Search results

The purpose of this investigation was to develop a digital instrument for the quantitative evaluation of pitting corrosion in metals.

This investigation comprised two central parts: research, testing and monitoring of the formation of pitting by conventional methods and applying American Society for Testing and Materials (ASTM) Standards, and the development of a virtual instrument based on the LabVIEW 2010 platform.

The methodology used was suitable for the analysis of pitting on carbon steel and aluminum alloy UNS A96061, used in the aerospace industry.

This technique allows pits to be to localized, measured and quantified on metallic surfaces, for corrosion evaluation in atmospheric and industrial environments.

This combination of conventional and digital methods can assist in corrosion control of pitting in industrial equipment.

The purpose of this paper is to evaluate the corrosion of silver due to hydrogen sulphide pollutant in indoor conditions at a microelectronics plant located in Mexicali, Baja California, a semi‐arid zone in the northwest of Mexico.

Silver coupons and silver plated on to copper‐lead frames are exposed in the assembly process building of a microelectronics company during a period of 60 days and also in a sheltered test chamber that simulates indoor conditions with ambient concentrations of atmospheric pollutants, temperature and relative humidity (rH). Other exposures are made in the test chamber to study the corrosion behaviour of silver coupons over a duration of 24 months. The corrosion products were analysed using the Scanning Electron Microscope (SEM) and Energy Dispersive X‐ray Spectroscopy (EDS). Corrosion rates were measured by Quartz Crystal Microbalance (QCM) under laboratory‐controlled conditions.

The presence of silver sulphide corrosion products, dendrites and whiskers is observed on the exposed samples using SEM and EDS analysis.

The paper is designed to establish whether the company, where the exposure is taking place, constituted an indoor environment with outdoor hydrogen sulphide pollutant in sufficient concentration to induce silver corrosion.

The methodology used in this work can be applied to study the indoor corrosion behaviour of other metals, which will be of interest to the microelectronics industry.

To develop and test a rapid method for evaluation of the corrosion protection (CP) of carbon steel (CS) by vapour corrosion inhibitors (VCI) films.

The determination of the CP by VCI on CSs is commonly carried out in a chamber applying neutral salt spray (NSS) and usually it takes many days. The common disadvantage of the various rapid methods created until now is the need of special laboratory equipment making their application complicated and inconvenient for field tests. The method for CP measurement of VCI films on CS described in this study is based on measurement of the height of the anodic peak under galvanostatic condition applied earlier on other types of films and coatings. By means of a calibration plot: peak height (V) vs NSS protection time (s), CP of VCI films on CS specimens expressed in hours NSS is determined in a few seconds without using an NSS chamber. Measurements of CP by VCI films under field conditions are performed applying a hand held tester.

Two groups of CS UNS G10180 steel specimens with increasing thickness of VCI films were studied – one in an NSS chamber and the second by the application of a corrosion tester. The correlation between the results obtained for the two groups of specimens was found and a calibration plot was made.

Based on this method, a special corrosion tester was developed, able to measure under field conditions as well.

The method subject of the paper is a further development of a galvanostatic method developed by the authors for CP evaluation of chromate films of Zn and Cd coatings. The method was modified according to the properties of VCI films

Colonies of Actynomyces israelii bacteria have been found in removed copper intra‐uterine devices (IUD) used as a long‐term contraceptive method. The purpose of this paper is to characterize the biofilm developed under anaerobic conditions by Actynomyces israelii on IUD surface, and its influence in the copper corrosion processes.

The dissolution of copper on the intra‐uterine cavity prevents conception because of the toxic effect of the ions released. Nevertheless, microbiological growths have been detected on the IUD devices retired after long periods of insertion. In order to know about the influence of the biofilm on the corrosion of copper, electrochemical, spectroscopic and surface analysis techniques were applied to study the phenomenon.

A porous Actynomyces israelii biofilm was formed on the copper IUD surface. The bacteria colony had developed in an exopolimeric substrate, which protects it from the toxic effect of copper ions. The corrosion process was not inhibited by the biofilm, due to the pores present which permit the transport of species through them.

The results of this study show that there is no decay in the contraceptive function of the IUDs due to the presence of a bacterial biofilm on its surface.

The relationship between microbial colonization and the corrosion process of copper IUD under anaerobic conditions was characterized. These results will complement previous investigations performed on the study of corrosion of copper IUDs under different conditions.

Aggressive environments that enhance indoor corrosion in industrial plants decrease the yielding of electronic equipment, causing electrical failures. The purpose of the present paper is to evaluate corrosion rates in metals used in electronic devices as a function of temperature, humidity and the concentrations of some air pollutants in order to predict the optimal conditions preventing or minimizing corrosion.

Atmospheric pollutants mainly sulphur oxides, penetrating through small crevices and holes into electronic plants in combination with climatic factors such as humidity and heat, promote corrosion. The corrosion rate of the five most used metals in the electronics industry: carbon steel, copper, nickel, silver, and tin, were studied gravimetrically as a function of variations in humidity, temperature and air pollutant concentrations from 2003 to 2005. The samples were exposed in an instrumented boot to indoor conditions and gravimetric measurements were performed together with measurements of the above‐mentioned parameters. Mathematical simulation applying Math Lab software was carried out as well. The ternary diagrams for pollutants, temperature and relative humidity were applied as a useful tool to correlate these parameters in indoor conditions with the corrosion rate of metals applied in the electronics industry.

The obtained results have shown that the presence of even small concentrations of air pollutants promoted corrosion processes when time of wetness conditions were reached.

The study was carried out in order to minimize the corrosion losses of the electronic plants situated especially in Mexicali City located on a semi‐desert zone in the Northwest of Mexico.

This paper establishes the relationship of variations of pollutants concentration, temperature and the relative humidity with the corrosion rate of metals in indoor conditions in the electronics industry located in the semi‐arid zone of Mexicali. Design was characterized and simulated using the MathLab software.

The electronics industry has grown over the past 50 years, mostly in developed countries, contributing to their economic progress. Particularly in the Baja California State located in the northwest of Mexico, these companies have prospered in the industrial parks of Mexicali considered as an arid zone and Ensenada, a port and city on the Pacific Ocean considered as a marine region. In both environments, during winter and summer, the climate impacts on indoor conditions, affecting humidity and temperature, and generating corrosion which decreases the yields of the electronic devices and industrial machines. The purpose of this paper is to investigate the effects of corrosion on electronic devices in these arid and marine environments.

The paper determines the corrosivity levels inside industrial plants of desertic and coast regions in Mexico, to evaluate the deterioration of electronic metals.

Relative humidity, temperature, time of wetness, are recorded and related to the corrosion process in arid and marine environments.

Some missing information about air pollution in Ensenada from some Environmental Monitoring Stations was a limitation, and the need to use complex atmospheric techniques.

The paper shows that it is very important to control metallic corrosion generated by climate factors and air pollution in indoor industrial plants: the corrosion of electronic devices and equipments depletes their yield and can lead to loss‐making failures.

Cubic B‐spline differential quadrature methods have been introduced. As test problems, two different solutions of advection‐diffusion equation are chosen. The first test problem, the transportion of an initial concentration, and the second one, the distribution of an initial pulse, are simulated. The purpose of this paper is to simulate the test problems.

The cubic B‐spline functions are chosen as test functions in order to construct the differential quadrature method. The error between the numerical solutions and analytical solutions are measured using various error norms.

The cubic B‐spline differential quadrature methods have produced acceptable solution for advection‐diffusion equation.

The advection‐diffusion equation has never been solved by any differential quadrature method based on cubic B‐splines.

This paper aims to develop a novel numerical method based on bi-cubic B-spline functions and alternating direction (ADI) scheme to study numerical solutions of advection diffusion equation. The method captures important properties in the advection of fluids very efficiently. C.P.U. time has been shown to be very less as compared with other numerical schemes. Problems of great practical importance have been simulated through the proposed numerical scheme to test the efficiency and applicability of method.

A bi-cubic B-spline ADI method has been proposed to capture many complex properties in the advection of fluids.

Bi-cubic B-spline ADI technique to investigate numerical solutions of partial differential equations has been studied. Presented numerical procedure has been applied to important two-dimensional advection diffusion equations. Computed results are efficient and reliable, have been depicted by graphs and several contour forms and confirm the accuracy of the applied technique. Stability analysis has been performed by von Neumann method and the proposed method is shown to satisfy stability criteria unconditionally. In future, the authors aim to extend this study by applying more complex partial differential equations. Though the structure of the method seems to be little complex, the method has the advantage of using small processing time. Consequently, the method may be used to find solutions at higher time levels also.

ADI technique has never been applied with bi-cubic B-spline functions for numerical solutions of partial differential equations.

The diffusion‐advection phenomena occur in many physical situations such as, the transport of heat in fluids, flow through porous media, the spread of contaminants in fluids and as well as in many other branches of science and engineering. So it is essential to approximate the solution of these kinds of partial differential equations numerically in order to investigate the prediction of the mathematical models, as the exact solutions are usually unavailable.

The difficulties arising in numerical solutions of the transport equation are well known. Hence, the study of transport equation continues to be an active field of research. A number of mathematicians have developed the method of time‐splitting to divide complicated time‐dependent partial differential equations into sets of simpler equations which could then be solved separately by numerical means over fractions of a time‐step. For example, they split large multi‐dimensional equations into a number of simpler one‐dimensional equations each solved separately over a fraction of the time‐step in the so‐called locally one‐dimensional (LOD) method. In the same way, the time‐splitting process can be used to subdivide an equation incorporating several physical processes into a number of simpler equations involving individual physical processes. Thus, instead of applying the one‐dimensional advection‐diffusion equation over one time‐step, it may be split into the pure advection equation and the pure diffusion equation each to be applied over half a time‐step. Known accurate computational procedures of solving the simpler diffusion and advection equations may then be used to solve the advection‐diffusion problem.

In this paper, several different computational LOD procedures were developed and discussed for solving the two‐dimensional transport equation. These schemes are based on the time‐splitting finite difference approximations.

The new approach is simple and effective. The results of a numerical experiment are given, and the accuracy are discussed and compared.

A comparison of calculations with the results of the conventional finite difference techniques demonstrates the good accuracy of the proposed approach.

The purpose of this study is to extend the cubic B-spline quasi-interpolation (CBSQI) method via Kronecker product for solving 2D unsteady advection-diffusion equation. The CBSQI method has been used for solving 1D problems in literature so far. This study seeks to use the idea of a Kronecker product to extend the method for 2D problems.

In this work, a CBSQI is used to approximate the spatial partial derivatives of the dependent variable. The idea of the Kronecker product is used to extend the method for 2D problems. This produces the system of ordinary differential equations (ODE) with initial conditions. The obtained system of ODE is solved by strong stability preserving the Runge–Kutta method (SSP-RK-43).

It is found that solutions obtained by the proposed method are in good agreement with the analytical solution. Further, the results are also compared with available numerical results in the literature, and a reasonable degree of compliance is observed.

To the best of the authors’ knowledge, the CBSQI method is used for the first time for solving 2D problems and can be extended for higher-dimensional problems.