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Article
Publication date: 2 August 2021

Lucie Zárybnická, Eliška Stránská, Kristýna Janegová and Barbora Vydrová

The study aims to focus on the preparation of a heterogeneous cation exchange membrane by a three-dimensional (3D) method – fused filament fabrication using a series of nozzles of…

138

Abstract

Purpose

The study aims to focus on the preparation of a heterogeneous cation exchange membrane by a three-dimensional (3D) method – fused filament fabrication using a series of nozzles of various diameters (0.4–1.0 mm). Polypropylene random copolymer (PPR) as a polymeric binder was mixed with 50 Wt.% of the selected conventional cation exchange resin, and a filament was prepared using a single screw mini extruder. Then filament was processed by FFF into the membranes with a defined 3D structure.

Design/methodology/approach

Electrochemical properties, morphology, mechanical properties and water absorption properties were tested.

Findings

Dependence of the tested properties on the used nozzle diameter was found. Both areal and specific resistances increased with increasing nozzle diameter. The same trend was also found for permselectivity. The optimal membrane with permselectivity above 90%, areal resistance of 8 O.cm2 and specific resistance of 124 O.cm2 was created using a nozzle diameter of 0.4 mm.

Originality/value

Using new materials for 3D print of cation exchange membrane with production without waste. The possibility of producing 3D membranes with a precisely defined structure and using a cheap 3D printing method. New direction of membrane structure formation. 3D-printed heterogeneous cation exchange membranes were prepared, which can compete with commercial membranes produced by conventional technologies. 3D-printed heterogeneous cation exchange membranes were prepared, which can compete with commercial membranes produced by conventional technologies.

Details

Rapid Prototyping Journal, vol. 27 no. 8
Type: Research Article
ISSN: 1355-2546

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Article
Publication date: 28 May 2024

Karel Dvorak, Lucie Zarybnicka, Radek Ševčík, Michal Vopalensky and Irena Adamkova

The purpose of this paper is to clarify the relationship between the use of different polymer matrices for the preparation of composite materials, namely, polyethylene…

147

Abstract

Purpose

The purpose of this paper is to clarify the relationship between the use of different polymer matrices for the preparation of composite materials, namely, polyethylene terephthalate-glycol (PET-G) and polyamide (PA), using Composite Fiber Co-Extrusion technology with the application of two types of carbon fibers, short and continuous. The aim of the study is also to extend the knowledge of the production of composite materials with a defined structure from the point of view of their influence on the microstructure and their physical-mechanical properties.

Design/methodology/approach

As part of the experiment, four types of samples were prepared, namely, two types of samples with PA polymer matrix and two types with PET-G polymer matrix. All types contained short carbon fibers and always one set from each polymer matrix in addition to continuous carbon fibers. All types were prepared using the same 3D printing parameters to avoid any further influence. The samples were then tested for microstructure using microCT, mechanical properties using a tensile test and dilatation characteristics from the point of view of aerospace applications. Finally, the raw materials themselves were tested.

Findings

The paper provides insight into the influence of polymer matrix types on the physico-mechanical properties of 3D printed composites. The analysis confirmed that the physico-mechanical results varied with respect to the interface between the polymer matrix and the carbon fiber. The implications of the conclusions can be extended to the development of products in the aerospace and automotive sectors.

Originality/value

This study provides information for composite applications in the aerospace industry, focusing on evaluating dilatation characteristics within very low temperatures (−60 °C) when using carbon fibers (continuous carbon fibers, short carbon fibers and a combination of both) in two types of thermoplastic matrices. This perspective on materials characterisation for aerospace applications is a very important and unpublished approach within the 3D printing of composites. These characteristics are important parameters in the design of prototypes and functional samples with regard to the resulting behaviour in real conditions.

Details

Rapid Prototyping Journal, vol. 30 no. 6
Type: Research Article
ISSN: 1355-2546

Keywords

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Article
Publication date: 9 July 2020

Lucie Zarybnicka and Eliska Stranska

This paper aims to focus on the preparation of a cation exchange filament for three-dimensional (3D) fused deposition modeling (FDM). The polymeric binder was mixed with the…

195

Abstract

Purpose

This paper aims to focus on the preparation of a cation exchange filament for three-dimensional (3D) fused deposition modeling (FDM). The polymeric binder was mixed with the selected conventional cation exchange resin and a filament was prepared using a mini extruder. Filaments were tested by mechanical properties, chemical properties, quality and melt flow index. Samples were prepared from granulate using a press, which were tested for electrochemical properties, thermal properties. The best result of ion exchange capacity (IEC) up to 3.0 meq/g of the dry matter was achieved with filament fill 65%. Permselectivity results above 90% were determined for 55%–65% filling of the cation exchanger. The results obtained are a promising step for the preparation of 3D printed cation exchange membranes (CEMs) with a defined structure.

Design/methodology/approach

The prepared granulates and filaments were evaluated using mechanical, rheological and thermal properties.

Findings

The prepared cation exchange filament can be used for the 3D printing process. The best result of IEC up to 3.0 meq/g of the dry matter was achieved with filament fill 65%. Permselectivity results above 90% were determined for 55%–65% filling of the cation exchanger, and area resistances 3.0 Ocm2 and specific resistances around 57 Ocm for 65% filling of the cation exchanger. The results obtained are a promising step for the preparation of 3D printed CEMs with a defined structure.

Originality/value

The prepared cation exchange filament. Using new materials for 3D print of cation exchange membrane. Production without waste. The possibility of producing 3D membranes with a precisely defined structure. Processing prepared filaments using a cheap FDM 3D printing method. New direction of membrane formation.

Details

Rapid Prototyping Journal, vol. 26 no. 8
Type: Research Article
ISSN: 1355-2546

Keywords

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