R. Kahraman, A.A. Al‐Mathami, H. Saricimen, N. Abbas and S.U. Rahman
The weather in the Arabian Gulf region constitutes an environment that is corrosive to carbon steel. In the Gulf region, atmospheric corrosion is aggravated further by the high…
Abstract
The weather in the Arabian Gulf region constitutes an environment that is corrosive to carbon steel. In the Gulf region, atmospheric corrosion is aggravated further by the high salinity of Gulf sea‐water. In addition, sulphur dioxide and deposits from combustion products tend to make the atmosphere in the Gulf region even more corrosive. Various inhibitors are reported in the literature that can help in the prevention of metal corrosion in aqueous environments. Among these, sodium dihydrogen orthophosphate, sodium benzoate, sodium nitrite and sodium nitrate were obtained and the effectiveness of certain corrosion inhibitors on carbon steel specimens was examined in a simulated atmospheric corrosion environment containing 2% NaCl and 1% Na2SO4 with various inhibitor concentrations. Test specimens were prepared from locally produced carbon steel reinforcing bars. It was found as a result of the test programme that treatment of the steel with 10 or 100mM sodium dihydrogen orthophosphate for one day at room temperature resulted in the best inhibition of corrosion. The results also demonstrated that inhibitors such as sodium benzoate and sodium nitrite were only similarly effective, as was sodium nitrate. Plans further study to examine the inhibition performance of sodium dihydrogen orthophosphate under actual atmospheric conditions.
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A. Al‐Mathami, H. Saricimen, R. Kahraman, M. Al‐Zahrani and S. Al‐Dulaijan
The purpose of this study was to evaluate the effectiveness of sodium dihydrogen orthophosphate as an inhibitor to slow down or prevent atmospheric corrosion of the local mild…
Abstract
The purpose of this study was to evaluate the effectiveness of sodium dihydrogen orthophosphate as an inhibitor to slow down or prevent atmospheric corrosion of the local mild steel during storage in the Arabian Gulf region. In light of the results of some preliminary studies, sodium dihydrogen orthophosphate was selected for further evaluation against atmospheric corrosion of steel after it was applied at 10 mM concentration for 1 day at room temperature.
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Thien Vuong Nguyen, Vy Do Truc, Tuan Anh Nguyen and Dai Lam Tran
This study aims to explore the synergistic effect of oxide nanoparticles (ZnO, Fe2O3, SiO2) and cerium nitrate inhibitor on anti-corrosion performance of epoxy coating. First…
Abstract
Purpose
This study aims to explore the synergistic effect of oxide nanoparticles (ZnO, Fe2O3, SiO2) and cerium nitrate inhibitor on anti-corrosion performance of epoxy coating. First, cerium nitrate inhibitors are absorbed on the surface of various oxide nanoparticles. Thereafter, epoxy nanocomposite coatings have been fabricated on carbon steel substrate using these oxide@Ce nanoparticles as both nano-fillers and nano-inhibitors.
Design/methodology/approach
To evaluate the impact of oxides@Ce nanoparticles on mechanical properties of epoxy coating, the abrasion resistance and impact resistance of epoxy coatings have been examined. To study the impact of oxides@Ce nanoparticles on anti-corrosion performance of epoxy coating for steel, the electrochemical impedance spectroscopy has been carried out in 3% NaCl solution.
Findings
ZnO@Ce3+ and SiO2@Ce3+ nanoparticles provide more enhancement in the epoxy pore network than modification of the epoxy/steel interface. Whereas, Fe2O3@Ce3+ nanoparticles have more to do with modification of the epoxy/steel interface than to change the epoxy pore network.
Originality/value
Incorporation of both oxide nanoparticles and inorganic inhibitor into the epoxy resin is a promising approach for enhancing the anti-corrosion performance of carbon steel.
Yinxia Dong, Mingtian Li, Yingjun Zhang, Chun Xie and Zhongwen Pan
The purpose of this study is to modify cerium dioxide with fumaric acid (CeO2-f) to improve its compatibility and dispersibility in epoxy resin and to investigate the effect of…
Abstract
Purpose
The purpose of this study is to modify cerium dioxide with fumaric acid (CeO2-f) to improve its compatibility and dispersibility in epoxy resin and to investigate the effect of the content on the coating performance.
Design/methodology/approach
To investigate whether CeO2-f reacts with epoxy resin by ring opening, CeO2-f and epoxy resin-treated CeO2-f (Ce CeO2-f/EP) were analyzed by infrared radiation (IR), X-ray diffraction (XRD) and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis). To reveal the effect of different content on coatings properties, neutral salt spray test (NSST) and electrochemical test were performed.
Findings
The results of IR, XRD, X-ray photoelectron spectroscopy and UV-Vis indicated that fumaric acid attached to the CeO2 surface by chemical bonding and underwent a ring-opening reaction with epoxy resin, thus, improving the compatibility of CeO2 in epoxy resin. NSST and electrochemical impedance spectroscopy results showed that the coatings containing 5% CeO2-f exhibited the optimal corrosion resistance. The reason is that a dense conversion film was established on the substrate surface.
Originality/value
The epoxy coatings using CeO2-f as fillers with synergistic inhibition ability are promising for the protection of carbon steel.
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Muazzam Ghous Sohail, Mohammad Salih, Nasser Al Nuaimi and Ramazan Kahraman
The purpose of this paper is to present the results of a two-year long study carried out in order to evaluate the corrosion performance of mild steel bare bars (BB) and…
Abstract
Purpose
The purpose of this paper is to present the results of a two-year long study carried out in order to evaluate the corrosion performance of mild steel bare bars (BB) and epoxy-coated rebar (ECR) in concrete under a simulated harsh environment of chlorides.
Design/methodology/approach
The blocks are subjected to Southern Exposure testing. The electrochemical impedance spectroscopy (EIS), linear polarization resistance (LPR) and Tafel plot are performed to measure the polarization resistance and corrosion current densities of these rebars. Knife-peel test was performed to assess the adhesion between epoxy and underlying steel after two years of exposure.
Findings
Mild steel BB showed a high corrosion current density of 1.24 µA/ cm2 in Tafel plots and a very low polarization resistance of 4.5 kΩ cm2 in LPR technique, whereas very high charge transfer resistance of 1672 and 1675 kΩ cm2 is observed on ECR and ECR with controlled damage (ECRCD), through EIS technique, respectively. EIS is observed to be a suitable tool to detect the defects in epoxy coatings. After two years of immersion in 3.89 percent NaCl− solution, the mild steel BB were severely corroded and a considerable weight loss was observed, whereas under heavy chloride attack, ECR showed no deterioration of epoxy coating and neither any corrosion of underlying steel. Results of this study show that the durability of reinforced concrete (RC) structures with respect to corrosion could be enhanced by using ECR, especially in harsh climatic conditions.
Originality/value
The corrosion performance of mild steel and ECR in concrete under a simulating splash zone environment is evaluated. EIS was used to evaluate the health of epoxy and corrosion state of underneath steel rebars. EIS was able to detect the defects in epoxy. The durability of RC structures could be enhanced in harsh climate regions by using ECR.
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Hai Tan, Yanbao Guo, Junqiang Wang, Deguo Wang and Yongjie Cui
The purpose of this study is to investigate the influence of additive particle size on the anti-corrosion behaviors of polyurethane (PU) coating.
Abstract
Purpose
The purpose of this study is to investigate the influence of additive particle size on the anti-corrosion behaviors of polyurethane (PU) coating.
Design/methodology/approach
The graphite (Gr) and poly-graphite (PGr) were used as large size additive and small size additive, respectively. The immersion test and electrochemical test were used to study the corrosion behaviors.
Findings
In the immersion test, the surface of the bare steel sample was corroded uniformly. However, for the steel samples with coatings, the surfaces were corroded locally. This phenomenon showed that the coating can isolate artificial sea-water and samples and then decreased the corrosion rate. Furthermore, the most severe corrosion was observed on the sample with the Gr/PU coating compared with other anti-corrosion coatings. The results of the electrochemical measurements indicated that the corrosion rate of the sample with PGr/PU coating was approximately two times lower than that of the sample with the Gr/PU coating and the sample with PGr/PU coating was hardest to be corroded.
Originality/value
To have a more objective and direct recognition of the particle size effect on the coating quality.
Xiaoli Che, A. Fakhrorazi, Wei-Kit Loke, Swarmilah Hariani and Qinyuan Chen
This study examines the effect of knowledge workers' (k-workers') leader-member exchange (LMX) on task performance and the mediation effect of affective commitment and…
Abstract
Purpose
This study examines the effect of knowledge workers' (k-workers') leader-member exchange (LMX) on task performance and the mediation effect of affective commitment and organizational citizenship behavior (OCB) in China.
Design/methodology/approach
In this study, 384 qualified questionnaires will be collected from k-workers in China by using a self-administered survey, and the partial least square structural equation modeling (PLS-SEM) technique was employed for data analysis.
Findings
This finding showed that LMX has positive relationship on affective commitment, organizational citizenship behavior and task performance. The result also confirmed the mediation effect of organizational citizenship behavior on the relationship between LMX and task performance.
Originality/value
This research provide some implement to manage, motivate and inspire the k-workers and finally promote the organizational performance.
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Ying-Chung Chen, Tsung-Hsien Yang and Siu-Tong Choi
This paper aims to study a dynamic analysis of a double-helical geared rotor system with oil-film bearing.
Abstract
Purpose
This paper aims to study a dynamic analysis of a double-helical geared rotor system with oil-film bearing.
Design/methodology/approach
A finite element model of a double-helical geared rotor system with oil-film bearing is developed, in which a rigid mass is used to represent the gear and the Timoshenko beam finite element represents the shaft; the equations of motion are obtained by applying Lagrange’s equation. Natural frequencies, Campbell diagram, lateral responses, axial responses, bearing stiffness coefficients, bearing damping coefficients and bearing force are investigated.
Findings
Natural frequencies and Campbell diagram of a double-helical geared rotor system with oil-film bearing are investigated. An increased helical angle enhanced the axial response of the system and reduced its lateral response. The distance between the node and bearing affected the lateral response magnitude on the node. The farther away the gear pair was from the central part of the shaft, the higher the system’s resonance frequency became. The different gear pair position has a significant influence on the bearing stiffness coefficient and bearing force, but it just has a little effect on the bearing damping coefficient.
Practical implications
The model of a double-helical geared rotor system with oil-film bearing is established in this paper. The dynamic characteristics of a double-helical geared rotor system with oil-film bearing are investigated. The numerical results of this study can be used as a reference for subsequent personnel research.
Originality/value
Although the dynamics characteristics of geared rotor bearing system have been reported in some literature, the dynamic analysis of a double-helical geared rotor-bearing system is still rarely investigated. This paper showed some novel results that lateral and axial response results are obtained by the different helical angle and different gear positions. In the future, it makes valuable contributions for further development of dynamic analysis of a double-helical geared rotor-bearing system.
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Yajun Chen, Zehuan Sui and Juan Du
This paper aims to focus on the research progress of intelligent self-healing anti-corrosion coatings in the aviation field in the past few years. The paper provides certain…
Abstract
Purpose
This paper aims to focus on the research progress of intelligent self-healing anti-corrosion coatings in the aviation field in the past few years. The paper provides certain literature review supports and development direction suggestions for future research on intelligent self-healing coatings in aviation.
Design/methodology/approach
This mini-review uses a systematic literature review process to provide a comprehensive and up-to-date review of intelligent self-healing anti-corrosion coatings that have been researched and applied in the field of aviation in recent years. In total, 64 articles published in journals in this field in the last few years were analysed in this paper.
Findings
The authors conclude that the incorporation of multiple external stimulus-response mechanisms makes the coatings smarter in addition to their original self-healing corrosion protection function. In the future, further research is still needed in the research and development of new coating materials, the synergistic release of multiple self-healing mechanisms, coating preparation technology and corrosion monitoring technology.
Originality/value
To the best of the authors’ knowledge, this is one of the few systematic literature reviews on intelligent self-healing anti-corrosion coatings in aviation. The authors provide a comprehensive overview of the topical issues of such coatings and present their views and opinions by discussing the opportunities and challenges that self-healing coatings will face in future development.
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Anagi Balachandra, Roz-Ud-Din Nassar and Parviz Soroushian
This study aims to report the development and experimental evaluation of three innovative corrosion-resistant modified epoxy coatings, namely, nanocomposite/toughened…
Abstract
Purpose
This study aims to report the development and experimental evaluation of three innovative corrosion-resistant modified epoxy coatings, namely, nanocomposite/toughened, self-healing and hybrid epoxy coatings, for application on steel substrates.
Design/methodology/approach
The corrosion resistance of these coatings was evaluated in a highly corrosive environment of salt fog spray for 2,500 h of exposure. Electrochemical impedance spectroscopy (EIS) measurements in sustained exposure to NaCl in a saturated Ca(OH)2 solution, rust creepage measurements at the location of scribe formed in the coatings and adhesion strength test were used to assess the performance of the innovative coatings. Commercially available marine-grade protective epoxy coatings were used as the reference coatings.
Findings
The test results showed that the modified epoxy coatings exhibited excellent corrosion resistance when exposed to an aggressive environment for extended periods. The EIS measurements, rust creepage measurements, pull-off strength and visual appearance of the aged modified–epoxy–coated specimens confirmed the enhanced corrosion resistance of the modified epoxy coatings.
Originality/value
Among the three types of modified coatings, the hybrid epoxy coating stands out to be the best performer.