Amir Khalaj Asadi, Morteza Ebrahimi and Mohsen Mohseni
The purpose of this work was to express a facile method to fabricate microcapsules containing linseed oil with melamine-urea-formaldehyde (MUF) shell in the presence of…
Abstract
Purpose
The purpose of this work was to express a facile method to fabricate microcapsules containing linseed oil with melamine-urea-formaldehyde (MUF) shell in the presence of polyvinylpyrrolidone (PVP) as an emulsifier. These microcapsules may be used in self-healing coating formulations.
Design/methodology/approach
In this work, different types of PVP (i.e., PVP with different molecular weights or K values) were used as emulsifiers and colloid protectors to encapsulate linseed oil in an MUF shell. Moreover, the effect of agitation rate on the morphology of the microcapsules was investigated. Microcapsule morphology and particle size distribution were evaluated using optical microscopy and scanning electron microscopy. Thermal studies were performed using a thermo-gravimetric analysis technique and chemical structure of materials was characterized by using Fourier transform infrared analysis.
Findings
In this work, microcapsules with a regular spherical shape and a shell thickness of about 330 nm were fabricated. The results revealed that the use of PVP in the fabrication of MUF could facilitate the synthesis process by eliminating the necessity of pH control during the reaction. In fact, the pH of the reaction media must be precisely controlled in conventional processes. The yield of microencapsulation was found to be 86.5 per cent when a high molecular weight of PVP (PVP K-90) was used. It was also found that the surface morphology of microcapsules became smoother when PVP K-90 was used. The results showed that the surface roughness and the average particle size decreased with an increase in stirring intensity. Mean diameter of the prepared microcapsules ranged from 34 to 346 μmin for various synthesis conditions.
Research limitations/implications
This work is limited to the encapsulation of a hydrophobic liquid (such as linseed oil) by an in situ polymerisation of amino resins.
Practical implications
The presented results can be used by researchers (in academia and industry) who are working in the field of fabrication microcapsules, in various applications such as pharmaceuticals, electrophoretic displays, textiles, carbonless copy papers, cosmetics, printing and self-healing materials.
Social implications
PVP is considered as an environmentally friendly emulsifier. Therefore, this process is less harmful to the environment. In addition, the prepared microcapsules may be used in self-healing coatings, which helps in reducing maintenance costs for buildings and steel structures.
Originality/value
Ethylene maleic anhydride and styrene maleic anhydride are usually used as emulsifiers in conventional methods for the preparation of amino resin microcapsules. These methods require an intensive and precise pH control to obtain favourable microcapsules, while in the present research, a facile method was used to fabricate MUF microcapsules containing linseed oil without needing any pH control during the reaction.
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Amir Khalaj Asadi, Morteza Ebrahimi and Mohsen Mohseni
The purpose of this investigation is to develop a facile method to encapsulate a sunlight-curable silicone-based resin into a melamine–urea–formaldehyde (MUF) shell in the…
Abstract
Purpose
The purpose of this investigation is to develop a facile method to encapsulate a sunlight-curable silicone-based resin into a melamine–urea–formaldehyde (MUF) shell in the presence of polyvinylpyrrolidone (PVP) as an emulsifier. These microcapsules can be used in self-healing coating formulations.
Design/methodology/approach
MUF microcapsules containing a sunlight-curable core (methacryloxypropyl-terminated polydimethylsiloxane, MAT-PDMS) have been fabricated by means of in situ polymerisation of an oil-in-water emulsion using PVP as an efficient and environmentally advantageous stabiliser. The effects of agitation rate and PVP concentration on the microencapsulation process have been investigated using optical microscopy (OM) and scanning electron microscopy (SEM). The chemical structure and thermal stability of the microcapsules have been studied using Fourier transform infrared (FTIR) spectroscopy and thermogravimetric analysis (TGA). The solvent resistance of the microcapsules has been determined as well.
Findings
It has been revealed that the pH of the reaction mixture remained almost constant during the reaction, which simplified the process. It has also been observed that the microencapsulation yield improved and the microcapsules’ surface morphology became smoother when a high PVP content was used. With an increase in stirring rate from 600 to 1,200 rpm, the surface roughness and the average particle size decreased. The mean diameter of the prepared microcapsules ranged from 32.1 to 327.1 µm depending on the synthesis conditions. It was demonstrated that the microcapsules had a high capacity for MAT-PDMS encapsulation (more than 88 Wt.%). The solvent stability of the microcapsules against different polar, semi-polar and non-polar solvents was also evaluated.
Research limitations/implications
This research is limited to the encapsulation of a hydrophobic and sunlight curable liquid (such as MAT-PDMS) by means of in situ polymerisation of amino resins.
Practical implications
The results can be used by researchers working on the fabrication of microcapsules for applications such as drugs, electrophoretic inks, electrophoretic displays, intumescent fire-retardant coatings and self-healing materials.
Social implications
In self-healing coatings, healing agents which can be cured by UV irradiation or sunlight are envisaged attractive because they are catalyst-free, environmentally friendly and relatively inexpensive. PVP is an environmentally friendly emulsifier. The prepared microcapsules can be used in self-healing coatings to help in reducing maintenance costs for buildings and steel structures.
Originality/value
The novel aspect of this work is the development of a sunlight-curable silicone-based resin that was encapsulated in a MUF shell in the presence of PVP. A simple method was used to fabricate MUF microcapsules containing MAT-PDMS without the need to control pH during the reaction. Conventional methods for the preparation of amino resin microcapsules require an intensive and precise pH control to obtain favourable microcapsules. MAT-PDMS can be cured by sunlight and is catalyst-free, environmentally friendly and relatively inexpensive.
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Mehran Rostami, Mohsen Mohseni and Zahra Ranjbar
The purpose of this paper is to investigate the effect of different PHS on the surface chemistry of fumed silica treated with aminopropyltrimethoxysilane (APTMS).
Abstract
Purpose
The purpose of this paper is to investigate the effect of different PHS on the surface chemistry of fumed silica treated with aminopropyltrimethoxysilane (APTMS).
Design/methodology/approach
The reaction conditions involved variation of pH ranging from acidic to alkaline. Different analytical techniques including FT‐IR spectroscopy, thermogravimetric analysis (TGA), CHN and Zeta potential analyses were employed to investigate the surface chemistry of treated particles. In addition, the stability of silanised silica dispersions were studied using turbidimetric and rheometric measurements.
Findings
It was revealed that in all conditions silica was more or less chemically grafted by the silane. When the pH of treating bath was adjusted to 1‐2 prior and during the reaction, 58 percent grafting was observed, as obtained by CHN and TGA analyses. At very alkaline conditions, however, the grafting content declined to 29 percent. The variations in grafting were dependent on the silane hydrolysis and its further condensation with the silica surface. Zeta potential measurements showed a drastic change from −7.1 mv to +18.01 mv (at pH 7) for the untreated particle and the one with the highest grafting, respectively. The dispersion stability of differently treated particles varied in solvents with different Hansen solubility parameters (HSP). Moreover, due to the variations of surface chemistry of particles, their rheological behaviours were significantly influenced.
Originality/value
The results obtained in this work showed that the surface chemistry of fume silica could be tuned with treating method. The highest content of grafting led to a better dispersion in solvents having greater hydrogen bonding component and to an inferior dispersion in solvents with higher polar component.
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Reza Kazemi, Mohsen Fallah, Bijan Abbasi and Seyyed Hossein MohseniArmaki
The purpose of this study is to achieve the low-cost, light-weight and compact antenna array with wide bandwidth and low side lobe levels for synthetic aperture radar (SAR…
Abstract
Purpose
The purpose of this study is to achieve the low-cost, light-weight and compact antenna array with wide bandwidth and low side lobe levels for synthetic aperture radar (SAR) applications in Ku frequency band.
Design/methodology/approach
A compact design of a rectangular microstrip patch antenna array using multilayered dielectric structure is presented in Ku-band for advanced broadband SAR systems. In this design, stepped pins are used to connect the microstrip feed lines to the radiating patches.
Findings
The simulation and fabrication results of the multilayered antenna and a 1×16-element linear array of the antenna with Taylor amplitude distribution in the feeding network are presented. The antenna element has a 10-dB impedance bandwidth of more than 26%, and the linear array shows reduction in bandwidth percentage (about 15.4%). Thanks to Taylor amplitude tapering, the side lobe level (SLL) of the array is lower than −24 dB. The maximum measured gains of the antenna element and the linear array are 7 and 19.2 dBi at the center frequency, respectively.
Originality/value
In the communication systems, a high gain narrow beamwidth radiation pattern achieved by an array of multiple antenna elements with optimized spacing is a solution to overcome the path loss, atmospheric loss, polarization loss, etc. Also, wideband characteristics and compact size are desirable in satellite and SAR systems. This paper provides the combination of these features by microstrip structures.
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Mohsen Tajdinian, Shahram Montaser Kouhsari, Kazem Mohseni and Mehdi Zareian Jahromi
Decaying DC component has important effect on extracting the fundamental component phasor. It directly affects the precision of protective relaying algorithms which act based on…
Abstract
Purpose
Decaying DC component has important effect on extracting the fundamental component phasor. It directly affects the precision of protective relaying algorithms which act based on fundamental frequency component. It can be noted that decaying DC component, harmonic components and off-nominal frequency conditions are the major issues which strongly effect phasor estimation. The paper aims to discuss these issues.
Design/methodology/approach
This paper proposes a novel hybrid approach for fundamental phasor estimation in order to remove the decaying DC component using Hilbert Transform and Discrete Fourier Transform.
Findings
The proposed method (PM) converges to the original value in one cycle in presence of harmonic components and off-nominal frequency condition. In addition, proposed algorithm is able to detect the frequency fluctuation. Thus, it is applicable for static and dynamic conditions. An extensive set of simulation results across static and dynamic validations demonstrated that the proposed approach has faster convergence and better precision than the present methods. In addition, during harmonic distortion and also frequency fluctuation, the PM provides a correct and reliable response.
Originality/value
The PM can calculate the DC component exactly from fault current signals and can be used in digital protection algorithms for phasor estimation.
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Mohsen Pakdaman, Sara Geravandi, Ali Hejazi, Mobin Salehi and Mahboobeh Davoodifar
Currently, the health system is a treatment-oriented system focused on service providers. In this system, the main focus is on the health market, with little attention on insured…
Abstract
Purpose
Currently, the health system is a treatment-oriented system focused on service providers. In this system, the main focus is on the health market, with little attention on insured. One way to get out of existing conditions is to empower the insured in order to involve them actively in maintaining and improving health. The paper aims to discuss these issues.
Design/methodology/approach
This qualitative study was done using the content analysis method. Based on the purposive sampling method and theoretical saturation criterion, 24 individuals including 12 health insurance experts and 12 insured participated in the study in 2018. The semi-structured interview method was used to collect data. Data were analyzed using MAXQDA10 software.
Findings
Having analyzed the interviews, 750 codes were obtained. These codes were categorized into two categories of “insurance experts” and “insured” and ten subcategories of “informing and educating, cost reduction, intersectional activities, expectations from the insured, services package, access to services, inability to pay costs, participation, and expectations from the insurance organization.”
Originality/value
This qualitative study was conducted to assess and determine the effective strategies for empowering the insured under health insurance. The results of this study are helpful to the health insurance organizations and health decision makers to detect the effective ways to develop the quality of insurance services, improve the status of insured, and increase access to health care goods and services.
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Mohsen Nazarzadeh Zare, Javad Pourkarimi and Sahba Rezaeian
The purpose of this paper is to identify the barriers and challenges to international interactions of the faculty members in Iran.
Abstract
Purpose
The purpose of this paper is to identify the barriers and challenges to international interactions of the faculty members in Iran.
Design/methodology/approach
To achieve the purpose, a qualitative phenomenological approach was used. The research population was all experts in the field of higher education in Iran, it included 17 experts who were selected through purposeful sampling by snowball method and based on theoretical saturation. To collect the data, a semi-structured interview was used and for the data analysis, an inductive content analysis was applied.
Findings
The findings showed that the barriers and challenges to faculty members’ international interactions can be defined through three main barriers: inside university barriers, outside university barriers, and individual barriers.
Practical implications
This research identified the barriers and challenges of faculty members’ international interactions in Iran. The method of this study can be applied in other applied fields as well.
Originality/value
This study adds to the authors’ knowledge about international interactions of the faculty members and also the barriers and challenges of these interactions, so to have more interactions of faculty members at the international level, universities should make an effort to identify barriers and eliminate them, more than ever.
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Since the election of June 2009, the Islamic Republic of Iran has witnessed a huge crisis with the outburst of street protests and demonstrations, challenging its validity…
Abstract
Since the election of June 2009, the Islamic Republic of Iran has witnessed a huge crisis with the outburst of street protests and demonstrations, challenging its validity. Indeed, it has been so intense that it has shaken the whole Islamic Republic for the first time since the 1979 Iranian revolution. What has happened since the disputed election was an upheaval few had anticipated, an opening of Pandora's box, with millions daring to question the, Velayate Fagih, the most important constituent of the Islamic Republic. This postelection period has created a “revolutionary”’ potential that has so far been met with repressive force and violence on the part of the ruling elites leaving no leverage for compromise. Of course, in the 30 years since the revolution, the Islamic Republic's power structures have faced factionalism. These recent developments demonstrate how deeply rooted run the contradictions and differences between the various groups. This upheaval has thrown all sorts of questions into the air: could Iran remain as a Republic? Or would Iran turn into a God's Kingdom, ever more dictatorial in its approach? Or would the splits within the ruling elites continue to crack the fabric of the regime? Will there be a similar schism to that which took place during the Constitutional Revolution in the early 20th century when a leading member of the clergy, Noori, was finally hanged in July 1909 for being openly against reform? Finally, what is the possibility of change beyond the Islamic Republic in Iran?
Elnaz Chitsazzadeh, Mahsa Chizfahm Daneshmandian, Najmeh Jahani and Mohammad Tahsildoost
The UNESCO recommendation under the historic urban landscapes (HUL) title and Operational Guidelines (OPG) were used to create dynamic protective boundaries to maintain the…
Abstract
Purpose
The UNESCO recommendation under the historic urban landscapes (HUL) title and Operational Guidelines (OPG) were used to create dynamic protective boundaries to maintain the integrity and authenticity of Isfahan's heritage waterways. Accordingly, by using GIS and Isfahan urban layers, three protective zones were proposed and evaluated; the central zone, the functional zone and the visual zone.
Design/methodology/approach
Heritage waterways in historic cities are not adequately protected against the negative impacts of urban development, and there is a lack of a dynamic protective system to protect their integrity and authenticity. The problem can be observed in Isfahan, a historic Iranian city, where the boundaries of urban heritage waterways (Madi canals) are usually rigid and arbitrary. This study aims to develop a practicable paradigm for determining protection boundaries for Isfahan's Jolfa Madi, an urban heritage waterway.
Findings
Compared to the current protective boundaries, the authors found that proposed protective boundaries create a greater amount of protection space, which makes a strong connection among the ecological, historical and socio-economic characteristics of the urban context. Furthermore, the protective zones based on the HUL approach give Isfahan's urban planning policy the opportunity to consider participatory tools, financial tools and regulatory systems.
Originality/value
Many studies have emphasized a fixed-width buffer or an arbitrary distance from the urban waterway's axis (urban heritage) or its banks. Although these protections include technical conservation or setting restrictions on the adjacent buildings and blocks, studying crucial concepts such as urban dynamic, urban heritage context and producing a particular technique for protected boundaries has not been investigated. In this article three dynamic boundaries are delineated with various functions in order to provide urban heritage with dynamic preservation and sustainable development for the historic urban landscapes.
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Kushagra Sharan, Deepak Dhayanithy and Deepa Sethi
This paper aims to examine the relationship between organizational learning (OL) and technology through the lens of strategic factors and to ascertain future research directions.
Abstract
Purpose
This paper aims to examine the relationship between organizational learning (OL) and technology through the lens of strategic factors and to ascertain future research directions.
Design/methodology/approach
The systematic literature review method was applied in three stages to the 76 articles obtained from Scopus, Web of Science, Google Scholar and EBSCO databases.
Findings
This research revealed the evolution of the role of OL in innovation, performance, knowledge management and technological adoption and showcases a detailed conceptual model relating technology outcomes (technological innovation and capabilities) to OL outcomes (technology absorptive capacity, technological proactivity, as well as information technology [IT] and organization process alignment).
Research limitations/implications
This review includes articles mainly in English and excludes conference proceedings.
Practical implications
This research attempts to guide managers and policymakers to foster an organizational culture conducive to technological adoption and OL. It helps organizations develop strategies for new product development, including strategic alliances and strategic leadership.
Originality/value
This review formalizes the linkages between technological absorptive capacity, technological proactivity and IT with technological innovation and capabilities. It identifies research gaps and elucidates future research directions.