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To study the drying effects of cobalt, manganous and mixed salts for their catalytic action in cross linking reactions occurring during the creation of an alkyd resin film.

The driers of Co‐octoate, Mn‐octoate, Mn‐octoate with an active organic ligand, and mixed drier containing the salts of Mn, Ca, and Zn were employed in the cross linking reactions of alkyls. The study verified the possibility of using manganese as an active cation in catalytic curing reactions. The course of the cross‐linking of alkyds was monitored on a model system of the reactions of drier with ethyl linoleate, using FTIR spectroscopy. Reaction‐rate constants corresponding to the first phase of cross linking were obtained. The driers under scrutiny were used to identify the time of the drying of alkyd resin modified with flax oil. The final phase of the cross linking reactions was monitored by means of measurement the hardness of the created alkyd film depending on time.

The driers under scrutiny were found to have catalytic effects in auto‐oxidation reactions. Very high efficiency was found with all of the driers. The highest efficiency was found with Co‐octoate resulting in the development of the highest hardness of coatings. Mn‐octoate and mixed driers show a steeper increase in film hardness than Co‐drier, yet the final films are suppler.

The driers studied can be conveniently used to accelerate creation of alkyd coatings modified with natural oils and designed for both industrial and decorative purposes.

The method of identifying the kinetic parameters of the cross‐linking reactions of alkyds is relatively new and facilitates the localisation of driers that are optimum for specific paints formulations. Of benefit is also the study of Mn‐driers that are more environmentally acceptable than Co‐driers.

The paper aims to investigate the drying effect exhibited by pigments combined with a Co(II) salt of 2‐ethylhexanoic acid (Co(II)) in an alkyd resin modified by soya bean oil.

Paint hardening was studied by means of a method that follows the progress of alkyd film drying. Another important method was employed to monitor the gradually increasing hardness of the drying films. Hardness of thin films was measured by the Persos method. ZnO, ZnO nanoparticles, V₂O₅, ZnS and TiO₂ were used to study the effect of solid inorganic pigments on alkyd film drying. The pigment particles were characterised by scanning electron microscopy. The investigated pigments were combined with a constant amount of the Co(II) drier that acts in the system as a homogeneous catalyst, while the investigated pigments played the role of heterogeneous catalysts.

Using certain pigments as catalysts in drying, alkyd resins brings about new findings concerning the function of fillers and pigments in paint films. ZnO nanoparticles substantially accelerate film drying and moreover, the resulting films exhibit substantially higher hardness than films containing other inorganic pigments. To prepare films exhibiting higher hardness within a shorter time, one may also use ZnO microparticles or ZnS. TiO₂ and V₂O₅ were identified as pigments that either do not take part in the drying process or reduce the hardness of the resulting film.

The investigated catalytic system pigment/Co(II) drier can be advantageously used to accelerate the formation of alkyd paints modified by natural oils both for industrial and decorative purposes. It was established that hardness of paint films containing ZnO nanoparticles is twice as high as that of films containing only the Co(II) drier without any pigment. This finding makes new applications of alkyd paints possible in all instances where higher hardness is required.

Considering pigments as heterogeneous catalysts in systems producing films by the oxypolymerising mechanism is a new approach that gives rise to new and original solutions.

This paper examines the linkages between the ethics and management control literatures and suggests some potentially fruitful areas for future research and for integration in the classroom.

We review topics in the ethics and management control literatures organizing them around the six modules used in the accounting ethics course taught at the University of Southern California: (a) professional standards, (b) distinguishing right from wrong, (c) understanding why (good) people do bad things, (d) getting employees to behave ethically (corporate ethics programs), (e) getting people to speak up when they see something wrong taking place (Giving Voice to Values), and (f) whistleblowing (the last resort).

While we find many topics where ethics and management control are concerned with similar issues, there are very few papers that approach these topics from the two perspectives.

We provide an overview of topics where ethics and management control overlap, and highlight the need for greater convergence between the two literatures. By linking MCS and ethics, organizations can provide a framework to promote behavior that both contributes to the achievement of the organization’s objectives and also follows ethical principles. We comment on what may happen when ethics and management control diverge, and discuss controls that can promote a strong ethical climate.

This study highlights the demand for low-cost and high accuracy products through the design and development of new 3D printing technologies. Besides, significant progress has been made in this field. A comparative study helps to understand the latest development in materials and future prospect of this technology.

Nevertheless, a large amount of progress still remains to be made. While some of the works have focused on the performances of the materials, the rest have focused on the development of new methods and techniques in additive manufacturing.

This paper critically evaluates the current 3D printing technologies, including the development and optimizations made to the printing methods, as well as the printed objects. Meanwhile, previous developments in this area and contributions to the modern trend in manufacturing technology are summarized briefly.

The paper can be summarized in three sections. Firstly, the existing printing methods along with the frequently used printing materials, as well as the processing parameters, and the factors which influence the quality and mechanical performances of the printed objects are discussed. Secondly, the optimization techniques, such as topology, shape, structure and mechanical property, are described. Thirdly, the latest development and applications of additive manufacturing are depicted, and the scope of future research in the relevant area is put forward.

The class of models that can be represented by STL files is larger than the class of models that can be printed using additive manufacturing technologies. Stated differently, there exist well-formed STL files that cannot be printed. This paper aims to formalize such a gap and describe a fully automatic procedure to turn any such file into a printable model.

Based on well-established concepts from combinatorial topology, this paper provide an unambiguous description of all the mathematical entities involved in the modeling-printing pipeline. Specifically, this paper formally defines the conditions that an STL file must satisfy to be printable, and, based on these, an as-exact-as-possible repairing algorithm is designed.

It has been found that, to cope with all the possible triangle configurations, the algorithm must distinguish between triangles that bind solid parts and triangles that constitute zero-thickness sheets. Only the former set can be fixed without distortion.

Owing to the specific approach used that tracks the so-called “outer hull,” models with inner cavities cannot be treated.

Thanks to this new method, the shift from a 3D model to a printed prototype is faster, easier and more reliable.

The availability of this easily accessible model preparation tool has the potential to foster a wider diffusion of home-made 3D printing in non-professional communities.

Previous methods that are guaranteed to fix all the possible configurations provide only approximate solutions with an unnecessary distortion. Conversely, this procedure is as exact as possible, meaning that no visible distortion is introduced unless it is strictly imposed by limitations of the printing device. Thanks to such unprecedented flexibility and accuracy, this algorithm is expected to significantly simplify the modeling-printing process, in particular within the continuously emerging non-professional “maker” communities.

The paper aims to illustrate the two kinds of analysis approach for which finite element method (FEM) can be successfully employed: the Poisson-Nernst-Planck (PNP) model and the Langevin-Lorentz-Poisson (LLP) one.

The approach of this work is to try making a survey of the use of the FEM in the modelling of charge transport/ion flow across membrane channels, in particular for the PNP analysis and for a particle based model such as LLP model.

In this paper, the two kinds of analysis approach for which FEM can be successfully employed, the PNP model and the LLP one, have been shown. In both cases the FEM is extremely useful to carry out these analysis and the simulation results obtained are in good agreement with experimental results.

The value of this paper is to demonstrate the FEM is extremely useful to carry out analysis and results which are in good agreement with experimental ones.

This paper aims to clarify the relationship between mechanical behaviors and the underlying geometry of periodic cellular structures. Particularly, the answer to the following research question is investigated: Can seemingly different geometries of the repeating unit cells of periodic cellular structure result in similar functional behaviors? The study aims to cluster the geometry-functional behavior relationship into different categories.

Specifically, the effects of the geometry on the compressive deformation (mechanical behavior) responses of multiple standardized cubic periodic cellular structures (CPCS) at macro scales are investigated through both physical tests and finite element simulations of three-dimensional (3D) printed samples. Additionally, these multiple CPCS can be further nested into the shell of 3D models of various mechanical domain parts to demonstrate the influence of their geometries in practical applications.

The paper provides insights into how different CPCS (geometrically different unit cells) influence their compressive deformation behaviors. It suggests a standardized strategy for comparing mechanical behaviors of different CPCS.

This paper is the first work in the research domain to investigate if seemingly different geometries of the underlying unit cell can result in similar mechanical behaviors. It also fulfills the need to infill and lattify real functional parts with geometrically complex unit cells. Existing work mainly focused on simple shapes such as basic trusses or cubes with spherical holes.

The purpose of this paper is to compare two opposite approaches chosen to regulate an industry.

The approach is based on studying the two selected regulation systems, Basel III and the Eurocodes and identifies how the one system regulates financial institutions and the other one civil engineering design.

The paper shows that the financial regulation uses a cause‐based approach to regulation, in which the causes of a crisis are found and controlled. The Eurocodes in civil engineering make no specific attempt to understand the specific causes of a failure; however, they provide a framework, which transfers full responsibility onto the designer if the designer decides not to adhere to a set of codes of practice. It is the trade‐off between less regulation and increased responsibility.

The paper presents a new way of understanding the impact and use of regulation by comparing it to a system which has the same purpose but uses opposite means. It shows how financial regulation in reality has limitations which are its inherent weakness.

The purpose of this paper is to explore the possibility of combining additive manufacturing (AM) with topology optimization to generate support structures for addressing the challenging overhang problem. The overhang problem is considered as a constraint, and a novel algorithm based on continuum topology optimization is proposed.

A mathematical model is formulated, and the overhang constraint is embedded implicitly through a Heaviside function projection. The algorithm is based on the Solid Isotropic Material Penalization (SIMP) method, and the optimization problem is solved through sensitivity analysis.

The overhang problem of the support structures is fixed. The optimal topology of the support structures is developed from a mechanical perspective and remains stable as the material volume of support structures changes, which allows engineers to adjust the material volume to save cost and printing time and meanwhile ensure sufficient stiffness of the support structures. Three types of load conditions for practical application are considered. By discussing the uniform distributive load condition, a compromise result is achieved. By discussing the point load condition, the removal work of support structures after printing is alleviated. By discussing the most unfavorable load condition, the worst collapse situation of the printing model during printing process is sufficiently considered. Numerical examples show feasibility and effectiveness of the algorithm.

The proposed algorithm involves time-consuming finite element analysis and iterative solution, which increase the computation burden. Only the overhang constraint and the minimum compliance problem are discussed, while other constraints and objective functions may be of interest.

Compared with most of the existing heuristic or geometry-based support-generating algorithms, the proposed algorithm develops support structures for AM from a mechanical perspective, which is necessary for support structures particularly used in AM for mega-scale construction such as architectures and sculptures to ensure printing success and accuracy of the printed model.

With the rapid development of AM, complicated structures result from topology optimization are available for fabrication. The present paper demonstrates a combination of AM and topology optimization, which is the trend of fabricating manner in the future.

This paper remarks the first of attempts to use continuum topology optimization method to generate support structures for AM. The methodology used in this work is theoretically meaningful and conclusions drawn in this paper can be of important instruction value and practical significance.

It is a challenge to print a model with the size that is larger than the working volume of a three-dimensional (3D) printer. The purpose of this paper is to present a feasible approach to divide a large model into small printing parts to fit the volume of a printer and then assemble these parts into the final model.

The proposed approach is based on the skeletonization and the minima rule. The skeleton of a printing model is first extracted using the mesh contraction and the principal component analysis. The 3D model is then partitioned preliminarily into many smaller parts using the space sweep method and the minima rule. The preliminary partition is finally optimized using the greedy algorithm.

The skeleton of a 3D model can effectively represent a simplified version of the geometry of the 3D model. Using a model’s skeleton to partition the model is an efficient way. As it is generally desirable to have segmentations at concave creases and seams, the cutting position should be located in the concave region. The proposed approach can partition large models effectively to well retain the integrity of meaningful parts.

The proposed approach is new in the rapid prototyping field using the model skeletonization and the minima rule. Based on the authors’ knowledge, there is no method that concerns the integrity of meaningful parts for partitioning. The proposed method can achieve satisfactory results by the integrity of meaningful parts and assemblability for most 3D models.