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The purpose of this study is to prepare nanoscale copolymer-silicon dioxide (SiO₂) dispersion for formulating textile printing white ink.

Nanoscale copolymer-SiO₂ dispersion was prepared via miniemulsion polymerization. The miniemulsion formulation was optimized for preparing stable SiO₂/O/W miniemulsion and nanoscale copolymer-SiO₂ dispersion. The nanoscale copolymer-SiO₂ was investigated by transmission electron microscope (TEM), X-ray diffraction (XRD), differential thermal gravity (DTG) and thermogravimetric analysis (TGA). The performance of white inks from this colorant was further investigated.

Nanoscale copolymer-SiO₂ had a core-shell structure with about 45 nm encapsulated copolymer layer when it was synthesized under optimal miniemulsion formulation 60 per cent mass ratio of styrene (St) to KH570-SiO₂, 5.0 per cent hexadecane to St and 2.0 per cent concentration of DNS-86. The nanoscale copolymer-SiO₂ white ink had high thermal and centrifugal stability with high purity and color fastness.

The miniemulsion polymerization conditions required a careful control before favorable results could be achieved.

The nanoscale copolymer-SiO₂ dispersion and white ink prepared by this method showed excellent stability. This research could accelerate the textiles inkjet printing application.

The reactive stabilizer DNS-86 is innovatively introduced into the miniemulsion polymerization to improve the stability of the nanoscale copolymer-SiO₂ dispersion. The white ink was formulated from nanoscale copolymer-SiO2 to improve the fastness of the printed fabrics.

The aim of this paper was to prepare a stable fluorescent disperse yellow paste by wet grinding process by adding naphthalene sulphonic derivative dispersing agent.

The dispersants 2-naphthalenesulphonic acid (NNO), naphthalene-sulphonic acid (MF) and benzyl naphthalene sulphonate formaldehyde condensate (CNF) were used to disperse the yellow dye. The particle size of the paste was characterised by particle size analyser. The paste centrifugal stability, diffusion properties, morphology and thermal properties were also tested for assessing its stability which could be helpful to prepare inks with good stability.

The particle sizes of dye pastes with dispersing agent NNO, MF and CNF were 161.1, 150.0 and 136.0 nm, respectively, after grinding for 6 h. The dye paste grinded with dispersing agent CNF presented good centrifugal and thermal properties. TEM images demonstrated that the morphologies of dye pastes grinded with dispersing agent MF and CNF were homogeneous nearly spherical nanoparticle and rarely generated agglomeration and precipitation.

The paste used for aqueous inkjet ink exhibited excellent thermal stability.