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Article
Publication date: 16 January 2017

Hengky Eng, Saeed Maleksaeedi, Suzhu Yu, Yu Ying Clarrisa Choong, Florencia Edith Wiria, Ruihua Eugene Kheng, Jun Wei, Pei-Chen Su and Huijun Phoebe Tham

Polymeric parts produced by 3D stereolithography (SL) process have poorer mechanical properties as compared to their counterparts fabricated via conventional methods, such as…

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Abstract

Purpose

Polymeric parts produced by 3D stereolithography (SL) process have poorer mechanical properties as compared to their counterparts fabricated via conventional methods, such as injection or compression molding. Adding nanofillers in the photopolymer resin for SL could help improve mechanical properties. This study aims to achieve enhancement in mechanical properties of parts fabricated by SL, for functional applications, by using well-dispersed nanofillers in the photopolymers, together with suitable post-processing.

Design/methodology/approach

Carbon nanotubes (CNTs) have high strength and Young’s modulus, making them attractive nanofillers. However, dispersion of CNTs in photopolymer is a critical challenge, as they tend to agglomerate easily. Achieving good dispersion is crucial to improve the mechanical properties; thus, suitable dispersion mechanisms and processes are examined. Solvent exchange process was found to improve the dispersion of multiwalled carbon nanotubes in the photopolymer. The UV-absorbing nature of CNTs was also discovered to affect the curing properties. With suitable post processing, coupled with thermal curing, the mechanical properties of SL parts made from CNTs-filled resin improved significantly.

Findings

With the addition of 0.25 wt.% CNTs into the photopolymer, tensile stress and elongation of the 3D printed parts increased by 70 and 46 per cent, respectively. With the significant improvement, the achieved tensile strength is comparable to parts manufactured by conventional methods.

Practical implications

This allows functional parts to be manufactured using SL.

Originality/value

In this paper, an improved procedure to incorporate CNTs into the photopolymer was developed. Furthermore, because of strong UV-absorption nature of CNTs, curing properties of photopolymer and SL parts with and without CNT fillers were studied. Optimized curing parameters were determined and additional post-processing step for thermal curing was discovered as an essential step in order to further enhance the mechanical properties of SL composite parts.

Details

Rapid Prototyping Journal, vol. 23 no. 1
Type: Research Article
ISSN: 1355-2546

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Article
Publication date: 14 April 2023

Suzhu Yu, Aloysius Tan, Wei Ming Tan, Xinying Deng, Cher Lin Tan and Jun Wei

This paper aims to develop flame-retardant (FR) polyamide 12 (PA12) nanocomposite from regenerated powder via selective laser sintering (SLS), an additive manufacturing technique.

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Abstract

Purpose

This paper aims to develop flame-retardant (FR) polyamide 12 (PA12) nanocomposite from regenerated powder via selective laser sintering (SLS), an additive manufacturing technique.

Design/methodology/approach

First, the morphology, processibility, thermal and mechanical properties of PA12 regenerated powder, consisting of 50 wt% new and 50 wt% recycled powder, as well as corresponding printed specimens, were evaluated to characterize the effects of previous SLS processing. Second, flame-retardant PA12 was developed by incorporating both single and binary halogen-free flame retardants into the regenerated powder.

Findings

It was found that the printed specimens from regenerated powder had much higher tensile and impact properties compared to specimens made from new powder, which is attributed to better particulate fusion and coalescence realized in higher temperature SLS printing. The effect of FRs on thermal, mechanical and flame retardant properties of the PA12 composites/nanocomposites was investigated systematically. It was found that the nanoclay, as a synergist, improved both flame-retardant and mechanical properties of PA12. UL94 standard rating of V-0 was achieved for the printed nanocomposite by incorporating 1 wt% nanoclay into 15 wt% phosphinates FR. Moreover, on average, the tensile and impact strength of the nanocomposite were increased by 26.13% and 17.09%, respectively, in XY, YZ and Z printing orientations as compared to the equivalent flame retardant composite with 20 wt% of the phosphinates FR.

Originality/value

This paper fulfills the need to develop flame retardant parts via SLS technology with waste feedstock. It also addresses the challenge of developing flame retardant materials without obviously compromising the mechanical properties by making use of the synergistic effect of nanoclay and organic phosphinates.

Details

Rapid Prototyping Journal, vol. 29 no. 7
Type: Research Article
ISSN: 1355-2546

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Article
Publication date: 2 May 2017

Bing Liang, Jiao Lv, Gang Wang and Tsubaki Noritatsu

The purpose of this paper is to prepare a novel halogen-free intumescent flame retardant (IFR) BHPPODC (benzene hydroquinone phosphorous oxy dichloride cyanuric chloride) for…

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Abstract

Purpose

The purpose of this paper is to prepare a novel halogen-free intumescent flame retardant (IFR) BHPPODC (benzene hydroquinone phosphorous oxy dichloride cyanuric chloride) for application to epoxy resin (EP) and study their mechanical and flame-retardant performance.

Design/methodology/approach

The IFR was synthesised by phenylphosphonic dichloride, hydroquinone and cyanuric chloride via solvent reaction, and the structure was fully characterised by proton nuclear magnetic resonance (1H-NMR), mass spectrometry (MS) and Fourier transform infrared (FT-IR) spectroscopy. The thermal stability, mechanical and flame properties and morphology of the char layer of the flame-retardant EP was investigated by using thermogravimetric analysis (TGA), tensile and Charpy impact tests, limiting oxygen index (LOI) and vertical burning test (UL-94) and scanning electron microscopy (SEM).

Findings

Results of the LOI indicated that the halogen-free flame retardant as an additive exhibits very good flame-retardant effects. The results showed that the addition of IFR improved the flame resistance properties of epoxies resin composites, and the residual char ratio at 800°C significantly increased.

Research limitations/implications

The IFR can be prepared successfully and can improve the flame-retardant performance.

Practical implications

This contribution can provide a high flame retardant performance and has minimal impact on the mechanical performance of the BHPPODC/EP composition.

Originality/value

This study showed that flame-retardant BHPPODC has an effective flame effect under optimal conditions. When the 12 Wt.% IFR was added to the EP, the LOI was 29.1 and the UL-94 rank can reach V-0 rank, the tensile strength was 83.86 MPa and the impact strength was 8.82 kJ/m2.

Details

Pigment & Resin Technology, vol. 46 no. 3
Type: Research Article
ISSN: 0369-9420

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