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The purpose of this paper was to protect carbon steel from corrosion with self–aggregated, eco-friendly, water-soluble hyperbranched polyamide-ester (Hb-PAE).

Hb-PAE was synthesized through bulk polycondensation reaction between maleic anhydride and di-isopropanol amine. Complete structural analysis for the obtained polymer was performed using Fourier Transfer Infra-Red Spectroscopy, 1H NMR, Thermal gravimetric analysis (TGA) and differential scanning calorimetry, and the molar mass was measured using gel permeation chromatography/refractive index. For this study, the surface activity of Hb-PAE with hydroxyl end groups was investigated. Surface tension of 1.0 × 10−6 to 0.1M of both Hb-PAE/H₂O and Hb-PAE/1N HCl systems was measured, and the critical aggregation concentration (CAC) in both systems was determined. Hb-PAE was examined as a corrosion inhibitor for plain carbon steel in both neutral (distilled water) and acidic (1N HCl) media. The corrosion of the steel was studied quantitatively by measuring its weight loss in both media in the absence and presence of Hb-PAE. The surface morphology of the exposed steel test samples was examined using scanning electron microscopy.

It was found that Hb-PAE inhibited corrosion of steel around the CAC, and its corrosion inhibition efficiency was increased by increasing its concentration.

The research can provide a reference for the relationship between the aggregation concentration of the prepared Hb-PAE with its corrosion inhibition efficiency on plain carbon steel. Hb-PAE as a corrosion inhibitor is environmentally acceptable, economical and readily available.

The purpose of this paper is to show how to remove some dyestuffs, as pollutants, from their aqueous solutions.

To achieve the goal, a water soluble hyperbranched poly (ester‐amide) (HBP) was synthesised using the melt polycondensation method by the reaction of maleic anhydride (MA) and diisopropanol amine (DIPA) at 140°C at a molar ratio of 1:1.3 MA: DIPA, respectively. This HBP was incorporated in the preparation of an effective microcrystalline cellulose (MCC)/dimethyloldihydroxyethylene urea (DMDHEU)/HBP adduct by crosslinking HBP with DMDHEU in presence of MCC. Furthermore, the prepared adduct was characterised by investigation its infra red and then utilised in the removal of three anionic dyestuffs from aqueous solutions, namely Irgalan Blau 3GL (an acid dye), SIRIUS Blau S‐BRR (a direct dye) and Levafix Brill Orange P‐GR (a hydrolysed reactive dye).

The results obtained revealed that the optimum conditions for preparing MCC/DMDHEU/HBP adduct are [HBP], 90 g/l; [DMDHEU], 200 g/l; LR, 1/3.3; [NC₄LH], 20 g/l; a time of 30 min and a temperature of 160°C. Moreover, the results also showed that the extent of removal of such dyestuffs from their aqueous solutions by the prepared adduct follows the order: reactive dye>acid dye>direct dye, it is more pronounced at lower than at higher pH values and the removal of each dye by that adduct follows a first‐order reaction.

Other substrates such as chitosan can be used to prepare more effective adducts.

Hyperbranched polymers can be used effectively to prepare ion exchangers capable of removing the pollutants of dyestuffs from their aqueous solutions.

The aforementioned prepared HBP is a novel hyperbranched polymer and could be applied in the removal of many other pollutants.

This paper aims to investigate the prepared modified alkyd and poly(ester-amide) (PEA) resins as antimicrobial and insecticide binders for surface coating applications.

Salicylic diethanolamine and 4-(N, N-dimethylamino) benzylidene glutamic acid were prepared and used as new sources of polyol and dibasic acid for PEA and alkyd resins, then confirmed by: acid value, FT-IR and 1H-NMR. The coating performance of the resins was determined using measurements of physico-mechanical properties. The biological and insecticide activities of the prepared resins were investigated.

The tests carried out revealed that the modified PEA and alkyd enhanced both phyisco-mechanical and chemical properties in addition to the biological and insecticide activities. The results of this paper illustrate that the introduction of salicylic diethanolamine and 4-(N, N-dimethylamino) benzylidene glutamic acid within the resin structure improved the film performance and enhanced the antimicrobial activity performance of PEA and alkyd resins.

The modified alkyd and PEA organic resins can be used as biocidal binders when incorporated into paint formulations for multiple surface applications, especially those that are exposed to several organisms.

Modified alkyd and PEA resins based on newly synthesized modifiers have a significant potential to be promising in the production and development of antimicrobial and insecticide paints, allowing them to function to restrict the spread of insects and microbial infection.

The purpose of this paper is to minimize corrosion-related pollution in the environment. From the lemongrass extract (LGE), the authors selected one of the best green inhibitors.

The corrosion and inhibition of mild steel in traditional acidification solutions were estimated by electrochemical measurements. The corrosion appearance was observed with scanning electron microscopy, atomic force microscopy micrographs and attenuated total reflectance infrared spectroscopy spectrum. The correlation was formed between the gained inhibition efficiency (IE)% from electrochemical measurements and certain quantum chemical parameters.

The results displayed that the IE was up to 90% when the LGE concentration was 300 ppm. The results confirmed that the theoretical experiments are very similar to the experimental observations.

For the first time, LGE was used as a cheap and safe corrosion inhibitor for mild steel corrosion in the acidification process. The mechanism of mild steel corrosion and anti-corrosion in acid solution has been suggested.

This study aims to offer an effective nanocomposite for potential use to consolidate and protect deteriorated archaeological pottery.

Three nanocomposites were used in the experimental study. This study used nano Primal AC33, silicon dioxide (SiO₂) and montmorillonite (MMT) nanoparticles to protect and consolidate pottery specimens. Pottery specimens were made at 800°C for this investigation. Consolidation materials were applied with a brush. The properties of the treated pottery specimens were assessed using several methods such as digital and scanning electron microscopes, static water contact angle, color alteration, physical properties and compressive strength.

Microscopic examination indicated the ability of the nano Primal AC33/MMT nanocomposites to cover the outer surface well and bind the inner granules. Concerning specimens with code F treated with nano Primal AC33 5%/MMT 3% nanocomposites, it achieved an increase in contact angle (120°), density (1.23 g/cm³) and compressive strength (561 kg/cm²), as well as a decrease in color change (ΔE = 2.62), water absorption (4.45%) and porosity (5.46%). The novelty of the results is due to the characteristics of nano Primal AC33 5%/MMT 3% nanocomposites used in the current study.

This study describes the significant results of the analytical methods used for evaluating consolidation materials used in this study. The findings offer useful information for the protection of archaeological pottery. The investigation indicated that nano Primal AC33 5%/MMT 3% nanocomposites gave the best results. Therefore, it is recommended to use this nanocomposite to consolidate archaeological pottery. As a result, the current work provides a promising first step in conserving archaeological pottery for future studies.

This study aims to examine the flow of unsteady mixed convective hybrid nanofluid over a rotating sphere with heat generation/absorption. The hybrid nanofluid contains different shapes of nanoparticles (copper [Cu] and aluminium oxide [Al₂O₃]) in the base fluid (water [H₂O]). The influence of different shapes (sphere, brick, cylinder, platelets and blades) of nanoparticle in water-based hybrid nanofluid is also investigated.

To analyse the nanomaterial, the flow model is established, and in doing so, the Prandtl’s boundary layer theory is incorporated into the present model. The bvp4c approach, i.e. finite difference method, is used to find the numerical solution of differential equations that is controlling the fluid flow. The effect of relevant flow parameters on nanofluid temperature and velocity profile is demonstrated in detailed explanations using graphs and bar charts, whereas numerical results for Nusselt number and the skin’s coefficient for various form parameters are presented in tabular form.

The rate of heat transfer is least for spherical-shaped nanoparticle because of its smoothness, symmetricity and isotropic behaviour. The rate of heat transfer is highest for blade-shaped nanoparticles as compared to other shapes (brick, cylindrical and platelet) of nanoparticles because the blade-shaped nanoparticles causes comparatively more turbulence flow in the nanofluid than other shapes of nanoparticle. Heat generation affects the temperature distribution and, hence, the particle deposition rate. The absorption of heat extracts heat and reduce the temperature across the rotating sphere. The heat generation/absorption parameter plays an important role in establishing and maintaining the temperature around the rotating sphere.

The numerical study is valid with the exception of the fluctuation in density that results in the buoyancy force and the functional axisymmetric nanofluid transport has constant thermophysical characteristics. In addition, this investigation is also constrained by the assumptions that there is no viscosity dissipation, no surface slippage and no chemically activated species. The hybrid nanofluid Al₂O₃–Cu/H₂O is an incompressible and diluted suspension. The single-phase hybrid nanofluid model is considered in which the relative velocity of water (H₂O) and hybrid nanoparticles (Al₂O₃–Cu) is the same and they are in a state of thermal equilibrium.

Study on convective flow across a revolving sphere has its applications found in electrolysis management, polymer deposition, medication transfer, cooling of spinning machinery segments, spin-stabilized missiles and other industrial and technical applications.

The originality of the study is to investigate the effect of shape factor on the flow of electrically conducting hybrid nanofluid past a rotating sphere with heat generation/absorption and magnetic field. The results are validated and provide extremely positive balance with the recognised articles. The results of the study provide many appealing applications that merit further study of the problem.

To modify a conventional evacuated tube, an improved asymmetric U-type evacuated tube (AUET) is proposed. This study aims to investigate the thermal and hydrodynamic performances of a modified tube and determine the optimal structural form.

Based on the variation of fluid proprieties with temperature, the formulated numerical model was validated and then deployed to investigate the natural circulation in the evacuated tubes. A dimensionless number was proposed to quantify the stratification effect. The influence of the degree of asymmetry of U-type evacuated tubes on the flow patterns, mass flow rate, temperature distribution, thermal stratification and energy conversion efficiency was studied.

When the degree of asymmetry is large, a higher velocity and better thermal stratification are achieved, thereby avoiding stagnant water at the bottom of the tubes simultaneously. Compared with the conventional evacuated tube, the improved evacuated tube exhibited a higher thermal efficiency.

The originally proposed AUET was proven to have better performance in avoiding stagnant water, reducing fluid mixing and improving the heat transfer efficiency.

The purpose of this paper is to study the effect of gamma-rays on murexide (Mx) dye and its possible use as radiation dosimeters in two different dosimetry systems. The first system depends on the Mx dye as a liquid dosimeter. The second dosimetry system depends also on the same dye but as in a gel form, which is more sensitive to gamma-rays.

The prepared Mx (solutions/gels) have a considerable two peaks at 324 and 521 nm that upon irradiation, the intensity of these peaks decreases with the increasing radiation dose.

The gamma-ray absorbed dose for these dosimeters was found to be up to 2 kGy for the solution samples and 40 Gy for the gels. Radiation chemical yield, dose response function, radiation sensitivity and before and after-irradiation stability under various conditions were discussed and studied.

It is expected that the radiolysis of the Mx dye can be used as radiation dosimeters in two different dosimetry systems; liquid and gel dosimeters. This can be applied in a wide range of gamma radiation practical industrial applications in water treatment, food irradiation dosimeters, radiotherapy and fresh food irradiation and seed production.

Both of the prepared Mx dyes, either as solutions or gel samples, can be facilely prepared from commercially, cheap, safe, available chemicals and suitable for useful applied Mx solutions and gels radiation dosimeters.

The purpose of this paper is to fall light on the possibility of using the biopolymer chitosan in gamma dose monitoring.

The chitosan films were irradiated to gamma rays in the range starting from 10 to 120 kGy at a dose rate of 1.4 kGy/h using ⁶⁰Co gamma source. The ultra violet and visible (UV/Vis) spectrophotometry were used to examine the optical properties of chitosan film. Also, Fourier transform infrared (FTIR) analysis was used to detect and trace any change in structural bands that may take place upon irradiation.

Increase in optical density of the chitosan film was recorded at 298 nm that correlated with increasing in the absorbed doses. Change in color of the film from pale yellow to denser yellow was detected upon increasing the absorbed doses. The close investigation for UV/Vis and FTIR analysis nominates the chitosan film to be used as a label-dosimeter in the range of 10–120 kGy depending on chitosan concentrations. The chitosan film has an excellent stability in different environmental conditions with ±3.7% uncertainty in measurements (2σ, approximately equal to a 95% confidence level).

Chitosan film may be used as a medium and high-dose monitor with an acceptable overall uncertainty in routine radiation processing

The useful dose range from 10 to 80 kGy was detected for different concentrations of chitosan (0.5, 1, 1.5 Wt%) that correlated with increasing the absorbed dose, which is assigned to the linear parts in the target response curves. For the dose range 10–120 kGy, the film may be used as label dosimeter with detected color change from pale yellow to dense yellow.

This paper aims to prepare alkyd protective paint by using modified alkyd with 3,6-dichloro benzo[b]thiophene-2-carbonyl glutamic acid (DCBTGA) as a source of dicarboxylic acid and evaluating their anticorrosive properties compared with those of unmodified alkyd coatings for steel protection.

Short, medium and long oil alkyds, which represented as (0, 10, 20 and 30% excess-OH) according to the resin constants (Patton, 1962), were prepared through a condensation polymerization reaction via a solvent process in a one-step reaction. The modification of alkyd was carried out by using DCBTGA as a source of dicarboxylic acid. The prepared modified alkyd was confirmed by IR and NMR spectral analysis. The physicochemical, mechanical and anticorrosion performance properties of the considered modified coating formulations against unmodified blank coating were studied to confirm their application efficiency.

The best results in terms of physicochemical, mechanical and anticorrosion performance properties were found according to the following of this order activity: 30 replacements of the modifier (DCBTGA) for each hydroxyl continent were 30% Ex-OH > 20% Ex-OH > 10% Ex-OH > 0% Ex-OH, compared with that formulation containing unmodified alkyd, especially with increasing the modifier percent.

The prepared DCBTGA-modified resins can be used for different applications based on the type of alkyd and application.