M.A. El‐Kashouti, G.H. Elgemeie, M.M El‐Molla, H.S. El‐Sayad and K.A.E. Ahmed
To synthesize some new heterocyclic disperse azo dyes and their utilization in textile printing.
Abstract
Purpose
To synthesize some new heterocyclic disperse azo dyes and their utilization in textile printing.
Design/methodology/approach
To prepare 1‐cayno‐1‐substituted aryl azo‐2‐methyl benzothiazole by the reaction of 2‐aminothiophenol with malononitrile and the end product coupled with different diazonium salts. The prepared dyestuffs are established using element analysis, IR measurements, 1H‐NMR and Mass spectra. Printing pastes containing the prepared dyestuffs and a thickener were used for printing polyester and/or nylon 6 using either transfer printing or traditional printing.
Findings
New selected arylazo cyanomethyl benzothiazole dyes were obtained from the reaction of diazotized aniline derivatives with 2‐cyanomethyl benzothiazole as a coupling component. The suitability of the prepared dyestuffs for either heat transfer printing or traditional printing on polyester and nylon 6 fabrics has been investigated. The prints obtained from dyes containing non polar groups which have sublimation properties possess high colour strength as well as good overall fastness properties if compared to those obtained using dyes containing polar groups.
Research limitations/implications
The new heterocyclic disperse azo dyes were prepared from 2‐cyanomethylbenzothiazole and were utilized in preparing pastes for textile printing to print polyester and nylon 6 fabrics. In addition, the variation in substituents on the synthesized dyes could also be studied.
Practical implications
The method of synthesis of the new dyestuffs provides a simple and practical solution to prepare some new heterocyclic disperse azo dyes with low molecular weight, suitable for sublimation in heat transfer printing methods.
Originality/value
The methods for synthesis of the new heterocyclic disperse azo dyes are simple. These dyestuffs could be used in textile printing of polyester and nylon 6 on an industrial scale.
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Keywords
M.H. Helal, G.H. Elgemeie, M.A. El‐kashouti, M.M. ElMolla, H.S. Elsayad and K.A. Ahmed
The purpose of this paper is to synthesise some disperse dyes containing a reactive group and study their applications on polyamide and wool printing by heat transfer and screen…
Abstract
Purpose
The purpose of this paper is to synthesise some disperse dyes containing a reactive group and study their applications on polyamide and wool printing by heat transfer and screen printing.
Design/methodology/approach
To prepare these dyes, arylhydrazones of acetylacetone were reacted with cyanothioacetamide in boiling ethanolic sodium ethoxide. The resultant salt was collected by filtration and dried, then the salt was dissolved in ethanol and reacted with chloroacetylchloride with stirring for 3 h, where chloroacetylechloride was added dropwise. The final precipitated product was collected by filtration and crystallised with an appropriate solvent. These prepared dyes were used to print polyamide and wool fabrics by using synthetic thickener in the printing paste for all techniques.
Findings
The structure of the synthesised dyes were established and confirmed for the reaction products on the basis of their elemental analysis and spectral data (MS, IR and 1H‐NMR). The suitability of the prepared dyestuffs for either heat transfer printing or traditional printing on nylon 6 and wool fabrics was investigated. The prints obtained from dyes possess high‐colour strength as well as excellent overall fastness properties.
Research limitations/implications
The synthesised heterocyclic reactive disperse azo dyes were prepared from the reaction of arylhydrazones of acetylacetone and thiocyanoacetamide to form the corresponding pyridinethione salts which underwent further reaction with chloroacetylchloride. The obtained dyes were utilised in preparing a paste for polyamide and wool fabric printing. In addition, both of the variation of the substituents on the synthesised dyes and the fastness properties were also studied.
Practical implications
The synthesis and use of reactive disperse dyes provide practical solution to over come the low fastness on polyamide and wool, when they are printed with disperse dyes only.
Originality/value
The result of the work aimed to define the scope and limitation of the authors' procedures for the synthesis of novel reactive disperse azo dyes to improve the low‐fastness properties of polyamide and wool, the dyes were synthesised in a simple way.
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Keywords
M.A. El‐Kashouti, M.M. El Molla, H.S. Elsayad, K.A. Ahmed, M.H. Helal and G.H. Elgemeie
To synthesise several new pyridine‐2(1H)thione containing an arylazo function and their applications in textile printing.
Abstract
Purpose
To synthesise several new pyridine‐2(1H)thione containing an arylazo function and their applications in textile printing.
Design/methodology/approach
To prepare substituted 5‐arylazopyridine‐2(1H)thione by the coupling of diazonium salts of aniline derivatives with dibenzoyl methane (1,3‐diphenyl‐1,3‐propanedione) to form arylhydrazone of dibenzoylmethane which react with cyanothioacetamide in boiling ethanolic sodium ethoxide to yield the 5‐arylazo‐2(1H)‐pyridinethione derivatives. The printing properties by screen printing or transfer printing technique of these dyes are reported by using sodium alginate as thickening agent.
Findings
The structure of 5‐arylazopyridine‐2(1H)thione dyes were established and confirm for the reaction products on the basis of their element analysis and spectral data (MS, IR and 1H‐NMR). The suitability of the prepared dyestuffs for either heat transfer printing or traditional printing on polyester and nylon 6 fabrics has been investigated. The prints obtained from dyes possess high‐colour strength as well as good overall fastness properties.
Research limitations/implications
Synthesis of azo dyes containing pyridinethiole moiety has never been reported in textile printing.
Practical implications
Production of simple and less costly dyes.
Originality/value
5‐arylazo pyridine‐2(1H)thione, the result of our work aimed to define the scope of and limitation of our procedures for the synthesis of novel 5‐arylazopyridine‐2(1H)thione.
M.H. Helal, G.H. Elgemeie, M.A. El‐kashouti and K.A. El‐zaher Ahmed
The purpose of this paper is to synthesise new heterocyclic disperse azo dyes based on benzothiazapine moiety and their printability on synthetic fabrics.
Abstract
Purpose
The purpose of this paper is to synthesise new heterocyclic disperse azo dyes based on benzothiazapine moiety and their printability on synthetic fabrics.
Design/methodology/approach
Ethyl cyanoacetate was refluxed with aniline derivatives for 3 h to form cyanoacetanilides which coupled with different diazonium salts. The products obtained were cyclised with 2‐amino thiophenol to form arylazo benzothiazapine derivatives. The structures of the new dyes were characterised by micro‐analysis as well as IR, 1H NMR and 13C NMR. Printing pastes containing the dyestuffs prepared and thickened with sodium alginate were used for printing synthetic fabrics using either transfer printing or traditional screen printing.
Findings
New heterocyclic monoazo dyes derived from benzothiazabine moiety were obtained by the coupling of diazotised aniline derivatives with ethylcyanoacetate anilides followed by cyclisation with 2‐amino thiophenol. The use of synthesised dyes for transfer‐ or screen‐printing polyester and nylon 6 fabrics has been studied. The synthesised dyes which contain electron withdrawing substituents (NO2) in the phenyl ring attached to the azo groups and electron‐donating (OCH3) group on the other phenyl ring exert a bathochromic effect.
Research limitations/implications
Synthesis of azo dyes containing benzothiazapine moiety has never been reported in textile printing.
Practical implications
Production of simple and less costly dyes.
Originality/value
Synthesis of aryl azo benzothiazapine dyes by a simple method and application in printing of synthetic fabrics.
Details
Keywords
Hamada Abdelwahab, Fatimah A.M. Al-Zahrani, Ali A. Ali, Ammar Mahmoud and Long Lin
This paper aims to synthesize new screen-printing ink formula based on new derivatives of azo thiadiazol disperse dyes and evaluate their characteristics after being printed on…
Abstract
Purpose
This paper aims to synthesize new screen-printing ink formula based on new derivatives of azo thiadiazol disperse dyes and evaluate their characteristics after being printed on polyester fabric substrates.
Design/methodology/approach
New dispersed dyes based on 1, 3, 4-Thiadiazole derivatives (dyes 1 and 2) were prepared and confirmed by different analyses, infrared (IR), mass and nuclear magnetic resonance (NMR) spectroscopy, and then formulated as colored materials in the screen-printing ink formulations. Printing pastes containing the prepared dyestuffs and other ingredients were used for printing polyester using screen-printing or traditional printing. The characteristics of printed polyester fabric substrates were measured by color measurements such as a*, b*, L*, C*, E, Ho, R% and color strength, as well as light, washing, crock and alkali perspiration fastness, and finally, the depth of penetration was evaluated.
Findings
The prepared 1, 3, 4-Thiadiazole derivatives (dyes 1 and 2) were obtained from the reaction of 5,5’-(1,4-phenylene)bis(1,3,4-Thiadiazole-2-amine) with resorcinol and m-toluidine as a coupling component. The suitability of the prepared dyestuffs for silk screen-printing on polyester fabrics has been investigated. The prints obtained from a formulation containing dye 1 possess high color strength as well as good overall fastness properties if compared to those obtained using dye 2.
Practical implications
The method of synthesis of the new dyestuffs and screen-printing ink provides a simple and practical solution to prepare some new heterocyclic disperse azo dyes, and they are formulated in the screen-printing inks for printing on a polyester fabric substrate.
Originality/value
The prepared disperse dyes based on 1,3,4-Thiadiazole derivatives (dyes 1 and 2) could be used in textile printing of polyester on an industrial scale.
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G.H. Elgemeie, K.A. Ahmed, E.A. Ahmed, M.H. Helal and D.M. Masoud
The purpose of this paper is to synthesize some novel 2-amino-6,6-dimethyl-9-phenyl-3-(phenyldiazenyl)-6,7-dihydropyrazolo-[5,1-b]quinazolin-8(5H)-one derivatives by…
Abstract
Purpose
The purpose of this paper is to synthesize some novel 2-amino-6,6-dimethyl-9-phenyl-3-(phenyldiazenyl)-6,7-dihydropyrazolo-[5,1-b]quinazolin-8(5H)-one derivatives by multi-component one-pot reaction using a microwave as a new tool for green chemistry.
Design/methodology/approach
An equimolor from arylazopyrazole, 5,5-dimethyl-1,3-cyclohexanedione (dimedone) and benzaldehyde derivatives was dissolved in Dimethylformamide (DMF) to be irradiated in a microwave for 15 minutes; after completion of the reaction, as indicated by Thin layer chromatograph (TLC), the reaction mixture was poured into ice water, filtered and then crystallized with an appropriate solvent.
Findings
The structure of the synthesized dyes was established and confirmed for the reaction products on the basis of their elemental analysis and spectral data (MS, IR and 1H-NMR). These prepared dyes were used to print polyester and polyamide fabrics using synthetic thickener in the printing paste for the silk screen technique. The synthesized dyes are superior in terms of yield, purity, color strength and fastness properties and will lead to valuable achievements for commercial production.
Originality/value
An efficient method for synthesis of pyrazoloquinazolinone dyes was designed. The novel procedure features short reaction time, moderate yields and simple workup. The authors studied its application in printing polyester and polyamide fabrics.
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Keywords
Starch/carboxymethylstarch‐poly (acrylonitrile, acrylamide, vinyl acetate) composites have been successfully prepared through polymerization of acrylonitrile, acrylamide or vinyl…
Abstract
Starch/carboxymethylstarch‐poly (acrylonitrile, acrylamide, vinyl acetate) composites have been successfully prepared through polymerization of acrylonitrile, acrylamide or vinyl acetate with starch or carboxymethyl starch (CMS) using ceric‐ion type CeIV catalyst. The obtained composites were saponified using alcoholic KOH solution. Regardless of the composite used, results obtained led to the following: (a) enhancement of solubility percent as compared with starch and CMS; (b) the size removal reaches 100 percent for a given set of desizing condition used; (c) the tensile strength and elongation at break increase with sizing, while crease recovery decreases; (d) sizing treatment in the presence of the prepared composites gives positive influence on the abrasion resistance; and (e) incorporation of CMS in composite form in the sizing formulation exerts a considerable positive influence on the performance properties of the sized fabrics as compared with other sizing agents under investigation.
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Keywords
Gülçin Baysal, Gizem Keleş, Berdan Kalav, F. Seniha Güner and Burçak Karagüzel Kayaoğlu
In this study, it is aimed to synthesize ultraviolet (UV)-curable water-borne polyurethane acrylate (WPUA) binders using different types of polyols (poly (propylene glycol), PPG…
Abstract
Purpose
In this study, it is aimed to synthesize ultraviolet (UV)-curable water-borne polyurethane acrylate (WPUA) binders using different types of polyols (poly (propylene glycol), PPG1000 and PPG2000 and poly (ethylene glycol), PEG1000 and PEG2000) at different molecular weights, DMPA (2,2-bis(hydroxymethyl) propionic acid) at different amounts and isophorone diisocyanate (IPDI) and use for pigment printing on synthetic leather.
Design/methodology/approach
UV-cured films were characterized by Fourier transform infrared spectroscopy (FTIR) and differential scanning calorimeter (DSC). The effect of binder structure on printing performance was determined with hardness, crock fastness, abrasion resistance and color measurements.
Findings
The highest abrasion resistance (60,000 cycles) and crock fastness values (dry crock and wet crock: 3/4) were obtained with binder PEG-C synthesized with PEG2000 and lower DMPA amount of 4.89 wt%; however, PEG-C binder showed lower hardness values. Due to lower urethane groups in PEG-C binder, more flexible films were obtained which imparted good adhesion property to printing film. Synthesized binders provided lower crock fastness and abrasion resistance properties than commercial WPUA binder.
Originality/value
Pigmented formulations including UV-curable water-borne synthesized PUA binder were developed and for the first time applied onto synthetic leather using screen printing method. Within this context, a new environmentally friendly printing method was proposed in this study including binder synthesis in the preparation of printing formulations.
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Keywords
Khaled Mohamed Seddik, Lamiaa Khamal El-Gabry and Marwa Atif Ali
This study aims to use hexanediol, pentaerythritol and keratin as crosslinking agents on the acrylic fabric used as garments.
Abstract
Purpose
This study aims to use hexanediol, pentaerythritol and keratin as crosslinking agents on the acrylic fabric used as garments.
Design/methodology/approach
Plain 1/1 acrylic fabric was produced with 14 and 11 weft yarn/cm using yarn count 28/2 Ne, then it was modified with different agents, and the effect of crosslinking on some of the inherent properties was determined. The color strength as well as washing fastness was evaluated. The Fourier transform infrared spectroscopy determined the changes that acted in the structure of the treated acrylic fabrics. Several physical and functional utility characteristics were studied such as stiffness, crease recovery, tensile strength and elongation, pilling, air permeability, absorbency and static electricity.
Findings
Polyacrylonitrile is one of the man-made materials used in the textile field; despite novel characteristics, it has some negative properties, especially in absorbency and pilling, which are improved after treatment.
Originality/value
The results presented that the different conditions that were used with cross-linkers enhanced the acrylic fabrics properties. Where analysis of variance test at P-value 0.05 and radar chart area offered that the treated acrylic fabric with 5% (w/v) keratin accomplished the highest preferable properties for end use.
Details
Keywords
Osama Abdulhameed, Abdurahman Mushabab Al-Ahmari, Wadea Ameen and Syed Hammad Mian
Hybrid manufacturing technologies combining individual processes can be recognized as one of the most cogent developments in recent times. As a result of integrating additive…
Abstract
Purpose
Hybrid manufacturing technologies combining individual processes can be recognized as one of the most cogent developments in recent times. As a result of integrating additive, subtractive and inspection processes within a single system, the relative benefits of each process can be exploited. This collaboration uses the strength of the individual processes, while decreasing the shortcomings and broadening the application areas. Notwithstanding its numerous advantages, the implementation of hybrid technology is typically affected by the limited process planning methods. The process planning methods proficient at effectively using manufacturing sources for hybridization are notably restrictive. Hence, this paper aims to propose a computer-aided process planning system for hybrid additive, subtractive and inspection processes. A dynamic process plan has been developed, wherein an online process control with intelligent and autonomous characteristics, as well as the feedback from the inspection, is utilized.
Design/methodology/approach
In this research, a computer-aided process planning system for hybrid additive, subtractive and inspection process has been proposed. A framework based on the integration of three phases has been designed and implemented. The first phase has been developed for the generation of alternative plans or different scenarios depending on machining parameters, the amount of material to be added and removed in additive and subtractive manufacturing, etc. The primary objective in this phase has been to conduct set-up planning, process selection, process sequencing, selection of machine parameters, etc. The second phase is aimed at the identification of the optimum scenario or plan.
Findings
To accomplish this goal, economic models for additive and subtractive manufacturing were used. The objective of the third phase was to generate a dynamic process plan depending on the inspection feedback. For this purpose, a multi-agent system has been used. The multi-agent system has been used to achieve intelligence and autonomy of different phases.
Practical implications
A case study has been developed to test and validate the proposed algorithm and establish the performance of the proposed system.
Originality/value
The major contribution of this work is the novel dynamic computer-aided process planning system for the hybrid process. This hybrid process is not limited by the shortcomings of the constituent processes in terms of tool accessibility and support volume. It has been established that the hybrid process together with an appropriate computer-aided process plan provides an effective solution to accurately fabricate a variety of complex parts.