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Investigates the adhesion and corrosion performance of selected silanes in primed galvanised steel. For comparison HDG steel was also treated with a chromate‐free and a chromate‐containing pre‐treatment. All treated panels were painted with three different primers. Corrosion resistance and paint adhesion of the primed panels were studied. Surface energy of the panels was measured by the contact angle method and is reported in terms of the Lewis base component. The corrosion resistance of the panels depended on the combination of the silane and the primer. Vinyltrimethoxysilane (VS) and γ‐aminopropyltriethoxysilane (γ‐APS) treatments improved the corrosion resistance of polyurethane primed panels. γ‐ureidopropyltrimethoxysilane (γ‐UPS) and VS treatments improved the performance of polyester primed panels. A relationship between the base components and the prohesion test results of γ‐UPS and γ‐APS treated panels was found, which indicates that acid‐base interactions improve the adhesion between these two silanes and the primers. γ‐UPS and γ‐APS treated panels also achieved excellent results in the humidity test with all three polymer coatings.