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Vitamin D deficiency is prevalent worldwide. This paper aims to investigate the vitamin D status and dietary intake in young university students.

Forty-one healthy students aged 18–29 years from Coventry University UK were recruited during January-February 2019, including white Caucasians (n = 18), African-Caribbeans (n = 14) and Asians (n = 9). Plasma 25(OH)D concentrations were measured and dietary vitamin D intake was determined. Chi-square and simple linear regression were used to analyse the data.

The plasma 25(OH)D concentrations were (36.0 ± 22.2) nmol/L in all subjects, (46.5 ± 25.3) nmol/L in white Caucasians, (22.6 ± 7.4) nmol/L in African-Caribbeans and (37.4 ± 21.7 nmol/L) in Asians. The majority (85.7%) of African-Caribbeans were vitamin D deficient compared with 22.2% of white Caucasians and 33.3% of Asians (p = 0.001). Overweight/obese subjects showed a significant higher proportion of vitamin D deficiency (65%) than normal weight subjects (28.6%) (p = 0.04). The average dietary vitamin D intake in all subjects was (4.6 ± 3.9) µg/day. Only 12.1% of the subjects met the recommended dietary vitamin D intake of 10 µg/day. Dietary vitamin D intake (p = 0.04) and ethnicity (p = 0.01) were significant predictors of 25(OH)D levels and accounted for 13% and 18.5% of 25(OH)D variance, respectively.

This small-scale study showed an alarmingly high prevalence of vitamin D deficiency among subjects from African-Caribbean origin during wintertime. Education programs and campaigns are urgently needed to fight the vitamin D deficiency in this population.

The targeted population were in a critical period of transition from adolescence toward adulthood involving in changes in behaviours and nutrition.

Based on core description, gas logging and laboratory analysis, this paper aims to study the controlling effect of the types of shale sedimentary microfacies in coal formations over shale reservoirs using the example of Shanxi formation in Northern Ordos Basin.

According to core observation, the authors selected typical samples of rock types for thin section analysis to determine the micro features and compositions of rocks.

By using core observation, we found that fine lithology in Shanxi formation included major shale, carbonaceous shale, partially carbonaceous shale, partially silty shale and silty shale with colors of gray, dark gray, black and/or gray. Shanxi Formation shale are deposited in plant-rich and plant-poor swamps, interdistributary depressions of delta plains, interfluvial depressions of meandering rivers as well as microfacies environment of natural levees and the distal crevasse splay.

Currently, the research on the shale gas in Shanxi Formation in the Ordos Basin is still in its infancy. There is yet no research on the fine-grained partition of the sedimentary facies in coal accumulation environment of Shanxi formation and the controlling effect of sedimentary microfacies over shale reservoirs.

Since their inception in late 2007, the Qualified Domestic Institutional Investor (QDII) funds, which help Chinese investors to invest in foreign capital markets, have experienced significant portfolio losses and persistent fund outflows. While these losses are large in absolute terms, QDII funds, on average, performed better than Chinese A-share funds, but slightly worse than a group of foreign mutual funds. Our study focuses on the QDII industry, and asks three interrelated questions: (1) why have there been large fund outflows from the industry? (2) what explains QDII funds’ poor performance? and (3) why have QDII funds been so heavily exposed to the Hong Kong market? Our empirical analysis shows that the persistent capital outflows were primarily a result of disappointing fund performance. This poor performance can, in turn, be explained by the deficiency of knowledge required of QDII fund managers to successfully invest in foreign capital markets and manage global portfolios. Finally, our study goes some way to explain the phenomenon of QDII funds’ large asset allocation in the Hong Kong market. This ‘Hong Kong bias’ is shown to be consistent with the well-documented ‘home bias’ behaviour in cross-border portfolio investment, but is greatly exacerbated by the lack of global investing experience of QDII managers.

Aluminum foam-filled thin-walled unit structures have received much attention for their excellent energy absorption properties. To improve the energy absorption effect of car energy absorption box under axial compression, this paper optimizes the fiber lay-up sequence, fiber angle and aluminum foam density of aluminum foam filled carbon fiber reinforced plastic (CFRP) thin-walled square tubes.

Design of sample points required to construct the proxy model using design of experiments (DOE) method, and the data sample points of different models are obtained through Abaqus simulation and test. A double high-precision proxy model with the maximum specific energy absorption (SEA) and the minimum initial peak crash force (PCF) as the evaluation index is constructed based on the response surface function method. The NSGA-II multi-objective genetic algorithm was used to optimize the design parameters and obtain the optimal solution for the Pareto front, and the results were verified by using the multi-objective optimization toolbox in design-expert.

The results show that the optimal solution to the multi-objective optimization problem with the inclusion of the lay-up sequence is ρ = 0.5g/cm3 for a fiber lay-up angle varying in the range ±15–90° and an aluminum foam density varying in the range 0.2g/cm3-0.5g/cm3, with a lay-up method of [±87°/±16°/±15°/±89°]. The two optimization methods correspond to SEA and PCF errors of 2.109% and 4.1828%, respectively. The optimized SEA value is 18.2 J/g and the PCF value is 18,230 N. The optimized design reduces the peak impact force and increases the specific energy absorption, which improves the energy absorption effect of thin-walled energy-absorbing boxes for automobiles.

In this paper, the impact resistance of CFRP thin-walled square tubes filled with aluminum foam is optimized. Based on numerical simulations and experiments to obtain the sample point data for constructing the dual-agent model, we investigate the effect of filling with different densities of aluminum foam under the simultaneous change of fiber lay-up angle and order on its mechanical properties in this process, and carry out the multi-objective optimization design with NSGA-II algorithm.

The purpose of this study is to develop luminescence sensors for the detection of nitroaromatic compounds (NACs) and metal ions to protect human health and prevent environmental pollution.

The composition and morphology of Eu-metal-organic frameworks (MOF) (1) were well characterized by powder X-ray diffraction, elemental analyses, Fourier-transform infrared spectroscopy, thermogravimetric analysis, X-ray photoelectron spectroscopy and scanning electron microscopy. The emission spectrum displays that 1 has significant characteristic emission bands of Eu(III) ions. The authors further investigated the fluorescence sensing performances of 1 to NACs and metal ions.

The results show that Eu-MOF (1) exhibits significant fluorescence quenching effect toward p-nitroaniline and Fe³⁺ ions with good stability and recyclability. This means that 1 can be used as a multifunctional sensing material for the detection of p-nitroaniline and Fe³⁺ ions.

The authors have successfully synthesized a fluorescence Eu-based sensing material under hydrothermal conditions. In addition, the fluorescence property and sensing performances for detecting NACs and metal ions were studied. The results suggest that 1 has highly selective fluorescence quenching toward p-nitroaniline and Fe³⁺ ions with not only high sensitivity and selectivity but also excellent stability and recyclability. Furthermore, this study has confirmed that the multifunctional MOF material is very useful in environment pollutants’ detection and monitoring.

We seek to quantify the relationship between urbanization and economic growth in China using recent advances in econometric techniques.

This study adopts a smoothed instrumental variables quantile regression (SIVQR) estimator to obtain consistent estimates of the effects of urbanization on economic growth in China. Our approach accounts for the differential impacts of urbanization across the conditional distribution of economic growth while allowing for an identification strategy that addresses the endogeneity of urbanization. Our main findings reveal that ignoring urbanization endogeneity leads to inconsistent estimates of urbanization effects. Further, we find a positive relationship between urbanization and growth resembling an inverted U-shape. This supports the hypothesis that the beneficial effects of urbanization intensify at initial stages while diminishing beyond a certain threshold, due perhaps to weakening scale economies.

Our main results indicate that the individual productivity gains brought by urbanization outweigh the negative effects thereof that impede productivity, thus contributing to the economic growth in China. Further, we find that ignoring differential impacts of urbanization underestimates the beneficial effects of urbanization for provinces whose quality of governance is in the vicinity of the center of quality distribution. Ignoring the endogeneity of urbanization generates inconsistent estimates of the elasticity of economic growth with respect to urbanization. Finally, we estimate an inverted U-shape resembling relationship between urbanization and growth.

First, future studies would benefit from incorporating more data as provinces further east on the mainland become more urbanized and urbanization runs its course. Second, controlling the barriers to rural-urban mobility would contribute to the robustness of the estimated relationship between urbanization and growth once such data became available. Unveiling the impact of government-imposed barriers is key to designing optimal policies that help fuel economic growth in the country. Finally, future research could benefit from information on urbanization sources not considered here such as inter-provincial migration, as such data become publicly available.

Quantifying the beneficial effects of urbanization on economic growth can help guide the government in China to further fuel the growth through a set of relevant policy tools that promote urbanization.

Rural-urban migration in China lays the groundwork for economic advancement in recipient cities and economies, as it may induce scale economies. This can benefit both the economy at large and the migrants.

The SIVQR estimator accounts for potential heterogeneous effects of urbanization across the entire conditional distribution of growth while allowing for an identification strategy that addresses the endogeneity of urbanization. An additional distinguishing feature of the current study is our use of the most recent novel, provincial-level data obtained from the National Bureau of Statistics of China. Our focus on a single country allows sidestepping issues arising from the inconsistency of the definition of urban across different countries while accounting for intra-country urbanization drivers intrinsic to China, such as natural features and geographic characteristics. Therefore, our approach has the potential to sidestep the bias resulting from the differences in mechanisms behind urbanization-growth relationships across different countries.

Polyetheretherketone (PEEK) is used to manufacture biomedical implants because it has a high strength-to-weight ratio and high strength and is biocompatible. However, the use of fused deposition modeling to print a PEEK results in low strength and crystallinity. This study aims to use the Taguchi method to optimize the printing factors to obtain the highest tensile strength of the printed PEEK object. The annealing effect on printed PEEK object and crystallinity are also investigated.

This study determines the printing factors including the printing speed, layer thickness, printing temperature and extrusion width. Taguchi experimental design with a L9 orthogonal array is used to print the tensile specimen and carried out the tensile test to compare the tensile strength and porosity. Analysis of variance (ANOVA) is used to determine the experimental error and to determine the optimization printing parameters to obtain the highest tensile strength. A multivariate linear regression analysis is used to obtain the linear regression equation for predicting the theoretical tensile strength. An X-ray analysis is achieved to evaluate the crystalline of printed object. The effect of annealing is investigated to improve the tensile strength of printed part. An intervertebral lumber device is printed to demonstrate the feasibility of the obtained optimization parameters for practical application.

Taguchi experiment designs nine sets of parameters to print the PEEK tensile specimen. The experimental results and the ANOVA present that the order in which the factors affect the tensile strength for printed PEEK parts is the layer thickness, the extrusion width, the printing speed and the printing temperature. The optimized printing parameters are a printing speed of 5 mm/s, a layer thickness of 0.1 mm, a printing temperature of 395 °C and an extrusion strand width of 0.44 mm. The average tensile strength of printed specimen with the optimized printing parameters is 91.48 MPa, which is slightly less than the theoretical predicted value of 94.34 MPa. After annealing, the tensile strength increases to 98.85 MPa, which is comparable to that for molded PEEK and the porosity decreases to 0.3 from 3.9%. X-ray diffraction results show that all printed and annealed specimens have a high degree of crystallinity. The printed intervertebral lumber device has ultimate compressive load of 13.42 kN.

The optimized printing parameters is suitable for low-price fused deposition modeling machine because it does not involve a table at high temperature and can print the PEEK object with high tensile strength and good crystalline. Annealing parameters offer a good solution for tensile strength improvement.

The potential implications of the three-dimensional printing (3DP) technology are growing enormously in the various health-care sectors, including surgical planning, manufacturing of patient-specific implants and developing anatomical models. Although a wide range of thermoplastic polymers are available as 3DP feedstock, yet obtaining biocompatible and structurally integrated biomedical devices is still challenging owing to various technical issues.

Polyether ether ketone (PEEK) is an organic and biocompatible compound material that is recently being used to fabricate complex design geometries and patient-specific implants through 3DP. However, the thermal and rheological features of PEEK make it difficult to process through the 3DP technologies, for instance, fused filament fabrication. The present review paper presents a state-of-the-art literature review of the 3DP of PEEK for potential biomedical applications. In particular, a special emphasis has been given on the existing technical hurdles and possible technological and processing solutions for improving the printability of PEEK.

The reviewed literature highlighted that there exist numerous scientific and technical means which can be adopted for improving the quality features of the 3D-printed PEEK-based biomedical structures. The discussed technological innovations will help the 3DP system to enhance the layer adhesion strength, structural stability, as well as enable the printing of high-performance thermoplastics.

The content of the present manuscript will motivate young scholars and senior scientists to work in exploring high-performance thermoplastics for 3DP applications.