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Alginate fiber with a breaking tenacity of up to 2.32 cN/dtex is prepared by spinning a sodium alginate solution in a coagulating solution of CaCl₂ aqueous solution followed by multi-roller drawing. Preparation parameters such as sodium alginate concentration, coagulant concentration and coagulation temperature, which affect the fiber tenacity, are investigated with an orthogonal test design, and the best spinning process is found with a coagulating 5% sodium alginate solution in 4% CaCl₂ at 40°C. The morphology, degree of crystallinity, thermal stability and the combustion performance of this alginate fiber are investigated by scanning electron microscopy (SEM), infrared (IR), X-ray diffraction (XRD), Thermo gravimetric Analysis (TGA) and Cone Calorimeter. Using the centrifugal dewatering method, the absorption capacity of this alginate fiber is determined, and has a capacity of 13.01 grams of man-made blood per gram. The test results show that fibers have an irregular cross-section without a thicker cortex and uniform longitudinal surface with grooves. The combustion property results demonstrate that the fiber has a self-flameretarding property.