Manawwer Alam and Naser Al‐Aandis
The purpose of this paper is to develop pyridine polyesteramide coatings from Linseed (Linum ussitatissimum) seeds oil for the utilisation of a sustainable resource as coating…
Abstract
Purpose
The purpose of this paper is to develop pyridine polyesteramide coatings from Linseed (Linum ussitatissimum) seeds oil for the utilisation of a sustainable resource as coating material, as well as to improve the coating properties.
Design/methodology/approach
Linseed oil was first converted into N,N bis 2‐hydroxyethyl linseed oil fatty amide (HELA). The resin was synthesized by the reaction of linseed oil fatty amide diol with 2,3‐pyridine di carboxylic acid to develop pyridine polyesteramide (Py‐PEA) and further treated with poly(styrene‐co‐maleic anhydride)(SMA) in different phr (part per hundred part of resin). The structural elucidation of Py‐PEA was carried out by FT‐IR, 1H‐NMR and 13C‐NMR spectral techniques. The thermal stability and curing behaviour of the resin were determined by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. The physico‐mechanical and anticorrosive properties were investigated by standard laboratory methods.
Findings
The authors developed a good anticorrosive coating material from sustainable resource. The physico‐mechanical and anticorrosive performance evaluation exhibited satisfactory results. The approach facilitated curing to occur at ambient temperature and the thermal studies revealed that Py‐PEA‐SMA‐45 might be safely used up to 140°C.
Practical implications
Poly(styrene‐co‐maleic anhydride) modified pyridine polyesteramide coatings showed the highest scratch hardness 3.0 kg, flexibility (1/8 inch canonical mandrel bend test) and gloss at 45° is 62‐64. Among all, Py‐PEA‐SMA 45 showed the best physico‐mechanical and chemical resistance performance. Thus, the resin may be used as an effective coating material.
Originality/value
The paper shows that the synthesis of polyesteramide resin from vegetable oil provides a new way to utilize a renewable resource based raw material.
Details
Keywords
Manawwer Alam and Naser M. Al‐Andis
The purpose of this study is to develop poly(etherfattyamide) coatings from Pongamia glabra seeds oil utilizing a sustainable resource, which is non edible, non medicinal and goes…
Abstract
Purpose
The purpose of this study is to develop poly(etherfattyamide) coatings from Pongamia glabra seeds oil utilizing a sustainable resource, which is non edible, non medicinal and goes as waste. Seed oil based poly(etherfattyamide) is used as a coating material to improve the coating properties especially gloss and alkali resistance.
Design/methodology/approach
Pongamia glabra oil was first converted into N,N′ bis 2‐hydroxyethyl Pongamia glabra oil fatty amide (HEPFA). HEPFA was treated with 1,4‐cyclohexanedimethanol (CHDM) to develop poly(etherfattyamide) (PEFA). PEFA was cured with (butylated melamine formaldehyde) (BMF) in different (35, 40, 45, 50) phr (part per hundred part of resin) to produce coating material. The structural elucidations of HEPFA and PEFA were carried out by FT‐IR, 1H‐NMR and 13C‐NMR spectral techniques. The thermal study was performed by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. The physico‐mechanical and chemical resistance/anticorrosive properties were investigated by standard laboratory methods.
Findings
The authors developed a good coatings material from a sustainable resource. The physico‐mechanical and anticorrosive performance evaluation exhibits satisfactory results. PEFA‐BMF coatings material showed good alkali resistance and high gloss. The thermal studies showed that PEFA‐BMF45 may be safely used up to 225°C.
Practical implications
BMF modified PEFA coatings showed the highest scratch hardness 3.5 kg, flexibility (1/8 inch conical mandrel bend test) and gloss at 45° is 76‐82. Among all, PEFA‐BMF45 showed the best physico‐mechanical and chemical resistance performance. Thus, it may be used as an efficient coating material.
Originality/value
The synthesis of BMF modified PEFA from Pongamia glabra oil using 1,4‐cyclohexanedimethanol has been studied for the first time providing a new approach to utilize a non edible seed oil – a sustainable resource.
Details
Keywords
Manawwer Alam and Naser M. Alandis
The purpose of this investigation was to develop sustainable resource-based anticorrosive coating material using Pongamia glabra seed oil and tannic acid (TA), as well as to…
Abstract
Purpose
The purpose of this investigation was to develop sustainable resource-based anticorrosive coating material using Pongamia glabra seed oil and tannic acid (TA), as well as to improve the coating properties.
Design/methodology/approach
TA-modified fatty amide diol was synthesized by condensation polymerization. First, Pongamia glabra seed oil was converted to fatty amide diol (Pongamia oil fatty amide, PFA) that was further modified by TA with different parts per hundred of resin (10, 15 and 20) to develop a polyether fatty amide (PFA-TA). The confirmation of reaction between TA and PFA was carried out using Fourier transform infrared spectroscopy. The thermal behavior of PFA-TA was studied by thermogravimetric analyses. Coatings of several PFA-TA resins were applied to steel (i.e. plain carbon steel) coupons to investigate their physico-mechanical and anticorrosive performance. The corrosion protection performance was observed using AC impedance and polarization tests.
Findings
TA-modified fatty amide coatings showed the highest scratch hardness of 2.5 kg, flexibility (1/8 inch) and gloss at 45° was 60-62. Among all compositions, PFA-TA15 showed the best physico-mechanical and anticorrosion performance. Corrosion tests of coated panels were examined in different corrosive media (3.5 wt per cent HCl, 3.5 wt per cent NaOH and 5.0 wt per cent NaCl) using potentiodynamic polarization and AC impedance measurements. PFA-TA may find application as an eco-friendly protective coating, and thermal analyses revealed that it can be safely used up to 300°C.
Originality/value
This paper provides the development of protective coatings for steel from non-edible seed oil and TA to utilize sustainable resources.