. The study employs a hermeneutical, rhetorical approach to understand and classify 352 Brazilian research articles on SEA. We employ Brown and Fraser’s (2006) categorizations of SEA literature to help in our analysis: the business case, the stakeholder–accountability approach, and the critical case. We argue that the business case is prominent in Brazilian studies. Second-stage analysis suggests that the major themes under discussion include measurement, consulting, and descriptive approach. We argue that these themes illustrate the degree of influence of the hegemonic politics relevant to emerging economics, as these themes predominantly concern economic growth and a capitalist context. This paper discusses trends and practices in the Brazilian literature on SEA and argues that the focus means that SEA avoids critical debates of the role of capitalist logics in an emerging economy concerning sustainability. We urge the Brazilian academy to understand the implications of its reifying agenda and engage, counter-hegemonically, in a social and political agenda beyond the hegemonic support of a particular set of capitalist interests.

The purpose of this paper is to study the corrosion of the coupling of two different types of stainless steel, austenitic and ferritic, used in the fabrication of water reservoirs in the solar energy industry.

Potentiodynamic polarization and gravimetric immersion tests were used to evaluate corrosion of the coupling of two different types of stainless steel, austenitic and ferritic.

The galvanic corrosion was not significant in the case of the coupling of AISI 304 and 444 steels. The difference of the open circuit potentials obtained for the AISI 304 and AISI 444 steels was 28 mV for the polished samples. The galvanic current density (i_g) was 55 nA/cm². The corrosion observed in the stainless steel couple was in the weld area.

The methodology used is adequate to evaluate generalized galvanic corrosion. The problem of the corrosion in the coupling of the stainless steels is a problem of localized corrosion and the observed 28 mV potential difference was lower than the dispersion of results usually obtained from readings of corrosion potentials in electrochemical cells.

The use of two different types of steel in contact with each other may lead to galvanic corrosion, and the welding of steel pieces may lead to several corrosion problems. Since the boiler may be used in different countries, subject to a great diversity of water quality, corrosion may be a significant problem.

Literature data of the AISI 444 steel corrosion behaviour are still scarce. The coupling of two different stainless steels (AISI 304 and 444) in the water reservoir manufacturing was a necessary requirement of the solar energy industry. The manufacturers of boilers must evaluate and quantify the corrosion processes, which occur in the equipment used in the solar energy industry. As the solar energy industry has matured in the last ten years, the corrosion of this equipment may be a significant problem in due course.

The purpose of this study is to evaluate the quality of organometallic coatings of automotive fuel tanks. Galvannealed steels and galvannealed steels coated with organometallic layers were analyzed using accelerated corrosion tests.

The characterization of galvannealed and organometallic coatings was done by mass (layer removal and weighing) and layer thickness (glow discharge optical emission spectroscopy and scanning electron microscopy), chemical composition (energy dispersive spectroscopy) and surface morphology (scanning electron microscopy). The accelerated corrosion tests were performed in accordance with SAE J2334 and GMW 14872 standards.

The samples tested using the GMW 14872 standard were more deteriorated as compared to the samples submitted to the SAE J2334 test because of the higher degree of aggressiveness of the GMW 14872 test. Despite the presence of white rust, the corrosion resistance of organometallic-coated steel samples was higher as compared to the resistance of galvannealed steel samples.

The organometallic coating is a commercial product, whose chemical composition is confidential.

This study reinforces the quality of automotive tanks with organometallic coating and helps to increase their competitiveness in the market tanks as compared to polymeric tanks.

The study contributes to increase the competitiveness of steel tanks against polymeric tanks that meet the technical requirements but are not environmentally friendly because they are multi-layered and cannot be recycled.

The novelty of this study is the comparison of the corrosion resistance of galvannealed steel tanks and galvannealed steel tanks with organometallic coatings. This corrosion evaluation joined with the physical and chemical characterization was not found in literature and is relevant to the materials selection of the automotive industry.