Search results

The purpose of this study was to investigate the microstructural evolution and hydrolytic stability of poly(phenylborosiloxane) (PPhBS) to further use and develop the oligomers as heat-resistant modifiers.

PPhBS was synthesized by direct co-condensation of boric acid (BA) and phenyltriethoxysilane (PTEOS). The structural evolution of PPhBS at high temperature was investigated by Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), differential thermal analysis (DTA), in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and 29Si nuclear magnetic resonance (NMR) spectroscopy. In addition, the change in the morphology of the PPhBS powder was examined to demonstrate the evolution of the chemical bonds, and the hydrolytic stability of PPhBS was investigated by a combination of X-ray diffraction (XRD) analysis, measurement of the mass loss in water and FTIR spectroscopy.

The results revealed that a cross-linking network was gradually formed with increasing temperature through the condensation of the residual hydroxyl groups in PPhBS, and the Si-OH and B-OH bonds remained even at a high temperature of 450°C. Furthermore, heat treatment improved the hydrolytic stability of the oligomer. The hydrolysis of the B-O-B bonds in PPhBS was reversible, whereas the Si-O-Si and Si-O-B bonds were highly resistant to hydrolysis.

The prepared PPhBS can be used as a heat-resistant modifier in adhesives, sealants, coatings and composite matrices.

Investigation of the structural evolution of a polyborosiloxane at high temperature by DRIFTS is a novel approach that avoided interference from moisture in the air. The insoluble mass fraction and the FTIR spectrum of PPhBS washed with water were used to investigate the hydrolytic stability of PPhBS.

This study aims to investigate the heat transfer mechanism of the uniforms used by people working in hot, humid and windy environments. Furthermore, the effectiveness of an opening structure added to the armpit of the uniforms in improving thermal comfort was comparatively examined.

A set of uniforms was tested with the opening at the armpit alternatively zipped or unzipped. Thermal manikin and human tests were performed in a climatic chamber simulating the specific environmental conditions, including wind speeds at four levels (0.15, 0.5, 2, 4 m/s) and relative humidities at two levels (50 and 85%). Static and dynamic thermal insulations of clothing (I_T) were examined by the thermal manikin tests. The human bodies' thermal responses, including heart rates (HR), eardrum temperatures (T_e), skin temperatures (T_sk) and subjective perceptions, were given by the human tests.

Special mechanisms of heat transfer in the specific uniforms used in tropical monsoon climates were revealed. Reductions on I_T were caused by the movement of the human body and the environmental wind, and the empirical equations would underestimate this reduction. The opening at the armpit was able to prompt more heat transfer under dynamic condition, with reducing the I_T by 11.8%, lowering the mean T_sk by 0.92°C, and significantly improving the subjective perceptions (p < 0.05). The heat exhaustion was alleviated with lowering the T_e by 0.32°C.

This study managed to improve the thermal performance of uniforms for workers under unforgiving conditions. The evaluation and design methods introduced by this study provided practical guidance for similar products with strict dress codes and cost control requirements based on the findings from thorough product tests and analysis.

The purpose of this study is to modify cerium dioxide with fumaric acid (CeO₂-f) to improve its compatibility and dispersibility in epoxy resin and to investigate the effect of the content on the coating performance.

To investigate whether CeO₂-f reacts with epoxy resin by ring opening, CeO₂-f and epoxy resin-treated CeO₂-f (Ce CeO₂-f/EP) were analyzed by infrared radiation (IR), X-ray diffraction (XRD) and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis). To reveal the effect of different content on coatings properties, neutral salt spray test (NSST) and electrochemical test were performed.

The results of IR, XRD, X-ray photoelectron spectroscopy and UV-Vis indicated that fumaric acid attached to the CeO₂ surface by chemical bonding and underwent a ring-opening reaction with epoxy resin, thus, improving the compatibility of CeO₂ in epoxy resin. NSST and electrochemical impedance spectroscopy results showed that the coatings containing 5% CeO₂-f exhibited the optimal corrosion resistance. The reason is that a dense conversion film was established on the substrate surface.

The epoxy coatings using CeO₂-f as fillers with synergistic inhibition ability are promising for the protection of carbon steel.