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1 – 10 of 11Jianli Xie, Jiayuan Hu, Jundong Lu and Xinmin Li
The purpose of this paper was to study the corrosion control of B10 copper-nickel alloy using the LiOH-N2H4 compound inhibitors and to evaluate the feasibility of replacing the…
Abstract
Purpose
The purpose of this paper was to study the corrosion control of B10 copper-nickel alloy using the LiOH-N2H4 compound inhibitors and to evaluate the feasibility of replacing the original inhibitors (NaNO2-Na2MoO4) with the new ones (LiOH-N2H4) for the chilled water system in a nuclear unit.
Design/methodology/approach
The corrosion resistance performance of B10 copper-nickel alloy was evaluated during the whole replacement process of inhibiters using electrochemical tests and surface analysis techniques.
Findings
The results indicated that the corrosion of B10 copper-nickel alloy could be prevented effectively using LiOH to increase the pH value of solution higher than 10.0 and using N2H4 to consume dissolved oxygen. During the replacement process of inhibitors from NaNO2-Na2MoO4 to LiOH-N2H4, the corrosion resistance performance of B10 copper-nickel alloy had not decreased greatly. The new LiOH-N2H4 inhibitor, which could enhance the compactness of rust, was able to reduce the corrosion rate of rusted B10 metal.
Originality/value
It is feasible and operable to replace the NaNO2-Na2MoO4 inhibitors with the LiOH-N2H4 inhibitors for the corrosion prevention of B10 copper-nickel alloy. The research results can provide guidelines for the inhibitor selection of chilled water system in a nuclear unit.
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Shun'an Cao, Jiayuan Hu, Jianli Xie, Qinqin Liang and Li Yin
The purpose of this paper is to set out a study of the film‐forming characteristics of octadecylamine (ODA), estimate the feasibility of shutdown protection using ODA at high…
Abstract
Purpose
The purpose of this paper is to set out a study of the film‐forming characteristics of octadecylamine (ODA), estimate the feasibility of shutdown protection using ODA at high temperatures, and determine the optimum process condition of shutdown protection for units under full load if ODA has a good film‐forming effect at high temperatures.
Design/methodology/approach
An autoclave was used to simulate the water‐vapor environments at 350‐560°C in the water‐steam system of power plants. The decomposition test of ODA was investigated and the ODA film‐forming characteristics were studied for furnace tube materials used in gas‐fired power plants.
Findings
Results showed that ODA had a decomposition equilibrium and the decomposition products did not contain harmful organic substances such as low molecular organic acids. ODA would form a satisfactory protective film in the range of 350‐560°C with the best film at 480°C. The protection effect of the film formed by ODA at 560°C was much stronger than was that of its oxide film, which showed the feasibility of shutdown protection using ODA for gas‐fired power plants operating under full load. The optimal conditions of shutdown protection under full load were as follows: the temperature was 560°C, the concentration of ODA was 80 mg/L, the pH was 9.5 and the exposure time was 2 h. From the experimental results of X‐ray photoelectron spectroscopy, it was known that the surface film on the specimens was composed of a compound of ferroferric oxide and ODA, and the film‐forming mechanism was chemical adsorption between N in the ODA and Fe.
Originality/value
It was found that ODA has a good film‐forming effect at high temperatures and it is practicable to implement shutdown protection for base‐load units. The research results can provide theoretical guidelines for shutdown protection of gas‐fired power plants.
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Jiayuan Hu, Shunan Cao, Li Yin, Qinqin Liang and Jianli Xie
Some power plants in China that adopt reverse osmosis (RO) product water as their fresh water source face serious metal corrosion of their water distribution system. The corrosion…
Abstract
Purpose
Some power plants in China that adopt reverse osmosis (RO) product water as their fresh water source face serious metal corrosion of their water distribution system. The corrosion process of carbon steel in RO product water is still not clear and there is no suitable anti‐corrosion method for the power plant to employ. The purpose of this paper is to study the corrosion behavior of carbon steel in RO product water, determine the factors leading to the high corrosion rate of carbon steel, and then suggest appropriate anti‐corrosion measures.
Design/methodology/approach
By measuring polarization curves and AC impedance values of the corrosion system and analyzing corrosion products using scanning electron microscopy (SEM), infrared spectroscopy (IR) and X‐ray diffraction (XRD), the corrosion behavior of Q235A carbon steel in the RO product water derived from seawater was studied.
Findings
The experimental results showed that the corrosion process of carbon steel in RO product water is controlled by the diffusion process of oxygen, and the corrosion products contain γ‐FeOOH, Fe3O4 and small amounts of α‐FeOOH. Although rust formed had a double layer structure, the outer rust layer, which contained γ‐FeOOH and a little α‐FeOOH, was thin. The inner rust layer, containing Fe3O4, was the main component of the rust layer. Due to the weak acidity of RO product water, γ‐FeOOH can be transformed to Fe3O4 very quickly and Fe3O4 will accumulate on the metal surface. Because of the electrical conductivity and fractured surface of the Fe3O4 layer, the corrosion product layer cannot inhibit the corrosion process by hindering the diffusion process of oxygen, and hence the corrosion rate of carbon steel is always high.
Originality/value
The paper describes the first systematic research to be carried out on the corrosion behavior of carbon steel in RO product water. It was found that the generation and accumulation of Fe3O4 on the metal surface was the primary reason leading to the high corrosion rate of carbon steel, and anti‐corrosion measures can be chosen following the following rules: deoxygenation, raising of the pH of the solution, or addition of corrosion inhibitors to the solution.
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Jiayuan Hu, Shun'an Cao, Jianli Xie and Li Yin
The purpose of this investigation was to study the effects of sodium hexametaphosphate and zinc sulfate on the corrosion control of rusted iron in reverse osmosis (RO) product…
Abstract
Purpose
The purpose of this investigation was to study the effects of sodium hexametaphosphate and zinc sulfate on the corrosion control of rusted iron in reverse osmosis (RO) product water of seawater.
Design/methodology/approach
The synergistic effects and inhibition effects of corrosion inhibitors on rusted carbon steel were studied using the weight-loss method, electrochemical tests and surface analysis techniques.
Findings
The results indicated that sodium hexametaphosphate could partly suppress the corrosion of rusted steel, but zinc sulfate used alone had no inhibition effect. Hexametaphosphate and zinc sulfate showed a strong synergistic effect and the optimal ratio of two chemicals was 1:1. The inhibition efficiency appeared to increase with increasing inhibitor concentration and the ideal dosage of inhibitors was set at 20 mg/L, when chemical cost and inhibition efficiency were taken into account. Surface analysis results proved that this compound inhibitor could make the rust layer much more compact. The inhibitive mechanism was to combine with rust and form a protective film, which consisted of iron oxide, polyphosphate and Zn(OH)2.
Originality/value
It was found that the compound inhibitor consisting of sodium hexametaphosphate and zinc sulfate had a good inhibitive effect on rusted iron in RO product water. The research results can provide theoretical guidelines for corrosion control of rusted pipes in power plants.
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Jiayuan Hu, Shun‐an Cao and Jianli Xie
The purpose of this paper is to explore the long‐term corrosion behavior of carbon steel in 3% NaCl solution and evaluate the effect of rust layer on the corrosion process.
Abstract
Purpose
The purpose of this paper is to explore the long‐term corrosion behavior of carbon steel in 3% NaCl solution and evaluate the effect of rust layer on the corrosion process.
Design/methodology/approach
The corrosion behavior of rusted carbon steel in 3% NaCl solution was studied by means of infrared spectroscopy (IR) and electrochemical impedance spectroscopy (EIS).
Findings
The results indicated that the corrosion of carbon steel was affected by chloride ion in initial immersion and then controlled by the rust layer. The rust layer consisted of a thin outer layer (γ‐FeOOH layer) and a thick inner layer (Fe3O4 layer). The outer rust layer facilitated the cathodic process via reduction of γ‐FeOOH, while the inner rust layer provided a large cathode area and oxygen could be reduced on its surface. As a result, the corrosion rate of carbon steel was determined by the limiting diffusion rate of oxygen and stabilized at a high value.
Originality/value
The corrosion model of rusted carbon steel in 3% NaCl solution was established. It is probable that the iron rust in all slightly acidic water with low alkalinity can promote the corrosion process via reduction of γ‐FeOOH. Anti‐corrosion measures for iron in this type of solutions should be aimed to reduce the promoting effect of rust layer on the metal corrosion. The NaCl solution prepared from tap water is more suitable for the substitution of artificial water than that prepared from deionized water.
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Abstract
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Jianli Cui, Junping Duan, Binzhen Zhang and Xueli Nan
This paper aims to provide a fabrication and measurement of a highly stretchable pressure sensor with a “V-type” array microelectrode on a grating PDMS substrate.
Abstract
Purpose
This paper aims to provide a fabrication and measurement of a highly stretchable pressure sensor with a “V-type” array microelectrode on a grating PDMS substrate.
Design/methodology/approach
First, the “V-type” array structure on the silicon wafer was fabricated by the MEMS technology, and the fabrication process included ultra-violet lithography and silicon etching. The “V-type” array structure on the master mold was then replicated into polycarbonate, which served as an intermediate, negative mold, using a conventional nanoimprint lithography technique. The negative mold was subsequently used in the PDMS molding process to produce PDMS “V-type” array structures with the same structures as the master mold. An Ag film was coated on the PDMS “V-type” array structure surface by the magnetron sputtering process to obtain PDMS “V-type” array microelectrodes. Finally, a PDMS prepolymer was prepared using a Sylgard184 curing agent with a weight ratio of a 20:1 and applied to the cavity at the middle of the two-layer PDMS “V-type” array microelectrode template to complete hot-press bonding, and a pressure sensor was realized.
Findings
The experimental results showed that the PDMS “V-type” array microelectrode has high stretchability of 65 per cent, temperature stability of 0.0248, humidity stability of 0.000204, bending stability and cycle stability. Capacitive pressure sensors with a “V-type” array microelectrode exhibit ideal initial capacitance (111.45 pF), good pressure sensitivity of 0.1143 MPa-1 (0-0.35 Mpa), fast response and relaxation times (<200 ms), high bending stability, high temperature/humidity stability and high cycle stability.
Originality/value
The PDMS “V-type” array structure microelectrode can be used to fabricate pressure sensors and is highly flexible, crack-free and durable.
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Jian Li, Diansheng Chen, Chunjing Tao and Hui Li
Many studies have shown that rehabilitation robots are crucial for lower limb dysfunction, but application of many robotics have yet to be seen to actual use in China. This study…
Abstract
Purpose
Many studies have shown that rehabilitation robots are crucial for lower limb dysfunction, but application of many robotics have yet to be seen to actual use in China. This study aimed to improve a lower limb rehabilitation robot by details improving and practical design.
Design/methodology/approach
Structures and control system of a lower limb rehabilitation robot are improved in detail, including joint calculations, comfort analysis and feedback logic creation, and prototype experiments on healthy individuals and patients are conducted in a hospital.
Findings
All participating subjects did not experience any problems. The experiment shows detail improving is reasonable, and feasibility of the robot was confirmed, which has potential for overcoming difficulties and problems in practical application.
Research limitations/implications
Therapeutic effects need to be evaluated in the future. Also, more details should be improved continuously based on the actual demand.
Originality/value
The improved robot could assist the lower limb during standing or walking, which has significance for practical application and patients in China.
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Shang Zhang, Jinpeng Wang, Yongjian Ke, Nan Li and Zhenwen Su
Turnover intention is a critical predictor of an employee’s turnover behaviour. A high level of turnover rate significantly affects the productivity and morale of an enterprise…
Abstract
Purpose
Turnover intention is a critical predictor of an employee’s turnover behaviour. A high level of turnover rate significantly affects the productivity and morale of an enterprise. Previous research has indicated that job satisfaction plays a critical role in influencing an employee's turnover intention, but the underlying factors related to job satisfaction remain under-explored, which impedes the development of effective strategies for reducing turnover intention. In addition, little research examined job satisfaction and turnover intention in the context of the COVID-19 pandemic, specifically in the Chinese construction industry. This study aims to investigate the impact of job satisfaction on turnover intention among professionals in the construction industry.
Design/methodology/approach
A questionnaire survey was employed to collect viewpoints from 449 professionals in the Chinese construction industry, followed by descriptive analysis, correlation analysis and structural equation modelling analysis to derive results.
Findings
The findings indicate that professionals in the industry generally have a slightly high level of job satisfaction while a slightly low level of turnover intention in the special period of the pandemic outbreak. Leadership and management, training and career development and interpersonal relationships are critical underlying factors leading to their turnover intention. Although demographic factors have no moderating effect between job satisfaction and turnover intention, among them, age, marital status and years of working experience have strongly positive relationships with job satisfaction while significantly negative relationships with turnover intention.
Originality/value
The findings provide valuable insights to fully understand the critical factors leading to turnover intention from the perspective of job satisfaction, which is helpful in developing effective measures to address the turnover problems for enterprises in the Chinese construction industry and those industries with similar characteristics in other regions.
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Meriem Aziez, Saber Benharzallah and Hammadi Bennoui
The purpose of this paper is to address the Internet of Things (IoT) service discovery problem and investigate the existing solutions to tackle this problem in many aspects.
Abstract
Purpose
The purpose of this paper is to address the Internet of Things (IoT) service discovery problem and investigate the existing solutions to tackle this problem in many aspects.
Design/methodology/approach
This paper presents an overview of IoT services aiming at providing a clear understanding about their features because this term is still ambiguous for the IoT service discovery approaches. Besides, a full comparison study of the most representative service discovery approaches in the literature is presented over four perspectives: the IoT information model, the mechanism of IoT service discovery, the adopted architecture and the context awareness. These perspectives allow classifying, comparing and giving a deeper understanding of the existing IoT service discovery solutions.
Findings
This paper presents a new definition and a new classification of IoT services and citation of their features comparing with the traditional Web services. This paper discusses the existing solutions, as well as the main challenges, that face the service discovery issue in the IoT domain. Besides, two classifications of the approaches are adopted on the basis of their service description model and their mechanism of discovery, and a set of requirements that need to be considered when defining an IoT service are proposed.
Originality/value
There are few number works that survey the service discovery approaches in the IoT domain, but none of these surveys discuss the service description models in the IoT or the impact of the context awareness aspect in the service discovery solution. There are also few works that give a comprehensive overview of IoT services to understand their nature to facilitate their description and discovery. This paper fills this gap by performing a full comparison study of multi-category and recent approaches for service discovery in the IoT over many aspects and also by performing a comprehensive study of the IoT service features.
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