Adekunle Sulaimon Ogunbadejo, Sunday Aribo, Oluwatoyin Adenike Olaseinde, Oladeji O. Ige and Peter Olubambi
This paper aims to investigate the stability of passive oxide film formed on the surface of 316L stainless steel in 3.5 Wt.% NaCl in the presence of two environmentally non-toxic…
Abstract
Purpose
This paper aims to investigate the stability of passive oxide film formed on the surface of 316L stainless steel in 3.5 Wt.% NaCl in the presence of two environmentally non-toxic inhibitors, i.e. leaf extracts of Musa spp. (MS) and Jatropha curcas (JC).
Design/methodology/approach
Current transients and potentiodynamic polarization curves were used to explain the stability of the passive film on Current transients and potentiodynamic polarization curves were used to explain the stability of the passive film on 316L stainless steel at both ambient temperature (25 °C) and 70 °C. For the potentiostatic tests, the coupons underwent cathodic stripping to remove the native oxide on their surfaces at −850 mV for 600 s, and a potential of 50 mV was imposed to observe the repassivation for 200 s. For the potentiodynamic tests, the pitting potential measured at 100 μA/cm2, corrosion potential and cathodic current density were obtained for analysis.
Findings
The current transients perfectly fitted into the exponential decay curve; i = is + ipeak exp(−t/τ), where the decay constant, τ measures the repassivating speed and extent to which the newly formed film heals and stabilizes. The current transients showed that MS and JC help in the repassivating process, especially at 300 ppm and 200 ppm, respectively, both at the lower temperature. The potentiodynamic curves mostly correlated with the current transients except for the hybrid inhibitor. The inhibitors increased the pitting potentials at concentrations that are correlated to their scanning electron micrograph images.
Research limitations/implications
Because they are cheap and environmentally friendly, plant extracts that are proven corrosion inhibitors could be used to aid the formation of passive film on passive alloys in not-so-aggressive environments.
Practical implications
Both MS and JC improve the film stability mostly at intermediate concentrations of 200 and 300 ppm, respectively, at ambient temperature and 70° C.
Social implications
Using leaf extracts of plants as green inhibitors is considered an environmentally friendly engineering solution.
Originality/value
The leaf extracts are a convenient resource of green inhibitors because their plants are readily available or could be easily naturalized, the processing technique to obtain the extracts is very cheap and the inhibitors are environmentally friendly. In addition, cathodic stripping exposes a relatively larger surface area than that obtained using the most common forms of depassivation; hence, the efficiency of the inhibitor in aiding the formation of the new oxide film to cover the bare surface would be better measured. There is very lean research data on the combined use of green inhibitors and cathodic stripping to study repassivating kinetics of passive alloys.
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Bukola Joseph Babalola, Ojo Jeremiah Akinribide, Olukayode Samuel Akinwamide and Peter Apata Olubambi
During the operation of nickel-based alloys as blades and discs in turbines, the sliding activity between metallic surfaces is subjected to structural and compositional changes…
Abstract
Purpose
During the operation of nickel-based alloys as blades and discs in turbines, the sliding activity between metallic surfaces is subjected to structural and compositional changes. In as much as friction and wear are influenced by interacting surfaces, it is necessary to investigate these effects. This study aims to understand better the mechanical and tribological characteristics of Ni-17Cr-10X (X = Mo, W, Ta) ternary alloy systems developed via spark plasma sintering (SPS) technique.
Design/methodology/approach
Nickel-based ternary alloys were fabricated via SPS technique at 50 MPa, 1100 °C, 100 °C/min and a dwell time of 10 mins. Scanning electron microscopy, X-Ray diffraction, energy dispersive X-ray spectroscopy, nanoindentation techniques and tribometer were used to assess the microstructure, phase composition, elemental dispersion, mechanical and tribological characteristics of the sintered nickel-based alloys.
Findings
The outcome of the investigation showed that the Ni-17Cr10Mo alloy exhibited the highest indentation hardness value of 8045 MPa, elastic modulus value of 386 GPa and wear resistance. At the same time, Ni-17Cr10W possessed the least mechanical and wear properties.
Originality/value
It can be shown that the SPS technique is efficient in the development of nickel-based alloys with good elemental distribution and without defects such as segregation of alloying elements, non-metallic inclusions. This is evident from the scanning electron microscopy micrographs.
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Praveen Kumar Bannaravuri and Anil Kumar Birru
The purpose of this paper is to determine the use of BLA along with SiC as economical reinforcements to enhance the mechanical behavior of hybrid composite. The purpose of this…
Abstract
Purpose
The purpose of this paper is to determine the use of BLA along with SiC as economical reinforcements to enhance the mechanical behavior of hybrid composite. The purpose of this research is the development of cost-effective aluminum hybrid metal matrix composites.
Design/methodology/approach
The present research work investigation evaluated the mechanical properties of Al-4.5%Cu alloy, Al-4.5Cu/10SiC, Al-4.5Cu/10SiC/2BLA and Al-4.5Cu/10SiC/4BLA composites by the Stir casting method. The fabricated composites were analyzed using optical microscopy (OM), scanning electron microscopy (SEM), and hardness and tensile test.
Findings
The microstructure modification with the addition of reinforcement particles in the matrix alloy and clear interface in between matrix and particles are observed. The density of the composite increased with the addition of SiC and decreased with the addition of BLA in comparison with that of matrix alloy. The hardness and tensile strength of the single-reinforced composite and hybrid composites improved with the addition of reinforcement particles. The strengthening of composites was due to load-bearing capacity of reinforcement particles over the matrix alloy and increased dislocation density of composites materials. The tensile failure mechanism of the composites is reveled with SEM analysis.
Practical implications
The papers reports the development of cost-effective and light weight aluminum hybrid composites with remarkable enhancement in the mechanical and tribological properties with the addition of BLA as economical reinforcement along with SiC.
Originality/value
The density, hardness and tensile values of fabricated aluminium composites were presented in this paper for the use in the engineering applications where the weight and cost are consider as a primary factors.
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Vitus Mwinteribo Tabie, Jamal-Deen Kukurah, Jianwei Li, Anthony Akayeti, James Kwasi Quaisie and Xiaojing Xu
Titanium alloys and composites have proven to contain desirable properties for use at elevated temperatures. One such material is the Ti750 composite, which can be used at…
Abstract
Purpose
Titanium alloys and composites have proven to contain desirable properties for use at elevated temperatures. One such material is the Ti750 composite, which can be used at temperatures up to 750°C for a brief period. This paper aims the microstructure, phase compositions, apparent porosity and hardness of both sintered and heat-treated TiC reinforced Ti750 composites for consideration in aircraft engine design.
Design/methodology/approach
The fabrication of TiC-reinforced Ti750 composites was achieved through spark plasma sintering (SPS). To analyze the microstructure and X-ray diffraction, a scanning electron microscope (SEM) with model number S-3400N and a D8 advance model machine were used, respectively. The microhardness of the samples was measured using a Vickers hardness tester with model HV-1000. The research incorporated three solid solution treatments: 975°C/3 h/AC, 1,010°C/3 h/AC and 1,025°C/3 h/AC, along with a solid-solution aging treatment at 1,010°C/3 h/AC + 750°C/8 h/AC. Additionally, oxidation analysis was conducted on the samples.
Findings
The microstructures contained enhanced TiC and Ti5Si3 phases in the near a-Ti matrix. The microhardness of the sintered composite was over twice that of the matrix alloy, and its porosity was reduced by about 0.35%. The sample treated at 1,010°C/3 h/AC had the highest enhanced peaks and microhardness of 1,277.1 HV. After oxidation at 800°C for 100 h, the accumulated weight of the solid solution composite at 1,010 °C/3 h/AC was the lowest (3.0 mg.cm-2). The surface microstructure contained oxides of TiO2 and a spalling white area containing a small amount of Al2O3 and SiO2.
Originality/value
There is limited research on Ti-Al-Sn-Zr-Mo-Si-based TMCs using a combination of the SPS method. This study used SiCp as a reinforcement for the Ti750 matrix alloy. The consolidation of SiCp and Ti750 powders using the SPS method, heat treatment of the resulting TiC reinforced Ti750 composites and study of the microstructure and properties of the composites are not found in literature or under consideration for publication in any media.
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Rabab M. Nasser and Nora M. Masmali
Plant development and use as green corrosion inhibitors are already recognized as one of the most environmentally friendly and effective protocols. In recent years, efforts have…
Abstract
Purpose
Plant development and use as green corrosion inhibitors are already recognized as one of the most environmentally friendly and effective protocols. In recent years, efforts have been made to find green corrosion inhibitors as an alternative to synthetic inhibitors for metals in acid medium. This paper aims to report the investigation of use of aqueous extracts of Tamarindus Indica as green inhibitors for corrosion of metals within different circumstances.
Design/methodology/approach
The use of Tamarindus Indica extracts (leaves, stem, fruit pulp and fruit husk) as corrosion inhibitors for mild steel and aluminum in different mediums (HCl, H2SO4, formic acid and citric acid) at different temperatures was investigated.
Findings
The inhibitory efficiency of Tamarindus Indica extracts increases with increasing concentration and decreases with increasing temperature. Langmuir is the adsorption isotherm, and the extract (inhibitor) is a mixed-type inhibitor (physisorption and chemisorption).
Practical implications
Tamarindus extracts (leaves, stem, fruit pulp and fruit husk) are effective inhibitors and can be used to protect metals from corrosion at different circumstances.
Originality/value
To the best of the authors’ knowledge, this is the first review that discusses the use of Tamarindus Indica extracts as corrosion inhibitors for metals.