Kumar P.E., Govindaraju M. and Sivakumar V.
The purpose of this paper is to study the corrosion inhibition performance of an eco-friendly drug clozapine on the corrosion of copper in 1.0 M nitric acid and 0.5 M sulfuric…
Abstract
Purpose
The purpose of this paper is to study the corrosion inhibition performance of an eco-friendly drug clozapine on the corrosion of copper in 1.0 M nitric acid and 0.5 M sulfuric acid solutions.
Design/methodology/approach
The corrosion inhibition nature of inhibitor molecule was evaluated by weight loss, electrochemical impedance spectroscopy and potentiodynamic polarization studies. An attempt was made to correlate the molecular properties of neutral and protonated forms of inhibitor molecule using quantum chemical calculations. The effect of temperature on the corrosion inhibition efficiency was also studied using electrochemical impedance spectroscopy. The potential of zero charge was determined to explain the mechanism of corrosion inhibition.
Findings
The studies on corrosion inhibition performance of clozapine showed that it has good corrosion inhibition efficiency on the corrosion of copper in 1.0 M nitric acid and 0.5 M sulfuric acid solutions. The adsorption of clozapine molecules onto the copper surface obeyed the Langmuir adsorption isotherm. The value of free energy of adsorption calculated is very close to −40 kJmol−1, indicating that the adsorption is through electrostatic coulombic attraction and chemisorption. The decrease in the value of energy of activation with the addition of inhibitor also shows the chemisorption of the inhibitor on the metal surface. The potential of zero charge and quantum chemical studies confirmed that the protonated molecules also get involved in the corrosion inhibition process through physisorption.
Originality/value
The present work indicates that clozapine can act as a good corrosion inhibitor for the corrosion of copper in acid media.
Details
Keywords
May El Barachi, Roch H. Glitho and Rachida Dssouli
Applications offered to end‐users as value‐added services play a vital role in the success of Internet telephony service providers. Today’s standard frameworks for developing them…
Abstract
Applications offered to end‐users as value‐added services play a vital role in the success of Internet telephony service providers. Today’s standard frameworks for developing them have several shortcomings that motivate the need for novel frameworks. Web services are an emerging paradigm for program‐to‐program interactions over the Internet. This paradigm is a prime candidate for application development in Internet Telephony because it may aid in addressing the drawbacks of today’s standard frameworks. This paper presents a case study that gives insights in the suitability of Web services as a standard framework for the development of conferencing applications in Internet Telephony. The case study includes the definition and the implementation of a novel Web service for conferencing, the implementation of the conference server in a SIP environment, the development of several conferencing applications (including a game), and performance evaluation. Based on this case study, we conclude that Web services are very promising for conferencing application development in Internet Telephony, especially as the performance can be significantly improved with the emerging techniques that are briefly discussed in the paper.
Details
Keywords
Imam Machdi, Toshiyuki Amagasa and Hiroyuki Kitagawa
The purpose of this paper is to propose general parallelism techniques for holistic twig join algorithms to process queries against Extensible Markup Language (XML) databases on a…
Abstract
Purpose
The purpose of this paper is to propose general parallelism techniques for holistic twig join algorithms to process queries against Extensible Markup Language (XML) databases on a multi‐core system.
Design/methodology/approach
The parallelism techniques comprised data and task parallelism. As for data parallelism, the paper adopted the stream‐based partitioning for XML to partition XML data as the basis of parallelism on multiple CPU cores. The XML data partitioning was performed in two levels. The first level was to create buckets for creating data independence and balancing loads among CPU cores; each bucket was assigned onto a CPU core. Within each bucket, the second level of XML data partitioning was performed to create finer partitions for providing finer parallelism. Each CPU core performed the holistic twig join algorithm on each finer partition of its own in parallel with other CPU cores. In task parallelism, the holistic twig join algorithm was decomposed into two main tasks, which were pipelined to create parallelism. The first task adopted the data parallelism technique and their outputs were transferred to the second task periodically. Since data transfers incurred overheads, the size of each data transfer needed to be estimated cautiously for achieving optimal performance.
Findings
The data and task parallelism techniques contribute to good performance especially for queries having complex structures and/or higher values of query selectivity. The performance of data parallelism can be further improved by task parallelism. Significant performance improvement is attained by queries having higher selectivity because more outputs computed by the second task is performed in parallel with the first task.
Research limitations/implications
The proposed parallelism techniques primarily deals with executing a single long‐running query for intra‐query parallelism, partitioning XML data on‐the‐fly, and allocating partitions on CPU cores statically. During the parallel execution, presumably there are no such dynamic XML data updates.
Practical implications
The effectiveness of the proposed parallel holistic twig joins relies fundamentally on some system parameter values that can be obtained from a benchmark of the system platform.
Originality/value
The paper proposes novel techniques to increase parallelism by combining techniques of data and task parallelism for achieving high performance. To the best of the author's knowledge, this is the first paper of parallelizing the holistic twig join algorithms on a multi‐core system.
Details
Keywords
The aim of this paper is to determine a parallel computational methodology for simultaneously predicting the macro/micro scale phenomena occurring during solidification processing…
Abstract
Purpose
The aim of this paper is to determine a parallel computational methodology for simultaneously predicting the macro/micro scale phenomena occurring during solidification processing with external electromagnetic stirring.
Design/methodology/approach
Macro and micro phenomena occurring in an electromagnetically‐stirred solidifying melt are simulated using a numerical model that integrates the finite element methodology for transport phenomena and the Monte‐Carlo cellular‐automata method for microstructure formation. Parallel algorithm is introduced to enhance the computational efficiency.
Findings
Computed results show that parallel algorithm can be effective in enhancing the computational efficiency of a combined macro/micro model if it is applied appropriately. Also, electromagnetically induced stirring can have a strong effect on the nucleation and grain growth and hence the final solidification microstructure.
Originality/value
This paper fulfils a need for developing an efficient numerical methodology to simulate complex electromagnetically‐assisted transport phenomena and microstructure formation during solidification processing systems.
Details
Keywords
Anil Mital, M. Govindaraju and B. Subramani
Seeks to determine whether hybrid inspection performance is superior to manual performance in a generic manufacturing setup. Explains the design of an experiment to achieve this…
Abstract
Seeks to determine whether hybrid inspection performance is superior to manual performance in a generic manufacturing setup. Explains the design of an experiment to achieve this comparison. Results include the fact that the hybrid method took substantially less time and caused fewer inspection errors. Notes that cost factors would need to be carefully considered before selection of a preferred method but that ultimately the hybrid method should be the logical choice.
Details
Keywords
Majorkumar Govindaraju, Arunkumar Pennathur and Anil Mital
In the increasingly competitive global economy, survival of an industry depends on catering to customer needs by quickly producing quality products and providing quality service…
Abstract
In the increasingly competitive global economy, survival of an industry depends on catering to customer needs by quickly producing quality products and providing quality service at an affordable price. In production, or in service, ergonomic considerations have manifested themselves in two distinct, yet related, domains. Focuses on the humans who contribute to product manufacture/service. It is frequently advocated that since humans are unreliable and less consistent, compared to machines, they are primarily responsible for lowering product and service quality. Ergonomic considerations, which, ironically, can improve human performance, are paid lip service during manufacturing system design. Compounding the problem is the current inability of most ergonomists to make ergonomic recommendations that do not run counter to the productivity and quality goals of system designers. Addresses these two issues by illustrating, through four case studies, the relationship between quality and variables that affect human performance.
Details
Keywords
Sarfaraz Kamangar, N. Ameer Ahamad, N. Nik-Ghazali, Ali E. Anqi, Ali Algahtani, C. Ahamed Saleel, Syed Javed, Vineet Tirth and T.M. Yunus Khan
Coronary artery disease (CAD) is reported as one of the most common sources of death all over the world. The presence of stenosis (plaque) in the coronary arteries results in the…
Abstract
Purpose
Coronary artery disease (CAD) is reported as one of the most common sources of death all over the world. The presence of stenosis (plaque) in the coronary arteries results in the restriction of blood supply, leading to myocardial infarction. The current study investigates the influence of multi stenosis on hemodynamic properties in a patient-specific left coronary artery.
Design/methodology/approach
A three-dimensional model of the patient-specific left coronary artery was reconstructed based on computed tomography (CT) scan images using MIMICS-20 software. The diseased model of the left coronary artery was investigated, having the narrowing of 90% and 70% of area stenosis (AS) at the left anterior descending (LAD) and left circumflex (LCX), respectively.
Findings
The results indicate that the upstream region of stenosis experiences very high pressure for 90% AS during the systolic period of the cardiac cycle. The pressure drops maximum as the flow travels into the stenotic zone, and the high flow velocities were observed across the 90% AS. The higher wall shear stresses occur at the stenosis region, and it increases with the increase in the flow rate. It is found that the maximum wall shear stress across 90% AS is at the highest risk for rupture. A recirculation region immediately after the stenosis results in the further development of stenosis.
Originality/value
The current study provides evidence that there is a strong effect of multi-stenosis on the blood flow in the left coronary artery.
Details
Keywords
Sumaira Qayyum, Muhammad Ijaz Khan, Tasawar Hayat and Ahmed Alsaedi
The purpose of this study is to analyze the Entropy generation analysis and heat transport in three-dimensional flow between two stretchable disks. Joule heating and heat…
Abstract
Purpose
The purpose of this study is to analyze the Entropy generation analysis and heat transport in three-dimensional flow between two stretchable disks. Joule heating and heat generation/absorption are incorporated in the thermal equation. Thermo-diffusion effect is also considered. Flow is conducting for time-dependent applied magnetic field. Induced magnetic field is not taken into consideration. Velocity and thermal slip conditions at both the disks are implemented. The flow problem is modeled by using Navier–Stokes equations with entropy generation rate and Bejan number.
Design/methodology/approach
Von Karman transformations are used to reduce the nonlinear governing expressions into an ordinary one and then tackled by homotopy analysis method for convergent series solutions. The nonlinear expressions for total entropy generation rate are obtained with appropriate transformations. The impacts of different flow variables on velocity, temperature, entropy generation rate and Bejan number are described graphically. Velocity, temperature and concentration gradients are discussed in the presence of flow variables.
Findings
Axial, radial and tangential velocity profiles show decreasing trend for larger values of velocity slip parameters. For a larger Brinkman number, the entropy generation increases, while a decreasing trend is noticed for Bejan number.
Originality/value
To the best of the authors’ knowledge, no such analyses have been reported in the literature.
Details
Keywords
Sumaira Qayyum, Tasawar Hayat and Ahmed Alsaedi
Investigation for convective flow of water-based nanofluid (composed of ferric oxide asnanoparticles) by curved stretching sheet of variable thickness is made. Bejan number…
Abstract
Purpose
Investigation for convective flow of water-based nanofluid (composed of ferric oxide asnanoparticles) by curved stretching sheet of variable thickness is made. Bejan number andentropy generation analysis is presented in presence of viscous dissipation, mixed convectionand porous medium.
Design/methodology/approach
In this paper, by using NDSolve of MATHEMATICA, the nonlinear system of equations is solved. Velocity, temperature, Bejan number and entropy generation for involved dimensionless variables are discussed.
Findings
Increase in velocity is depicted for larger curvature parameter, and opposite trend is witnessed for higher nanoparticle volume concentration. Enhancement in temperature is seen for higher Eckert number while reverse behavior is noticed for larger curvature parameter. Entropy rate increases for variation of curvature parameter, Brinkman number and nanoparticle volume fraction. Bejan number decays for mixed convection and curvature parameters.
Originality/value
To the authors’ knowledge, there exists no study yet which describes flow by curved sheet of variable thickness. Such consideration with nanoparticles seems important task. Thus, the main objective here is to determine entropy generation in ferromagnetic nanofluid flow due to variable thickened curved stretching surface. Additionally, effects of Joule heating, porous medium, mixed convection and viscous dissipation are taken into account.
Details
Keywords
Ayodeji E. Oke and Seyi S. Stephen
The interaction of systems through a designated control channel has improved communication, efficiency, management, storage, processing, etc. across several industries. The…
Abstract
The interaction of systems through a designated control channel has improved communication, efficiency, management, storage, processing, etc. across several industries. The construction industry is an industry that thrives on a well-planned workflow rhythm; a change in the environmental dynamism will either have a positive or negative impact on the output of the project planned for execution. More so, raising the need for effective collaboration through workflow and project planning, grid application in construction facilitates the relationship between the project reality and the end users, all with the aim of improving resources and value management. However, decentralisation of close-domain control can cause uncertainty and incompleteness of data. And this can be a big factor, especially when a complex project is being executed.