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An indirect electrochemical reduction and dyeing with indigo were carried out here to solve problems of low dye reduction rate and poor dyeing depth in the current electrochemical dyeing process.

Response surface analysis tests were performed to evaluate the effects of ferrous sulfate concentration, medium concentration, sodium hydroxide concentration and reduction time on the reduction efficiency of indirect electrochemical reduction of indigo.

The conditions obtained by design-expert optimization showed that the concentration of FeSO₄·7H₂O has the most significant effect on the reduction performance of dye liquor. Under the optimized electrochemical reduction dyeing process, the rate of dye reduction could be reached 91.21 per cent and the K/S value of indirect electrochemical dyeing of indigo can be achieved to 12.96, which is increased by about 9.56 per cent compared with that of Na₂S₂O₄ dyeing with the same color fastness basically.

The recyclability and biodegradability of the dye remain to be explored.

The strategy presented here can be developed to replace a substantial part of electrochemical dyeing with optimized product quality and reduced environmental pollution in denim production.

The strategy presented here can be developed to replace a substantial part of electrochemical dyeing with optimized product quality and reduced environmental pollution in denim production.

Application of the Fe(II)-DGS-Abal B complex media system in the indirect electrochemical reduction of indigo.

The purpose of this study is to improve the performance of sodium borohydride in reducing indigo at room temperature, the divalent copper ion complex was combined with electrochemical technology for the reduction of indigo by sodium borohydride.

According to the K/S value of the dyed cloth sample, find a more suitable ligand for the copper ion in the catholyte. Response surface analysis tests were performed to evaluate the effects of sodium borohydride concentration, sodium hydroxide concentration and copper sulfate pentahydrate concentration on the reduction potential of the dye solution and the K/S value of the dyed fabric samples.

Sodium gluconate was found to be a more suitable ligand for copper ions in catholyte. The effects of NaOH concentration as well as the interaction of NaBH₄ and NaOH on the reduction potential of the catholyte and the K/S value of the dyed fabric samples were extremely significant. The optimal concentrations of NaBH₄, NaOH and CuSO₄•5H₂O were 0.5, 2.5 and 0.65 g/L. In the case of the optimized condition, the absolute value of the reduction potential was 968, and the K/S value was 11.92, which is comparable with that of the conventional reduction process with sodium dithionite.

The divalent copper ion complex combined with electrochemical technology was applied in the process of reducing indigo with NaBH₄ at room temperature.

To improve the problems as the heavy burden of sewage treatment and environmental pollution caused by the traditional sodium hydrosulfite reduction dyeing of indigo, this study aims to carry out the direct electrochemical reduction dyeing for indigo with the eco-friendly Cu(II)/sodium borohydride reduction system under normal temperature and pressure conditions.

The electrochemical behavior of Cu(II)/sodium borohydride reduction system was investigated by cyclic voltammetry. And, the dyeing performance of the Cu(II)/sodium borohydride reduction system was developed by optimizing the concentration of copper sulfate in the anode electrolyte, applied voltage and reduction time via single-factor and orthogonal integrated analysis.

The dyeing performance of the Cu(II)/sodium borohydride reduction system is superior to that of the traditional reduction dyeing with sodium hydrosulfite. In the case of the optimized condition, the soaping fastness and dry/wet rubbing fastness of the dyed fabric in the two reduction dyeing processes were basically comparable, the K/S value of electrocatalytic reduction of indigo by Cu(II)/NaBH4 is 11.81, which is higher than that obtained by traditional sodium hydrosulfite reduction dyeing of indigo.

The innovative electrocatalytic reduction system applied herein uses sodium borohydride as the hydrogen source combined with Cu(II) complex as the catalyst, which can serve as a medium for electron transfer and active the dye molecule to make it easier to be reduced. The electrochemical dyeing strategy presented here provides a new idea to improve the reduction dyeing performance of indigo by sodium borohydride.

Regular cable trench inspection is crucial, and robotics automation provides an efficient and safer alternative to manual labor. However, existing robots have limited capabilities in traversing obstacles and lack a mechanical arm for detecting cables and equipment. This study aims to develop an intelligent robot for cable trench inspection, enhancing obstacle-crossing abilities and incorporating a mechanical arm for inspection tasks.

This study presents an intelligent robot for cable trench inspection, featuring a six-degree-of-freedom mechanical arm mounted on a six-track chassis with four flippers. The robot's climbing and obstacle-crossing stability, as well as the motion range of the mechanical arm, are analyzed. The positioning, navigation and remote monitoring systems are developed. Experiments, including climbing and obstacle-crossing performance tests, along with navigation and positioning system tests, are conducted. Finally, the robot's practicability is verified through field testing.

Equipped with flipper tracks, the cable trench inspection robot can traverse obstacles up to 30 cm high and maintain stable locomotion on 30° slopes. Its navigation system enables autonomous operation, while the mechanical arm performs cable current detection tasks. The remote monitoring system provides comprehensive control of the robot and environmental parameter monitoring in cable trenches.

The front and rear flipper tracks enhance the robot's ability to traverse obstacles in cable trenches. The mechanical arm addresses cable current and equipment contact detection issues. The navigation and remote monitoring systems improve the robot's autonomous operation and environmental monitoring capabilities. Implementing this robot can advance the automation and intelligence of cable trench inspections.

Drawing on conservation of resources theory, this study aims to develop a resource-based model depicting a decreased level of psychological resourcefulness – relational energy, as a novel explanatory mechanism that accounts for the harm of abusive supervision, and we further investigate the role of leader humor as a boundary condition.

We applied multilevel path analysis to test our hypotheses with three-time-point survey data collected from 226 supervisor-employee dyads in a telecommunication company in China across six months.

Our results show that abusive supervision is negatively related to employee relational energy, leading to a subsequent decline in employee job performance. The predictions of the depleting effects get alleviated by leader humor.

This study foregrounds the importance of employee relationship management in the workplace and reveals that some abusive supervisors may manage to sustain employee performance and relational energy by using humor in their interactions, which necessitates immediate intervention.

These findings offer novel insights into the deleterious impact of abusive supervision by demonstrating the critical role of relational energy in dyadic interactions. We also reveal the potential dark side of leader humor in the context of abuse in the workplace.

In Chinese libraries, short video platforms have emerged as a channel for new media marketing. Thus, this study aims to explore libraries’ communication influence on China’s largest short video platform, that is, Douyin (the Chinese version of Tiktok), and to provide corresponding suggestions for improvement of libraries’ communication influence in the short video platform.

Based on the Douyin Communication Index (DCI), this paper collects the top 200 library Douyin accounts of cultural reading in China and uses statistical and content analyses to evaluate the communication influence of library Douyin accounts.

Study findings show that libraries of various types and in various regions currently have an unbalanced development trend, with public libraries accounting for the vast majority and nearly half of the libraries located in China’s eastern region. Analysis of variance shows differences in the influence of Douyin communication among library types. Correlation analysis shows that indicators with a high correlation with DCI include the number of new works, likes, shares, and comments. In marketing content, the library’s high-impact short videos have characteristics of value, interest, and emotional touch.

This study uses a hybrid research method to explore Chinese libraries’ communication influence using the Douyin short video platform. Compared to other parts of the world, short videos in Chinese libraries have unique characteristics. They are rooted in China’s history and reality, showcasing the unique charm of Chinese library culture and serving as a unique reference for library marketing activities around the world.