Zhenxiao Chen, Derek Ingham, Mohammed Ismail, Lin Ma, Kevin J. Hughes and Mohamed Pourkashanian
The purpose of this paper is to investigate the effects of hydrogen humidity on the performance of air-breathing proton exchange membrane (PEM) fuel cells.
Abstract
Purpose
The purpose of this paper is to investigate the effects of hydrogen humidity on the performance of air-breathing proton exchange membrane (PEM) fuel cells.
Design/methodology/approach
An efficient mathematical model for air-breathing PEM fuel cells has been built in MATLAB. The sensitivity of the fuel cell performance to the heat transfer coefficient is investigated first. The effect of hydrogen humidity is also studied. In addition, under different hydrogen humidities, the most appropriate thickness of the gas diffusion layer (GDL) is investigated.
Findings
The heat transfer coefficient dictates the performance limiting mode of the air-breathing PEM fuel cell, the modelled air-breathing fuel cell is limited by the dry-out of the membrane at high current densities. The performance of the fuel cell is mainly influenced by the hydrogen humidity. Besides, an optimal cathode GDL and relatively thinner anode GDL are favoured to achieve a good performance of the fuel cell.
Practical implications
The current study improves the understanding of the effect of the hydrogen humidity in air-breathing fuel cells and this new model can be used to investigate different component properties in real designs.
Originality/value
The hydrogen relative humidity and the GDL thickness can be controlled to improve the performance of air-breathing fuel cells.
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Jinbei Tian, Mohammed S. Ismail, Derek Ingham, Kevin J. Hughes, Lin Ma and Mohamed Pourkashanian
This paper aims to investigate the impact of three different flow channel cross sections on the performance of the fuel cell.
Abstract
Purpose
This paper aims to investigate the impact of three different flow channel cross sections on the performance of the fuel cell.
Design/methodology/approach
A comprehensive three-dimensional polymer electrolyte membrane fuel cell model has been developed, and a set of conservation equations has been solved. The flow is assumed to be steady, fully developed, laminar and isothermal. The investigated cross sections are the commonly used square cross section, the increasingly used trapezoidal cross section and a novel hybrid configuration where the cross section is square at the inlet and trapezoidal at the outlet.
Findings
The results show that a slight gain is obtained when using the hybrid configuration and this is because of increased velocity, which improves the supply of the reactant gases to the catalyst layers (CLs) and removes heat and excess water more effectively compared to other configurations. Further, the reduction of the outlet height of the hybrid configuration leads to even better fuel cell performance and this is again because of increased velocity in the flow channel.
Research limitations/implications
The data generated in this study will be highly valuable to engineers interested in studying the effect of fluid cross -sectional shape on fuel cell performance.
Originality/value
This study proposes a novel flow field with a variable cross section. This design can supply a higher amount of reactant gases to the CLs, dissipates heat and remove excess water more effectively.
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Isaac Chukwuemezu Okereke, Mohammed S. Ismail, Derek Ingham, Kevin J. Hughes, Lin Ma and Mohamed Pourkashanian
This paper aims to numerically investigate the impact of gas diffusion layer (GDL) anisotropic transport properties on the overall and local performance of polymer electrolyte…
Abstract
Purpose
This paper aims to numerically investigate the impact of gas diffusion layer (GDL) anisotropic transport properties on the overall and local performance of polymer electrolyte fuel cells (PEFCs).
Design/methodology/approach
A three-dimensional numerical model of a polymer electrolyte fuel cell with a single straight channel has been developed to investigate the sensitivity of the fuel cell performance to the GDL anisotropic transport properties – gas permeability, diffusivity, thermal conductivity and electrical conductivity. Realistic experimentally estimated GDL transport properties were incorporated into the developed PEFC model, and a parametric study was performed to show the effect of these properties on fuel cell performance and the distribution of the key variables of current density and oxygen concentration within the cathode GDL.
Findings
The results showed that the anisotropy of the GDL must be captured to avoid overestimation/underestimation of the performance of the modelled fuel cell. The results also showed that the fuel cell performance and the distributions of current density and oxygen mass fraction within the cathode GDL are highly sensitive to the through-plane electrical conductivity of the GDL and, to a lesser extent, the through-plane diffusivity, and the thermal conductivity of the GDL. The fuel cell performance is almost insensitive to the gas permeability of the GDL.
Practical implications
This study improves the understanding of the importance of the GDL anisotropy in the modelling of fuel cells and provides useful insights on improving the efficiency of the fuel cells.
Originality/value
Realistic experimentally estimated GDL transport properties have been incorporated into the PEFC model for the first time, allowing for more accurate prediction of the PEFC performance.
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Mohammed S. Ismail, Mohamed R. Berber, Ziyad A. Alrowaili and Mohamed Pourkashanian
This paper aims to numerically solve fully developed laminar flow in trapezoidal ducts with rounded corners which result following forming processes.
Abstract
Purpose
This paper aims to numerically solve fully developed laminar flow in trapezoidal ducts with rounded corners which result following forming processes.
Design/methodology/approach
A two-dimensional model for a trapezoidal duct with rounded corners is developed and conservation of momentum equation is solved. The flow is assumed to be steady, fully developed, laminar, isothermal and incompressible. The key flow characteristics including the Poiseuille number and the incremental pressure drop have been computed and tabulated for a wide range of: sidewall angle (θ); the ratio of the height of the duct to its smaller base (α); and the ratio of the fillet radius of the duct to its smaller base (β).
Findings
The results show that Poiseuille number decreases, and all the other dimensionless numbers increase with increasing the radii of the fillets of the duct; these effects were found to amplify with decreasing duct heights or increasing sidewall angles. The maximum axial velocity was shown to increase with increasing the radii of the fillets of the duct. For normally used ducts in hydrogen fuel cells, the impact of rounded corners cannot be overlooked for very low channel heights or very high sidewall angles.
Practical implications
The data generated in this study are highly valuable for engineers interested in estimating pressure drops in rounded trapezoidal ducts; these ducts have been increasingly used in hydrogen fuel cells where flow channels are stamped on thin metallic sheets.
Originality/value
Fully developed laminar flow in trapezoidal ducts with four rounded corners has been solved for the first time, allowing for more accurate estimation of pressure drop.
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Elena Carcadea, H. Ene, D.B. Ingham, R. Lazar, L. Ma, M. Pourkashanian and I. Stefanescu
This paper aims to present a three‐dimensional computational fluid dynamics (CFD) model that simulates the fluid flow, species transport and electric current flow in PEM fuel…
Abstract
Purpose
This paper aims to present a three‐dimensional computational fluid dynamics (CFD) model that simulates the fluid flow, species transport and electric current flow in PEM fuel cells.
Design/methodology/approach
The model makes use of a general‐purpose CFD software as a basic tool incorporating fuel cell specific submodels for multi‐component species transport, electrochemical kinetics, water management and electric phase potential analysis in order to simulate various processes that occur in a PEM fuel cell.
Findings
Three dimensional results for the flow field, species transport, including waster formations, and electric current distributions are presented for two test flow configurations in the PEM fuel cell. For the two cases presented, reasonable predictions have been obtained, and this provides an insight into the effect of the flow designs to the operation of the fuel cell.
Research limitations/implications
It is appreciated that the CFD modeling of fuel cells is, in general, still facing significant challenges due to the limited understanding of the complex physical and chemical processes existing within the fuel cell. The model is now under further development to improve its capabilities and undergoing further validations.
Practical implications
The model simulations can provide detailed information on some of the key fluid dynamics, physical and chemical/electro‐chemical processes that exist in fuel cells which are crucial for fuel cell design and optimization.
Originality/value
The model can be used to understand the operation of the fuel cell and provide and alternative to experimental investigations in order to improve the performance of the fuel cell.
Details
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Mohammed Ismail, Derek Ingham, Kevin J Hughes, Lin Ma and Mohamed Pourkashanian
The purpose of this paper is to numerically investigate the effects of the shape on the performance of the cathode catalyst agglomerate used in polymer electrolyte fuel cells…
Abstract
Purpose
The purpose of this paper is to numerically investigate the effects of the shape on the performance of the cathode catalyst agglomerate used in polymer electrolyte fuel cells (PEFCs). The shapes investigated are slabs, cylinders and spheres.
Design/methodology/approach
Three 1D models are developed to represent the slab like, cylindrical and spherical agglomerates, respectively. The models are solved for the concentration of the dissolved oxygen using a finite element software, COMSOL Multiphysics®. “1D” and “1D axisymmetric” schemes are used to model the slab like and cylindrical agglomerates, respectively. There is no one-dimensional scheme available in COMSOL Multiphysics® for spherical coordinate systems. To resolve this, the governing equation in “1D” scheme is mathematically modified to match that of the spherical coordinate system.
Findings
For a given length of the diffusion path, the variation in the performances of the investigated agglomerates is dependent on the operational overpotential. Under low magnitudes of the overpotentials, where the performance is mainly limited by reaction, the slab-like agglomerate outperforms the spherical and cylindrical agglomerates. In contrast, under high magnitudes of the overpotentials where the agglomerate performance is mainly limited by diffusion, the spherical and cylindrical agglomerates outperform the slab-like agglomerate.
Practical implications
The current advances in the nano-fabrication technology gives more flexibility in designing the catalyst layers in PEFCs to the desired structures. If the design of the agglomerate catalyst is to be assessed, the current micro-scale modelling offers an efficient and rapid way forward.
Originality/value
The current micro-scale modelling is an efficient alternative to developing a full (or half) fuel cell model to evaluate the effects of the agglomerate structure.
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Wei Chen, Hengjie Xu, Wenyuan Mao, Meihong Liu, Xuejian Sun and Qiangguo Deng
This study aims to investigate the influence mechanism of thermal-mechanical deformations on the CO2 mixture gases dry gas seal (DGS) flow field and compare the deformation…
Abstract
Purpose
This study aims to investigate the influence mechanism of thermal-mechanical deformations on the CO2 mixture gases dry gas seal (DGS) flow field and compare the deformation characteristics and sealing performance between two-way and one-way thermal-fluid-solid coupling models.
Design/methodology/approach
The authors established a two-way thermal-fluid-solid coupling model by using gas film thickness as the transfer parameter between the fluid and solid domain, and the model was solved using the finite difference method and finite element method. The thermal-mechanical deformations of the sealing rings, the influence of face deformation on the flow field and sealing performance were obtained.
Findings
Thermal-mechanical deformations cause a convergent gap between the two sealing end faces, resulting in an increase in the gas film thickness, but a decrease in the gas film temperature and sealing ring temperature. The axial relative deformations of rotating and stationary ring end faces caused by mechanical and thermal loads in the two-way coupling model are less than those in the one-way coupling (OWC) model, and the gas film thickness and leakage rate are larger than those in the OWC model, whereas the gas film stiffness is the opposite.
Originality/value
This paper provides a theoretical support and reference for the operational stability and structural optimization design of CO2 mixture gases DGS under high-pressure and high-speed operation conditions.
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Bashar Shboul, Mohamed E. Zayed, Hadi F. Marashdeh, Sondos N. Al-Smad, Ahmad A. Al-Bourini, Bessan J. Amer, Zainab W. Qtashat and Alanoud M. Alhourani
This paper aims to assess the economic, environmental, policy-related and social implications of establishing green hydrogen production in Jordan.
Abstract
Purpose
This paper aims to assess the economic, environmental, policy-related and social implications of establishing green hydrogen production in Jordan.
Design/methodology/approach
The comprehensive analysis has been investigated, including economic assessments, environmental impact evaluations, policy examinations and social considerations. Furthermore, the research methodology encompasses energy demand, sector, security and supply analysis, as well as an assessment of the availability of renewable energy resources.
Findings
The results indicate substantial economic benefits associated with green hydrogen production, including job creation, increased tax revenue and a reduction in energy imports. Additionally, the study identifies positive environmental impacts, such as decreased greenhouse gas emissions and air pollution. Noteworthy, two methods could be used to produce hydrogen, namely: electrolysis and thermochemical water splitting. As a recommendation, the study proposes that Jordan, particularly Aqaba, take proactive measures to foster the development of a green hydrogen industry and collaborate with international partners to exchange best practices and establish the necessary infrastructure.
Originality/value
To the best of the authors’ knowledge, this paper is among the first to provide a comprehensive perspective on the potential of green hydrogen production as a driving force for Jordan’s economy, while also benefiting the environment and society. However, the research recognizes several challenges that must be addressed to materialize green hydrogen production in Jordan, encompassing high renewable energy costs, infrastructure development requirements and community concerns. Despite these obstacles, the study asserts that the potential advantages of green hydrogen production outweigh the associated risks.
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Mehmet Numan Kaya, Oguz Uzol, Derek Ingham, Faruk Köse and Riza Buyukzeren
The purpose of this paper is to thoroughly investigate the aerodynamic effects of blade pitch angle on small scaled horizontal axis wind turbines (HAWTs) using computational fluid…
Abstract
Purpose
The purpose of this paper is to thoroughly investigate the aerodynamic effects of blade pitch angle on small scaled horizontal axis wind turbines (HAWTs) using computational fluid dynamics (CFD) method to find out the sophisticated effects on the flow phenomena and power performance.
Design/methodology/approach
A small HAWT is used as a reference to validate the model and examine the aerodynamic effects. The blade pitch angle was varied between +2 and −6 degrees, angles which are critical for the reference wind turbine in terms of performance, and the CFD simulations were performed at different tip speed ratio values, λ = 2, 3, 4, 5, 6, 7, 9 and 10.5 to cover the effects in various conditions. Results are examined in two different aspects, namely, general performance and the flow physics.
Findings
The power performance varies significantly according to the tip speed ratio; the power coefficient increases up to a certain pitch angle at the design tip speed ratio (λ = 6); however, between λ = 2 and 4, the more the blade is pitched downwards, the larger is the power coefficient, the smaller is the thrust coefficient. Similarly, for tip speed ratios higher than λ = 8, the positive effect of the low pitch angles on the power coefficient at λ = 6 reverses. The flow separation location moves close to the leading edge at low tip speed ratios when the blade is pitched upwards and the also tip vortices become more intense. In conclusion, the pitch control can significantly contribute to the performance of small HAWTs depending on different conditions.
Originality/value
In the literature, only very little attention has been paid to the aerodynamic effects of pitch angle on HAWTs, and no such study is available about the effects on small HAWTs. The change of blade pitch angle was maintained at only one degree each time to capture even the smallest aerodynamic effects, and the results are presented in terms of the power performance and flow physics.